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1.发明公开PROCEDE DE PREPARATION D'UN OXYDE DE LITHIUM ET DE VANADIUM DU TYPE LI(1+A)V3O8 有权VERFAHREN ZUR HERSTELLUNG EINES LITHIUM-VANADIUM-OXIDS DES TYPS LI（1 + A）V3O8
公开(公告)号：EP1718567A2
公开(公告)日：2006-11-08
申请号：EP05717638.0
申请日：2005-02-16
IPC分类号： C01G31/00
CPC分类号： H01M4/485 , C01G31/00 , C01P2004/03 , C01P2004/10 , C01P2004/54 , C01P2004/61 , C01P2006/40 , H01M4/131 , H01M4/136 , H01M10/052
摘要： The invention relates to a method for preparing a lithium and vanadium oxide and the thus obtained products consisting in preparing a precursor gel by reacting hydrogen peroxide with V2O5-α in an aqueous medium in the presence of a lithium precursor and in exposing said gel to a heat treatment in an oxidant atmosphere at a temperature ranging from 260 °C to 580 °C. A compound of a formula Li1+α V3O8, (0,1=α= 0,25) consists of needle-shaped grains having a bimodal distribution, wherein the length (L) of the first distribution needles ranges from 10 to 50 νm and the length (L) of the second distribution needles ranges from 1 to 10 νm. When l is the grain width, L the length and e the thickness thereof, said dimensions are such as 4
摘要翻译： 含有呈双峰分布的针状晶粒的锂钒氧化物复合物（I）是新的。 式Li 1 +αV 3 O 8（其中α大于0.1且小于0.25）的钒钒络合物（I），其包含呈现双峰分布的针形式的晶粒（其中针的第一种模式的长度为10 -50微米，针的长度为1-50微米，长宽比和长度比大于4，小于100），是新的。 还包括：（1）（I）的准备; （2）锂电池用正极（A），其包含（I）作为活性物质; 和（3）包含（A）和由电解质分离的负极的电池，所述电解质在溶剂中包含锂盐溶液。
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2.发明授权OXYDE DE LITHIUM ET DE VANADIUM, UN PROCEDE POUR SA PREPARATION, SON UTILISATION COMME MATIERE ACTIVE D'ELECTRODE 有权OXYD OFF和钒锂，HERSTELLUNGSVEFAHREN，其作为活性电极材料
公开(公告)号：EP1438761B1
公开(公告)日：2011-08-10
申请号：EP02785529.5
申请日：2002-10-08
发明人： JOUANNEAU, Séverine , GUYOMARD, Dominique , LE GAL LA SALLE, Annie , VERBAERE, Alain , LASCAUD, Stéphane , BOURGEON, Nelly , DESCHAMPS, Marc
IPC分类号： H01M4/48
CPC分类号： H01M4/131 , H01M4/134 , H01M4/136 , H01M4/40 , H01M4/405 , H01M4/485 , H01M4/5825 , H01M10/052 , H01M10/0565 , H01M10/0566 , H01M10/0587
摘要： The invention relates to a lithium and vanadium oxide having formula Li1+xV3O8, wherein 0.1 ≤ x ≤ 0.25. Said oxide has a monoclinic crystalline structure and comprises non-agglomerated grains in the form of moncrystalline pellets having a length L of between 1 and 100νm, a width l such that 4 ∫L/l ∫100, and a thickness e such that 4 L/e ∫100, with e
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3.发明公开OXYDE DE LITHIUM ET DE VANDIUM Li1+ V3O8 (0,1 0,25) PROCEDE POUR SA PREPARATION 有权氧化锂锂和钒锂Li1 + V3O8（0,1 0,25）程序POUR SA制备
公开(公告)号：EP1831110A1
公开(公告)日：2007-09-12
申请号：EP05809319.6
申请日：2005-10-18
CPC分类号： H01M4/131 , C01G31/00 , H01M4/136 , H01M4/485 , H01M4/5825 , H01M4/62 , H01M10/0525 , Y02E60/122
摘要： The invention relates to a lithium and vanadium oxide. The oxide corresponds to formula Li1+α V3O8 (0,1≤ α ≤0,25) and is made up of agglomerates of small needles whose length L is 400 - 1000 nm, whose width is such that 10
摘要翻译： 本发明涉及锂和钒氧化物。 该氧化物对应于式Li1 +αV3O8（0,1≤α≤0.25）并且由长度L为400-1000nm，宽度为10
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公开(公告)号：EP1831109A1
公开(公告)日：2007-09-12
申请号：EP05809094.5
申请日：2005-10-18
CPC分类号： C01G31/00 , C01P2002/72 , C01P2006/40 , H01M4/131 , H01M4/136 , H01M4/405 , H01M4/485 , H01M4/525 , H01M4/58 , H01M4/5815 , H01M4/5825 , H01M4/62 , H01M4/625 , H01M10/0525
摘要： The invention relates to the preparation of a Ϝ-LiV2O5 optionally carbon material. The method consists in preparing a composition consisting of carbon and Li and V precursors, and in subjecting it to thermal treatment. The composition is prepared by bringing carbon, V2O5-α and a Li precursor into contact, the quantities thereof being such that the ratio of concentrations [V2O5]/[Li] is 0.95 1.05, carbon exceeding by at least 25 % in relation to the stoichiometry. Thermal treatment is carried out in two stages: a first stage at a temperature of 90 °C -150 °C during 1 -12 hours; a second stage at a temperature of 420 °C - 500 °C, during 10 mins - 1 hour, in a nitrogen or argon atmosphere or in a vacuum. Applications: positive-electrode active matter.
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公开(公告)号：EP1831945B1
公开(公告)日：2008-04-30
申请号：EP05809230.5
申请日：2005-10-18
CPC分类号： H01M4/622 , B01J23/22 , H01M4/133 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2004/028 , Y10S977/773 , Y10S977/811 , Y10T428/292 , Y10T428/2993
摘要： The invention relates to a nanostructured material. Said material is a nanostructured carbon material consisting of agglomerates of small needles of Li1+aV3O8 and ßLixV2O5 (0,l≤ α ≤ 0,25 et 0,03 ≤ x ≤ 0,667 surrounded by a discontinuous coating of spherical carbon particles. It is obtained by means of a process consisting in preparing a carbon precursor gel by bringing carbon, V2O5- α an a Li precursor into contact with each other, the amounts thereof being such that the ratio of concentrations [V2O5]/[Li] ranges from 1.15 to 1.5, and the mass ratio (carbon)/ (carbon + V2O5+ Li precursor) is 10 to 15, and in subjecting the gel to heat treatment including a first stage at 8O0C - 15O0C pendant 3-12 h, and a second stage between 3000C and 35O0C, during 10 mins to 1 hour, in a nitrogen or argon atmosphere. n. Applications: positive-electrode active material.
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公开(公告)号：EP1849205A2
公开(公告)日：2007-10-31
申请号：EP06709130.6
申请日：2006-01-19
申请人： Batscap
发明人： DESCHAMPS, Marc
CPC分类号： H01M10/056 , H01M6/187 , H01M10/0525 , H01M2300/0082 , H01M2300/0094
摘要： The invention relates to a bilayer polymer electrolyte for a lithium battery. The inventive electrolyte comprises N and P layers which are each formed by a solid solution of an Li salt in a polymer material, said Li salt being the same in both layers, whereby the concentration of polymer material is at least 60 % by weight and the concentration of lithium salt is between 5 and 25 % by weight. The polymer material from layer P contains a solvating polymer and a non-solvating polymer, the weight ratio between the two polymers being such that the solvating polymer forms a continuous network. The polymer material from layer N is formed by a solvating polymer and, optionally, a non-solvating polymer, the weight ratio between the two polymers being such that the solvating polymer forms a continuous network and the non-solvating polymer does not form a continuous network.
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7.发明公开
公开(公告)号：EP1790030A1
公开(公告)日：2007-05-30
申请号：EP05779662.5
申请日：2005-06-27
申请人： Batscap
CPC分类号： H01B1/20 , G02F1/1525 , H01B1/122 , H01M4/13 , H01M4/62 , H01M6/166 , H01M6/181 , H01M6/188 , H01M10/0525 , H01M10/0565 , H01M10/0568
摘要： The invention concerns an ionic conducting material containing an oligoether sulphate. The material comprises an ionic compound in solution in a solvating polymer. The ionic compound is a mixture of a lithium bis(trifluoromethanesulphonyl)imidide and of at least one lithium oligoether sulphate selected among lithium oligoether sulphate of formula R-[O-CH2-CH2)]n-O-SO3-Li+ (I), wherein: R is a CmH2m+1 group with 1 = m =4 and 2 = n =17, and lithium oligoether sulphate of formula Li+ O-SO2-O-CH2 [CH2-O-CH2]p-CH2-O-SO2-O- Li+ (II), wherein 3 =p =45; the overall ratio Ot/Lit is not more than 40, Ot representing the total number of atoms O supplied by the solvating polymer and by the oligoether; the LiTFSI content is such that the Ot/LiTFSI ratio is not less than 20.
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8.发明授权
公开(公告)号：EP1790030B1
公开(公告)日：2009-02-25
申请号：EP05779662.5
申请日：2005-06-27
申请人： Batscap
CPC分类号： H01B1/20 , G02F1/1525 , H01B1/122 , H01M4/13 , H01M4/62 , H01M6/166 , H01M6/181 , H01M6/188 , H01M10/0525 , H01M10/0565 , H01M10/0568
摘要： The invention concerns an ionic conducting material containing an oligoether sulphate. The material comprises an ionic compound in solution in a solvating polymer. The ionic compound is a mixture of a lithium bis(trifluoromethanesulphonyl)imidide and of at least one lithium oligoether sulphate selected among lithium oligoether sulphate of formula R-[O-CH2-CH2)]n-O-SO3-Li+ (I), wherein: R is a CmH2m+1 group with 1 = m =4 and 2 = n =17, and lithium oligoether sulphate of formula Li+ O-SO2-O-CH2 [CH2-O-CH2]p-CH2-O-SO2-O- Li+ (II), wherein 3 =p =45; the overall ratio Ot/Lit is not more than 40, Ot representing the total number of atoms O supplied by the solvating polymer and by the oligoether; the LiTFSI content is such that the Ot/LiTFSI ratio is not less than 20.
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9.发明公开COPOLYMERE D'OXYDE D'ETHYLENE OU DE PROPYLENE ET D'UN OXIRANE PORTANT UN GROUPEMENT IONIQUE 有权丙烯或环氧乙烷的共聚物及其与离子性基团的环氧乙烷
公开(公告)号：EP1853644A1
公开(公告)日：2007-11-14
申请号：EP06709281.7
申请日：2006-02-09
申请人： Batscap
发明人： SANCHEZ, Jean-Yves , DESCHAMPS, Marc , ALLOIN, Fannie , CHAUVIN, Christophe , IOJOIU, Christina
IPC分类号： C08G65/22 , C08G65/321 , C08G65/24
CPC分类号： C08G65/321 , C08G18/0828 , C08G18/5072
摘要： The invention relates to a copolymer of ethylene oxide or propylene oxide and of at least one substituted oxirane bearing an ionic group. The copolymer is characterised in that the chain thereof comprises repeating units -O-CH2 CH(-CH2-O-SO3-Li+)-, repeating units -O-CH2- CHR-, in which R is H or CH3, and, optionally, repeating units -O-CH2-CH(-CH2R')-, in which R' is a functional group. The invention can be used to produce an electrolyte in electrochemical devices, selective membranes, reference membranes.
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公开(公告)号：EP1831945A2
公开(公告)日：2007-09-12
申请号：EP05809230.5
申请日：2005-10-18
CPC分类号： H01M4/622 , B01J23/22 , H01M4/133 , H01M4/625 , H01M10/052 , H01M10/0525 , H01M10/0562 , H01M10/0565 , H01M2004/028 , Y10S977/773 , Y10S977/811 , Y10T428/292 , Y10T428/2993
摘要： The invention relates to a nanostructured material. Said material is a nanostructured carbon material consisting of agglomerates of small needles of Li1+aV3O8 and ßLixV2O5 (0,l≤ α ≤ 0,25 et 0,03 ≤ x ≤ 0,667 surrounded by a discontinuous coating of spherical carbon particles. It is obtained by means of a process consisting in preparing a carbon precursor gel by bringing carbon, V2O5- α an a Li precursor into contact with each other, the amounts thereof being such that the ratio of concentrations [V2O5]/[Li] ranges from 1.15 to 1.5, and the mass ratio (carbon)/ (carbon + V2O5+ Li precursor) is 10 to 15, and in subjecting the gel to heat treatment including a first stage at 8O0C - 15O0C pendant 3-12 h, and a second stage between 3000C and 35O0C, during 10 mins to 1 hour, in a nitrogen or argon atmosphere. n. Applications: positive-electrode active material.
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