摘要:
A precatalyst for the polymerization of α-olefins, having the formula FeuMalc vXw(LA)y(LB)z wherein: - Malc is an alkali metal and/or an alkaline-earth metal. - X is an anion; - LA is a Lewis acid; - LB is a Lewis base; - u is between 0.001 and 10; - v is an integer > 1; - w is between 1 and 20; - y is between 0 and 10; z is between 0 and 10.
摘要:
The invention relates to a crosslinkable composition X, comprising: at least one organopolysiloxane compound A comprising, per molecule, at least two C 2 -C 6 alkenyl radicals bonded to silicon atoms; at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom; at least one catalyst C which is a complex corresponding to the following formula: [Fe(L 1 )2] in which: the symbol Fe represents iron at degree of oxidation II; the symbols L 1 , which may be identical or different, represent a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonylated compound; optionally at least one adhesion promoter D; and optionally at least one charge E. The invention also relates to the use of the previously described catalyst C as silicone composition crosslinking catalyst, to a silicone composition crosslinking method, characterized in that it consists in heating the composition X to a temperature of between 70 and 200°C, and to the resulting crosslinked silicone material Y.
摘要:
The invention relates to a crosslinked silicone material Y obtained by heating to a temperature of between 70 and 200°C, preferably between 80 and 150°C, and more preferably between 80 and 130°C, a crosslinkable composition X comprising: at least one organopolysiloxane compound A comprising, per molecule, at least two C 2 -C 6 alkenyl radicals bonded to silicon atoms; at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom; at least one catalyst C which is a complex corresponding to the following formula: [Ni (L 1 ) 2 ] in which: the symbol Ni represents nickel at degree of oxidation II; the symbols L 1 , which may be identical or different, represent a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonylated compound; optionally at least one adhesion promoter D; and optionally at least one charge E. The invention also relates to a crosslinkable composition X, to the use of the previously described catalyst C as silicone composition crosslinking catalyst, to a silicone composition crosslinking method, characterized in that it consists in heating the composition X to a temperature of between 70 and 200°C, and to the resulting crosslinked silicone material Y.