NOUVEAUX CATALYSEURS DE RETICULATION DE COMPOSITIONS SILICONES
    8.
    发明公开
    NOUVEAUX CATALYSEURS DE RETICULATION DE COMPOSITIONS SILICONES 审中-公开
    NOUVEAUX CATALYSEURS DE RETICULATION组合物硅

    公开(公告)号:EP3215557A1

    公开(公告)日:2017-09-13

    申请号:EP15801908.3

    申请日:2015-11-06

    IPC分类号: C08G77/08 C08L83/04 C08L83/14

    摘要: The invention relates to a crosslinkable composition X, comprising: at least one organopolysiloxane compound A comprising, per molecule, at least two C
    2 -C
    6 alkenyl radicals bonded to silicon atoms; at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom; at least one catalyst C which is a complex corresponding to the following formula: [Fe(L
    1 )2] in which: the symbol Fe represents iron at degree of oxidation II; the symbols L
    1 , which may be identical or different, represent a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonylated compound; optionally at least one adhesion promoter D; and optionally at least one charge E. The invention also relates to the use of the previously described catalyst C as silicone composition crosslinking catalyst, to a silicone composition crosslinking method, characterized in that it consists in heating the composition X to a temperature of between 70 and 200°C, and to the resulting crosslinked silicone material Y.

    摘要翻译: 本发明涉及可交联组合物X,其包含:至少一种有机聚硅氧烷化合物A,其每分子包含至少两个与硅原子键合的C 2 -C 6烯基; 至少一种有机氢聚硅氧烷化合物B,其每分子包含至少两个与相同或不同硅原子键合的氢原子; 至少一种催化剂C,其为对应于下式的配合物:[Fe(L1)2]其中:符号Fe表示氧化度为II的铁; 符号L1可以相同或不同,表示β-二羰基阴离子或β-二羰基化合物的烯醇化物阴离子的配体; 任选地至少一种助粘剂D; 和任选地至少一种电荷E.本发明还涉及前述催化剂C作为有机硅组合物交联催化剂与有机硅组合物交联方法的用途,其特征在于其包括将组合物X加热至70℃ 和200℃,并且得到交联的硅氧烷材料Y.