摘要:
The present invention relates to a polyolefin composition comprising (v) a crosslinkable polyolefin with hydrolysable silane groups (A), (vi) a dihydrocarbyl tin dicarboxylate (B) as a silanol condensation catalyst according to the following formula (I): wherein R1 and R2 independently are hydrocarbyl groups having at least 6 carbon atoms, and R3 and R4 independently are hydrocarbyl groups having at least 8 carbon atoms, to a wire or cable comprising a layer made of such a composition, and to the use of such a composition for the production of a layer of a cable.
摘要:
The invention relates to silane-functionalised polyolefin compositions, to silane-crosslinkable polyolefin compositions and to silane-crosslinked polyolefin compositions, to a preparation process thereof, to their use for producing products and to the obtained products, to their use for W&C applications, preferably for producing one or more layers of a cable comprising said silane-functionalised polyolefin composition, as well as to silane-crosslinked cables comprising polyolefin compositions.
摘要:
The present invention relates to a semiconductive polyolefin composition comprising: (i) up to 80 wt.% of a polyolefin (I), (ii) carbon black, and (iii) optionally up to 60 wt.% of a polymer (II) having a melting point of not less than 100 °C, wherein the polyolefin (I) has a co-monomer content of equal to or less than 4.3 mol%, to the use of that composition for the production of a power cable and to a power cable comprising that composition.
摘要:
A cable comprising an electrical conductor with insulating and protecting layers surrounding the conductor is described. The cable is characterised in that at least one layer selected from said insulating and protecting layers consists of a crosslinked ethylene-alkyl (meth)-acrylate-unsaturated silane terpolymer composition wherein the alkyl (meth)acrylate comonomer comprises more than 5 mole% and the terpolymer composition has a tensile modulus, determined according to ISO 527-2 (1 mm/min) of less than 100 MPa. Preferably, the crosslinked ethylene-alkyl (meth)acrylate polymer is a moisture curable ethylene-alkyl (meth)acrylate-vinyl trialkoxysilane terpolymer, wherein the trialkoxysilan termonomer comprises 0.2-5 % by weight of the polymer composition. The polymer composition may include from 0 up to 50 % by weight of a plasticiser, up to 60 % by weight of a filler, and up to 10 % by weight of an additive.
摘要:
A composition for an insulating layer of a medium to high voltage power cable is disclosed. The composition comprises a cross-linkable polymer with hydrolysable silane groups, and a silanol condensation catalyst of formula (I) ArSO3H or a precursor thereof, Ar being a benzene ring substituted with at least one hydrocarbyl radical such that the total number of carbon atoms of the hydrocarbyl radical (s) is 8-20, or a naphthalene ring substituted with at least one hydrocarbyl radical such that the total number of carbon atoms of the hydrocarbyl radical(s) is 4-18, and the catalyst of formula (I) containing 14-28 carbon atoms in total. A medium to high voltage cable with an insulating layer that has a thickness of more than 2 mm and that comprises the cross-linked product of the above mentioned composition is also disclosed, as is a process of preparing such a cable by cross-linking the cable in the presence of steam at a superatmospheric pressure. Preferably the crosslinking is carried out with saturated steam in a vulcanising tube at about 0.8-1.2 MPa and 170-190°C.
摘要:
The invention relates to silane-functionalised polyolefin compositions, to silane- crosslinkable polyolefin compositions and to silane-crosslinked polyolefin compositions, to a preparation process thereof, to their use for producing products and to the obtained products, to their use for W&C applications, preferably for producing one or more layers of a cable comprising said silane-functionalised polyolefin composition, as well as to silane-crosslinked cables comprising polyolefin compositions.
摘要:
A cable comprising an electrical conductor with insulating and protecting layers surrounding the conductor is described. The cable is characterised in that at least one layer selected from said insulating and protecting layers consists of a crosslinked ethylene-alkyl (meth)-acrylate-unsaturated silane terpolymer composition wherein the alkyl (meth)acrylate comonomer comprises more than 5 mole% and the terpolymer composition has a tensile modulus, determined according to ISO 527-2 (1 mm/min) of less than 100 MPa. Preferably, the crosslinked ethylene-alkyl (meth)acrylate polymer is a moisture curable ethylene-alkyl (meth)acrylate-vinyl trialkoxysilane terpolymer, wherein the trialkoxysilan termonomer comprises 0.2-5 % by weight of the polymer composition. The polymer composition may include from 0 up to 50 % by weight of a plasticiser, up to 60 % by weight of a filler, and up to 10 % by weight of an additive.
摘要:
A composition for an insulating layer of a medium to high voltage power cable is disclosed. The composition comprises a cross-linkable polymer with hydrolysable silane groups, and a silanol condensation catalyst of formula (I) ArSO3H or a precursor thereof, Ar being a benzene ring substituted with at least one hydrocarbyl radical such that the total number of carbon atoms of the hydrocarbyl radical (s) is 8-20, or a naphthalene ring substituted with at least one hydrocarbyl radical such that the total number of carbon atoms of the hydrocarbyl radical(s) is 4-18, and the catalyst of formula (I) containing 14-28 carbon atoms in total. A medium to high voltage cable with an insulating layer that has a thickness of more than 2 mm and that comprises the cross-linked product of the above mentioned composition is also disclosed, as is a process of preparing such a cable by cross-linking the cable in the presence of steam at a superatmospheric pressure. Preferably the crosslinking is carried out with saturated steam in a vulcanising tube at about 0.8-1.2 MPa and 170-190°C.