摘要:
This invention provides a polybutadiene capable of improving wear resistance and resistance to crack growth in a rubber composition and a tire, wherein values of e, f and g derived from the following determinant (I): 1.7455 0 - 0.0151 - 0.0454 0.4292 - 0.0129 - 0.007 0 0.3746 log 10 a / d log 10 a / b log 10 a / c = e f g (wherein a is a mountain peak value around 1130 cm -1 in a transmittance spectrum through Fourier transform infrared spectroscopy (FT-IR), and b is a valley peak value around 967 cm -1 , and c is a valley peak value around 911 cm -1 , and d is a valley peak value around 736 cm -1 ) satisfy relationships of equation (II): (Calculated value of cis-1,4 bond) = e/(e+f+g)x100 ≥ 99 and equation (III): Calculated value of vinyl bond = g / e + f + g x 100 ≤ 0.
摘要翻译:本发明提供一种能够提高橡胶组合物和轮胎中的耐磨性和抗裂纹生长性的聚丁二烯,其中衍生自以下决定基(I)的e,f和g的值为:1.7455 0-0.0151-0.0454 0.4292-0.0129〜 0.007 0 0.3746 log 10 a / d log 10 a / b log 10 a / c = efg(其中a是通过傅立叶变换红外光谱(FT-IR)的透射光谱中的1130cm -1附近的山峰值,b 是约967cm -1处的谷峰值,c是围绕911cm -1的谷峰值,d是736cm -1附近的谷峰值)满足式(II)的关系:(顺式 -1,4键)= e /(e + f + g)×100‰¥99和等式(III):乙烯基键的计算值= g / e + f + g ¢x 100‰¤0。
摘要:
This invention relates to an aromatic vinyl compound-conjugated diene compound copolymer capable of giving excellent wear resistance and resistance to wet skid to a tire, and more particularly to an aromatic vinyl compound-conjugated diene compound copolymer obtained by an addition polymerization of an aromatic vinyl compound and a conjugated diene compound in the presence of a polymerization catalyst composition comprising at least one specified metallocene complex selected from the group consisting of a metallocene complex represented by the following general formula (I):
(wherein M is a lanthanoid element, scandium or yttrium, and Cp R is independently a non-substituted or substituted indenyl, and R a to R f are independently an alkyl group having a carbon number of 1-3 or a hydrogen atom, and L is a neutral Lewis base, and w is an integer of 0-3) and so on, wherein a content of cis-1,4 bond in a conjugated diene compound portion is not less than 80%.
摘要:
There are provided a rubber composition simultaneously improving low loss factor and wear resistance as compared with the conventional ones as well as a tire using such a rubber composition. The invention lies in a rubber composition using a modified conjugated diene rubber and being excellent in the low loss factor and wear resistance as well as a tire. The rubber composition of the invention is formed by compounding a filler to a rubber component containing (A) a modified conjugated diene rubber having a cis-bond content in conjugated diene portion of not less than 87% and a vinyl bond content of not more than 2% and containing a functional group reactive with a filler and (B) a modified polymer having a modifying functional group number per 1 molecule of an unmodified polymer of not less than 0.6.
摘要:
There are provided a rubber composition simultaneously improving low loss factor and wear resistance as compared with the conventional ones as well as a tire using such a rubber composition. The invention lies in a rubber composition using a modified conjugated diene rubber and being excellent in the low loss factor and wear resistance as well as a tire. The rubber composition of the invention is formed by compounding a filler to a rubber component containing (A) a modified conjugated diene rubber having a cis-bond content in conjugated diene portion of not less than 87% and a vinyl bond content of not more than 2% and containing a functional group reactive with a filler and (B) a modified polymer having a modifying functional group number per 1 molecule of an unmodified polymer of not less than 0.6.
摘要:
A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by -OR5 where R5 is a monovalent organic group, with the proviso that A, R?1, R2, R4, and R5¿ are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.
摘要:
A method of producing cis-1,4-polydienes, the method comprising the step of contacting conjugated diene monomer with a lanthanide-based catalyst system in the presence of less than 20 % by weight of organic solvent based on the total weight of monomer, organic solvent, and resulting polymer, where the lanthanide-based catalyst system is the combination of or reaction product of (a) a lanthanide compound, (b) an organoaluminum hydride, (c) a trihydrocarbylaluminum, and (d) a halogen-containing compound.
摘要:
A continuous process for producing conjugated diene polymers comprising the steps of contacting, within an hydrocarbon solvent and within a continuous reactor, conjugated diene monomer and a catalyst composition prepared by combining: (a) a lanthanide compound, (b) an alkylating agent, and (c) a halogen-containing compound, and maintaining a non-ideal flow pattern within the continuous reactor so that 10% of the reagents entering the reactor at a reference time t0 are still present within the continuous reactor at a time t0 + xtrt, where trt is the residence time corresponding to ideal flow within the continuous reactor and x is a numeral greater than 1.5.