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    A process for producing alpha-olefin polymers
    1.
    发明公开
    A process for producing alpha-olefin polymers 失效
    Verfahren zur Herstellung von alpha-Olefinpolymeren。

    公开(公告)号：EP0284287A2

    公开(公告)日：1988-09-28

    申请号：EP88302299.8

    申请日：1988-03-16

    申请人： Chisso Corporation

    发明人： Masuda, Jun ,  Shiraishi, Takeshi ,  Komori, Nobutoshi ,  Uwai, Toshihiro

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F4/6465

    摘要： Olefins are polymerised in the presence of a catalyst comprising in combination:

    (1) a titanium trichloride composition obtained by reducing TiCℓ₄ with an organoaluminum compound or a reaction product of an organoaluminum compound with an electron donor;
    (2) an organoaluminum compound; and
    (3) an alkoxy group- or phenoxy group-containing organosilicon compound of the formula:
          R¹ n Si(OR²) 4-n
    in which R¹ is a hydrogen or halogen atom or a C₁-C₂₀ hydrocarbon radical; R² is a C₁-C₂₀ hydrocarbon radical; and n is 0, 1, 2 or 3.

    摘要翻译： 烯烃在催化剂存在下聚合，所述催化剂组合包括：（1）通过用有机铝化合物还原TiC 14或有机铝化合物与电子给体的反应产物获得的三氯化钛组合物; （2）有机铝化合物; 和（3）下式的烷氧基或苯氧基的有机硅化合物：其中R 1是氢或卤素原子或C 1 -C 20的具有下式的R 1 nSi（OR 2）4-n的有机硅化合物 烃基; R 2是C 1 -C 20烃基; 且n为0,1,2或3。

    Solid catalyst component for alpha-olefin polymerization and process for producing the same
    2.
    发明公开
    Solid catalyst component for alpha-olefin polymerization and process for producing the same 失效
    对于Olefinenpolymerisation及其制造方法的固体催化剂组分。

    公开(公告)号：EP0229413A1

    公开(公告)日：1987-07-22

    申请号：EP86202177.1

    申请日：1986-11-28

    申请人： Chisso Corporation

    发明人： Shimizu, Hiroshi ,  Sato, Akihiro ,  Uwai, Toshihiro ,  Tachibana, Masami

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  Y10S526/901 ,  Y10S526/908 ,  Y10S526/909 ,  C08F4/655 ,  C08F4/6576

    摘要： A solid catalyst component which can produce a-olefin polymers having a high stereoregularity and a good powder fluidity, stably and with a good efficiency in gas phase polymerization, particularly in gas phase copolymerization, a catalyst for a-olefin polymerization using the above solid catalyst component and a process for producing the above catalyst component, are provided,

    which solid catalyst component is characterized in that it contains titanium as an active ingredient and is in the form of hollow fine particles, and
    which process is characterized by adding a reaction product (I) of an organoaluminum compound (A) with an electron donor (B,) to TiCℓ 4 and reacting these under agitation in a baffle ratio of 0.35 or less with a power required for agitation of 2.50 KW/m 3 or less at a temperature of 0° to 70°C for a period of I to 10 hours and further reacting an electron donor (B 2 ) and an electron acceptor (E) with the resulting solid product (II) to obtain a solid product (III) i.e. the solid catalyst component.

    Catalysts for polymerization of olefins
    6.
    发明公开
    Catalysts for polymerization of olefins 失效
    用于烯烃聚合的催化剂

    公开(公告)号：EP0415704A3

    公开(公告)日：1992-04-22

    申请号：EP90309387.0

    申请日：1990-08-28

    申请人： CHISSO CORPORATION

    发明人： Tachibana, Masami ,  Uwai, Toshihiro ,  Matukawa, Tetuya ,  Hayasida, Teruaki

    IPC分类号： C08F4/637 ,  C08F4/636 ,  C08F4/685 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6565 ,  C08F4/6367 ,  C08F4/685 ,  C08F4/6365

    摘要： A catalytic ingredient for use in the polymerization of olefins comprises a carrier comprising a magnesium compound precipitated from solution and a catalytic component supported on the carrier and which is a titanium halide, vanadyl halide or vanadium halide, the catalyst being obtained by a process which comprises the steps of:
    (A) mixing (a) one or more magnesium compounds with (c) a saturated or unsaturated monohydric alcohol or a polyhydric alcohol, for reaction in solution in the presence of (b) carbon dioxide in an inert hydrocarbon solvent, to obtain component (A); (B) subjecting component (A) to mixing and reaction with (d) a titanium halide and/or a vanadyl halide and/or a vanadium halide and/or a silane halide together with (e) a boron compound, thereby giving solid product (I); (C) reacting solid product (I) with (f) a cyclic ether thereby causing dissolution and re-precipitation to give solid product (II); and (D) subjecting solid product (II) to further reaction with (g) component (B) consisting of a titanium halide and/or a vanadyl halide and/or a vanadium halide as defined for (d) above, thereby to give solid product (III): followed either by further reaction with a mixture of component (B) and (h) an electron donor or by reaction of (g) with the solid product (III) obtained by the reaction between the solid product (II) and (h), thereby obtaining solid product (IV) for use as the catalytic component. In modifications, the boron compound (e) may be replaced by a silane and/or siloxane compound; and/or an alcohol or polyhydric alcohol may be used in step (C).

    A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer
    8.
    发明公开
    A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer 无效
    一种制备固体催化剂组分的烯烃聚合和处理的烯烃聚合过程

    公开(公告)号：EP0700936A1

    公开(公告)日：1996-03-13

    申请号：EP95113524.3

    申请日：1995-08-29

    申请人： CHISSO CORPORATION

    发明人： Uwai, Toshihiro ,  Tachibana, Masami ,  Saito, Jun

    IPC分类号： C08F10/00 ,  C08F4/654

    CPC分类号： B01J19/26 ,  B01J19/18 ,  B01J19/1862 ,  B01J2208/00176 ,  B01J2219/00094 ,  C08F10/00 ,  Y10S526/901 ,  C08F4/6543

    摘要： A solid catalyst component for olefin polymerization superior in shatter resistance and narrowness of particle size distribution, is provided,
       which component is prepared by
       spraying a mixture of Mg compound with an alcohol in a molten state, in a column; cooling the inside of the column; to obtain a component (B); partly removing the alcohol from (B), to obtain a solid component (C); contacting a halogen-containing Ti compound and an electron donor with (C); to obtain (D); contacting (D) with a halogen-containing Ti compound;
       in the above process,
       specifying the composition formulas of (A), (B) and (C); specifying the X-ray diffraction spector of (C) in comparison of that of (B); and contacting (C) with a halogen-containing Ti compound and an electron donor using an aliphatic hydrocarbon of a specified b.p., in a specified temperature.

    摘要翻译： 用于烯烃聚合中的抗破碎性和粒度分布的狭窄性优良的固体催化剂组分，被提供，其成分是通过在熔融状态下在醇喷雾的Mg化合物的混合物与，在一列中制备 冷却塔的内部; 以获得组分（B）; 部分地去除从（B）的醇，得到固体成分（C）; 接触含卤素的钛化合物和（C）电子给体; 以获得（D）; 接触（D）与含卤素的Ti化合物; 在上述过程中，指定的（A）的组合物式中，（B）和（C）; 在（B）的事实的比较指定（C）的X射线衍射斯佩克特; 接触和（C）与含卤素的Ti化合物和电子给体，使用在指定的沸点的脂族烃，在规定的温度。

    A process for producing alpha-olefin polymers
    10.
    发明公开
    A process for producing alpha-olefin polymers 失效
    一种生产α-烯烃聚合物的方法

    公开(公告)号：EP0284287A3

    公开(公告)日：1990-09-19

    申请号：EP88302299.8

    申请日：1988-03-16

    申请人： Chisso Corporation

    发明人： Masuda, Jun ,  Shiraishi, Takeshi ,  Komori, Nobutoshi ,  Uwai, Toshihiro

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F4/6465

    摘要： Olefins are polymerised in the presence of a catalyst comprising in combination:
    (1) a titanium trichloride composition obtained by reducing TiCℓ₄ with an organoaluminum compound or a reaction product of an organoaluminum compound with an electron donor; (2) an organoaluminum compound; and (3) an alkoxy group- or phenoxy group-containing organosilicon compound of the formula:
          R¹ n Si(OR²) 4-n
    in which R¹ is a hydrogen or halogen atom or a C₁-C₂₀ hydrocarbon radical; R² is a C₁-C₂₀ hydrocarbon radical; and n is 0, 1, 2 or 3.