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    Solid catalyst component for alpha-olefin polymerization and process for producing the same
    1.
    发明公开
    Solid catalyst component for alpha-olefin polymerization and process for producing the same 失效
    对于Olefinenpolymerisation及其制造方法的固体催化剂组分。

    公开(公告)号：EP0229413A1

    公开(公告)日：1987-07-22

    申请号：EP86202177.1

    申请日：1986-11-28

    申请人： Chisso Corporation

    发明人： Shimizu, Hiroshi ,  Sato, Akihiro ,  Uwai, Toshihiro ,  Tachibana, Masami

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  Y10S526/901 ,  Y10S526/908 ,  Y10S526/909 ,  C08F4/655 ,  C08F4/6576

    摘要： A solid catalyst component which can produce a-olefin polymers having a high stereoregularity and a good powder fluidity, stably and with a good efficiency in gas phase polymerization, particularly in gas phase copolymerization, a catalyst for a-olefin polymerization using the above solid catalyst component and a process for producing the above catalyst component, are provided,

    which solid catalyst component is characterized in that it contains titanium as an active ingredient and is in the form of hollow fine particles, and
    which process is characterized by adding a reaction product (I) of an organoaluminum compound (A) with an electron donor (B,) to TiCℓ 4 and reacting these under agitation in a baffle ratio of 0.35 or less with a power required for agitation of 2.50 KW/m 3 or less at a temperature of 0° to 70°C for a period of I to 10 hours and further reacting an electron donor (B 2 ) and an electron acceptor (E) with the resulting solid product (II) to obtain a solid product (III) i.e. the solid catalyst component.

    A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer
    2.
    发明公开
    A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer 无效
    一种制备固体催化剂组分的烯烃聚合和处理的烯烃聚合过程

    公开(公告)号：EP0700936A1

    公开(公告)日：1996-03-13

    申请号：EP95113524.3

    申请日：1995-08-29

    申请人： CHISSO CORPORATION

    发明人： Uwai, Toshihiro ,  Tachibana, Masami ,  Saito, Jun

    IPC分类号： C08F10/00 ,  C08F4/654

    CPC分类号： B01J19/26 ,  B01J19/18 ,  B01J19/1862 ,  B01J2208/00176 ,  B01J2219/00094 ,  C08F10/00 ,  Y10S526/901 ,  C08F4/6543

    摘要： A solid catalyst component for olefin polymerization superior in shatter resistance and narrowness of particle size distribution, is provided,
       which component is prepared by
       spraying a mixture of Mg compound with an alcohol in a molten state, in a column; cooling the inside of the column; to obtain a component (B); partly removing the alcohol from (B), to obtain a solid component (C); contacting a halogen-containing Ti compound and an electron donor with (C); to obtain (D); contacting (D) with a halogen-containing Ti compound;
       in the above process,
       specifying the composition formulas of (A), (B) and (C); specifying the X-ray diffraction spector of (C) in comparison of that of (B); and contacting (C) with a halogen-containing Ti compound and an electron donor using an aliphatic hydrocarbon of a specified b.p., in a specified temperature.

    摘要翻译： 用于烯烃聚合中的抗破碎性和粒度分布的狭窄性优良的固体催化剂组分，被提供，其成分是通过在熔融状态下在醇喷雾的Mg化合物的混合物与，在一列中制备 冷却塔的内部; 以获得组分（B）; 部分地去除从（B）的醇，得到固体成分（C）; 接触含卤素的钛化合物和（C）电子给体; 以获得（D）; 接触（D）与含卤素的Ti化合物; 在上述过程中，指定的（A）的组合物式中，（B）和（C）; 在（B）的事实的比较指定（C）的X射线衍射斯佩克特; 接触和（C）与含卤素的Ti化合物和电子给体，使用在指定的沸点的脂族烃，在规定的温度。

    Catalysts for polymerization of olefins
    4.
    发明公开
    Catalysts for polymerization of olefins 失效
    用于烯烃聚合的催化剂

    公开(公告)号：EP0415704A3

    公开(公告)日：1992-04-22

    申请号：EP90309387.0

    申请日：1990-08-28

    申请人： CHISSO CORPORATION

    发明人： Tachibana, Masami ,  Uwai, Toshihiro ,  Matukawa, Tetuya ,  Hayasida, Teruaki

    IPC分类号： C08F4/637 ,  C08F4/636 ,  C08F4/685 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6565 ,  C08F4/6367 ,  C08F4/685 ,  C08F4/6365

    摘要： A catalytic ingredient for use in the polymerization of olefins comprises a carrier comprising a magnesium compound precipitated from solution and a catalytic component supported on the carrier and which is a titanium halide, vanadyl halide or vanadium halide, the catalyst being obtained by a process which comprises the steps of:
    (A) mixing (a) one or more magnesium compounds with (c) a saturated or unsaturated monohydric alcohol or a polyhydric alcohol, for reaction in solution in the presence of (b) carbon dioxide in an inert hydrocarbon solvent, to obtain component (A); (B) subjecting component (A) to mixing and reaction with (d) a titanium halide and/or a vanadyl halide and/or a vanadium halide and/or a silane halide together with (e) a boron compound, thereby giving solid product (I); (C) reacting solid product (I) with (f) a cyclic ether thereby causing dissolution and re-precipitation to give solid product (II); and (D) subjecting solid product (II) to further reaction with (g) component (B) consisting of a titanium halide and/or a vanadyl halide and/or a vanadium halide as defined for (d) above, thereby to give solid product (III): followed either by further reaction with a mixture of component (B) and (h) an electron donor or by reaction of (g) with the solid product (III) obtained by the reaction between the solid product (II) and (h), thereby obtaining solid product (IV) for use as the catalytic component. In modifications, the boron compound (e) may be replaced by a silane and/or siloxane compound; and/or an alcohol or polyhydric alcohol may be used in step (C).

    Catalysts for polymerization of olefins
    8.
    发明公开
    Catalysts for polymerization of olefins 失效
    碳酸酯化烯烃聚合。

    公开(公告)号：EP0599355A1

    公开(公告)日：1994-06-01

    申请号：EP93120272.5

    申请日：1990-08-28

    申请人： CHISSO CORPORATION

    发明人： Tachibana, Masami ,  Uwai, Toshihiro ,  Matukawa, Tetuya ,  Hayasida, Teruaki

    IPC分类号： C08F10/00 ,  C08F4/658

    CPC分类号： C08F10/00 ,  C08F4/6565 ,  C08F4/6367 ,  C08F4/685 ,  C08F4/6365

    摘要： A catalytic ingredient for use in the polymerization of olefins comprises a carrier comprising a magnesium compound precipitated from solution and a catalytic component supported on the carrier and which is a titanium halide, vanadyl halide or vanadium halide, the catalyst being obtained by a process which comprises the steps of:

    (A) mixing (a) one or more magnesium compounds of the formulae Mg(OR¹) n (OR²) 2-n and/or MgR 3 m (OR) 2-m (in which R¹, R², R³ and R⁴ are the same or are different and each is a C₁-C₂₀ alkyl group, an allyl group, a C₃-C₂₀ cycloalkyl group or a C₅-C₂₀ aromatic group; and m and n are the same or are different and each has a value of from 0 to 2), with (c) a saturated or unsaturated monohydric alcohol of the general formula, R⁵OH (in which R⁵ is a C₁-C₂₀ alkyl group, allyl group, a C₃-C₂₀ cycloalkyl group, or a C₅-C₂₀ aromatic group), or a polyhydric alcohol having from 1 to 20 carbon atoms, for reaction in solution in the presence of (b) carbon dioxide in an inert hydrocarbon solvent, to obtain component (A);
    (B) subjecting component (A) to mixing and reaction with (d) a titanium halide of the formula TiX p (OR⁶) 4-p and/or a vanadyl halide of the formula VOX q (OR⁷) 3-q and/or a vanadium halide of the formula VX r (OR⁸) 4-r and/or a silane halide of the formula SiX s (OR⁹) 4-s (in which X is Cℓ or Br; each of R⁶, R⁷, R⁸ and R⁹ is a C₁-C₂₀ alkyl group, an allyl group or C₃-C₂₀ cycloalkyl group; each of p, r and s is an integer of from 1 to 4; and q is an integer of from 1 to 3); together with (e) a siloxane compound having an -Si-O-Si- bond alone or in admixture with a silane compound of the formula SiR 10 t  (OR¹¹) 3-t (in which R¹⁰ and R¹¹ are each a C₁-C₂₀ alkyl group, or allyl group, a C₃-C₂₀ cycloalkyl group or a C₅-C₂₀ aromatic group; and t has a value of from 0 to 3), thereby giving solid product (I);
    (C) reacting solid product (I) with (f) a saturated or unsaturated monohydric alcohol of the formula R¹²OH (in which R¹² is a C₁-C₂₀ alkyl group, allyl group, a C₃-C₂₀ cycloalkyl group or C₅-C₂₀ aromatic group) or a polyhydric alcohol having up to 20 carbon atoms and (g) a cyclic ether thereby causing dissolution and re-precipitation to give solid product (II); and
    (D) subjecting solid product (II) to further reaction with (g) component (B) consisting of a titanium halide and/or a vanadyl halide and/or a vanadium halide as defined for (d) above, thereby to give solid product (III): followed by further reaction with a mixture of component (B) and (h) an electron donor thereby obtaining solid product (IV) for use as the catalytic component.

    摘要翻译： 用于烯烃聚合的催化成分包括载体，其包含从溶液中沉淀出的镁化合物和负载在载体上的催化组分，其为卤化钛，氧化钒或卤化钒，所述催化剂通过以下方法得到： 步骤：（A）混合（a）一种或多种式Mg（OR 1）n（OR 2）2-n和/或MgR 3·m（OR）2-m的镁化合物（其中R R 1，R 2，R 3和R 4相同或不同，各自为C 1 -C 20烷基，烯丙基，C 3 -C 20环烷基或C 5 -C 20芳族 基团; m和n相同或不同并且各自具有0至2的值），其中（c）具有通式R 5 OH的饱和或不饱和一元醇（其中R 5为 >为碳原子数1〜20的多元醇，在（b）的存在下，在溶液中进行反应，可以举出碳原子数为1〜20的烷基，烯丙基，碳原子数为3〜20的环烷基， ）二氧化碳 在惰性烃溶剂中，得到组分（A）; （B）使组分（A）与（d）式TiXp（OR 6）4-p的卤化钛和/或式VOXq（OR 7）3- q和/或式VXr（OR 8）4-r的卤化钒和/或式SiXs（OR 9）4-s的硅烷卤化物（其中X为C 1或Br;各自为 的R 6，R 7，R 8和R 9是C 1 -C 20烷基，烯丙基或C 3 -C 20环烷基; p，r和s各自为 1〜4; q为1〜3的整数）; 与（e）单独具有-Si-O-Si键的硅氧烷化合物或与式SiR 10_t（OR 1 1）3-t的硅烷化合物的混合物（其中R 1， 0和R 1各自为C 1 -C 20烷基或烯丙基，C 3 -C 20环烷基或C 5 -C 20芳族基团; t为0至3的值），由此 给出固体产物（I）; （C）使固体产物（I）与（f）式R 1 OH的饱和或不饱和一元醇（其中R 1）为C 1 -C 20烷基，烯丙基 ，C 3 -C 20环烷基或C 5 -C 20芳族基团）或具有至多20个碳原子的多元醇和（g）环醚，从而引起溶解和再沉淀得到固体产物（II）; 和（D）使固体产物（II）进一步与（g）由上述（d）定义的卤化钛和/或氧化钒和/或卤化钒组成的组分（B）进一步反应，从而得到固体 产物（III）：随后与组分（B）和（h）电子供体的混合物进一步反应，从而获得用作催化组分的固体产物（IV）。

    Catalysts for polymerization of olefins
    9.
    发明公开
    Catalysts for polymerization of olefins 失效
    碳酸酯化烯烃聚合。

    公开(公告)号：EP0415704A2

    公开(公告)日：1991-03-06

    申请号：EP90309387.0

    申请日：1990-08-28

    申请人： CHISSO CORPORATION

    发明人： Tachibana, Masami ,  Uwai, Toshihiro ,  Matukawa, Tetuya ,  Hayasida, Teruaki

    IPC分类号： C08F4/637 ,  C08F4/636 ,  C08F4/685 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6565 ,  C08F4/6367 ,  C08F4/685 ,  C08F4/6365

    摘要： A catalytic ingredient for use in the polymerization of olefins comprises a carrier comprising a magnesium compound precipitated from solution and a catalytic component supported on the carrier and which is a titanium halide, vanadyl halide or vanadium halide, the catalyst being obtained by a process which comprises the steps of:

    (A) mixing (a) one or more magnesium compounds with (c) a saturated or unsaturated monohydric alcohol or a polyhydric alcohol, for reaction in solution in the presence of (b) carbon dioxide in an inert hydrocarbon solvent, to obtain component (A);
    (B) subjecting component (A) to mixing and reaction with (d) a titanium halide and/or a vanadyl halide and/or a vanadium halide and/or a silane halide together with (e) a boron compound, thereby giving solid product (I);
    (C) reacting solid product (I) with (f) a cyclic ether thereby causing dissolution and re-precipitation to give solid product (II); and
    (D) subjecting solid product (II) to further reaction with (g) component (B) consisting of a titanium halide and/or a vanadyl halide and/or a vanadium halide as defined for (d) above, thereby to give solid product (III): followed either by further reaction with a mixture of component (B) and (h) an electron donor or by reaction of (g) with the solid product (III) obtained by the reaction between the solid product (II) and (h), thereby obtaining solid product (IV) for use as the catalytic component.

    In modifications, the boron compound (e) may be replaced by a silane and/or siloxane compound; and/or an alcohol or polyhydric alcohol may be used in step (C).

    摘要翻译： 用于烯烃聚合的催化成分包括载体，其包含从溶液中沉淀出的镁化合物和负载在载体上的催化组分，其为卤化钛，氧化钒或卤化钒，所述催化剂通过以下方法得到： 步骤：（a）将（a）一种或多种镁化合物与（c）饱和或不饱和一元醇或多元醇混合，在（b）二氧化碳存在下在惰性烃溶剂中在溶液​​中反应， 得到组分（A）; （B）使组分（A）与（d）卤化钛和/或氧化钒和/或卤化钒和/或硅烷卤化物一起混合并与（e）硼化合物反应，由此得到固体产物 （一世）; （C）使固体产物（I）与（f）环醚反应，从而引起溶解和再沉淀得到固体产物（II）; 和（D）使固体产物（II）进一步与（g）由上述（d）定义的卤化钛和/或氧化钒和/或卤化钒组成的组分（B）进一步反应，从而得到固体 然后通过与组分（B）和（h）电子给体的混合物进一步反应或通过（g）与固体产物（II）之间的反应获得的固体产物（III）的反应进一步反应， 和（h），从而获得用作催化组分的固体产物（IV）。 在修饰中，硼化合物（e）可以被硅烷和/或硅氧烷化合物代替; 和/或醇或多元醇可以在步骤（C）中使用。