摘要:
The present application relates to a liquid crystal composition having a Δε of not less than 0 comprising at least two components, characterized by containing at least one liquid crystalline compound represented by the general formula (1):
where, R 1 represents hydrogen, fluorine, an alkyl group having 1 to 15 carbon atoms or an alkenyl group having 2 to 15 carbon atoms; each of rings A 1 , A 2 and A 3 independently represents trans -1,4-cyclohexylene group, 1,4-cyclohexenylene group, trans -1,4-silacyclohexylene group, 1,4-phenylene group, 2,3-difluoro-1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, pyrimidine-2,5-diyl group, pyridine-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydropyrane-2,5-diyl group, 1,3-dithiane-2,5-diyl group or tetrahydrothiopyrane-2,5-diyl group; X 1 represents hydrogen or fluorine; Y 1 represents hydrogen or an alkyl group having 1 to 15 carbon atoms, in which each of optional nonadjacent methylene groups (-CH 2 -) may be substituted by oxygen; 1 represents an integer from 0 to 10; in which each of optional nonadjacent methylene groups in (-CH 2 -) 1 may be substituted by oxygen; and each of m and n independently represents 0 or 1.
摘要:
An object of the invention is to provide liquid crystalline compounds having a comparatively high voltage holding ratio, high Δn and high Δε, and being excellent in miscibility with known liquid crystalline compounds at low temperatures; to provide liquid crystal compositions comprising the liquid crystalline compound; and to provide liquid crystal display devices fabricated by using the liquid crystal composition; the liquid crystalline compounds are expressed by the general formula (1) wherein R represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; n1 and n2 are independently 0, 1, or 2 provided that the sum of n1 and n2 is 1 or 2; ring A and ring B independently represent 1,4-phenylene, fluorine substituted 1,4-phenylene expressed by the formula (a) or 1,4-cyclohexylene provided that at least one of ring A and ring B is fluorine substituted 1,4-phenylene expressed by the formula (a); Za, Zb, and Zc independently represent single bond, -CH 2 CH 2 -, -COO-, -CF 2 O-, or -CH 2 CH 2 CH 2 CH 2 -; Q 1 , Q 2 , Q 3 , Q 4 , Q 5 , Q 6 , and Q 7 independently represent hydrogen atom, a halogen atom, or methyl group provided that when at least one of Za, Zb, and Zc is -CH 2 CH 2 -, Q 2 is fluorine atom; Y represents hydrogen atom, a halogen atom, or a halogenated alkyl group having 1 to 5 carbon atoms; and each atom constituting this compound may be replaced by its isotope.
摘要:
There are provided a novel compound having a quite high voltage holding ratio, low threshold voltage, quite low temperature-dependency, large Δ ε and superior compatibility with various liquid crystal materials even at a low temperature, as well as a liquid crystal composition and a liquid crystal display element obtained by using 3-fluoro-4-(1,1,2,2-tetrafluoroethoxy)phenyl = 4-(trans-4-propylcyclohexyl)benzoate is used for a liquid crystal composition and in a liquid crystal display element.
摘要:
There are provided optical compensators for liquid crystal displays containing columnar complexes consisting of substituted melamines (compound 1) and disubstituted benzoic acids (compound 2 or 3), or mixtures made thereof, having negative optical birefringence, and liquid crystal displays held between crossed polarizers and the optical compensator,
wherein n is 6 to 20 respectively in the above-described R's.
摘要:
The present invention provides a furan derivative compound having physical properties suitable as a liquid crystal display material, for example, such as 5-(4'-trans-pentyl-trans-bicyclohexyl-4-yl)-2-methylfuran, 5-(4-(4-trans-pentylcyclohexyl)phenyl)-2-ethylfuran, 5-(trans-4-propylcyclohexyl)fur-2-yl-3,4-dibromobenzene, 2-(4-trans-pentylcyclohexyl)-5-(4-trans-propylcyclohexyl)furan and 2-(4-trans-(2,3-difluoro-4-methoxyphenyl)cyclohexyl)-5-(5-trans-propyl-1,3-dioxan-2-yl)furan; a liquid crystal composition containing the said compound; and a liquid crystal display device comprising the said liquid crystal composition.
摘要:
There is provided a new polysilazane product from a specific precursor. Desired molecular weight of the polysilazane can be obtained by selecting proper molar ratio of R₁SiHX₂ and R₂R₃SiX₂ as raw materials. The polysilazane is stable during storage without gelation. The polymerization of the precursor can be carried out without gelation even at a high temperature and hence can be completed in a short time. The polysilazane can be made into ceramics fiber by spinning from a solution and subsequent firing.
摘要:
There are provided a liquid crystalline compound having a large negative Δε, low viscosity, a large K 33 /K 11 value, a small Δε/ε⊥ and mutually excellent solubility even at extremely low temperature; a liquid crystal composition prepared from a liquid crystalline compound; and a liquid crystal display device fabricated from such a liquid crystal composition. The liquid crystalline compound of the present invention is a liquid crystalline compound represented by the following general formula (1): where, R 1 represents hydrogen, fluorine, an alkyl group having 1 to 15 carbon atoms, or an alkenyl group having 2 to 15 carbon atoms; each of rings A 1 , A 2 , and A 3 independently represents trans -1,4-cyclohexylene group, 1,4-cyclohexenylene group, trans -1,4-silacyclohexylene group, 1,4-phenylene group, 2,3-difluoro-1,4-phenylene group, 2-fluoro-1,4-phenylene group, 3-fluoro-1,4-phenylene group, pyrimidine-2,5-diyl group, pyridine-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydropyrane-2,5-diyl group, 1,3-dithiane-2,5-diyl group, or tetrahydrothiopyrane-2,5-diyl group; X 1 represents hydrogen or fluorine; Y 1 represents hydrogen or an alkyl group having 1 to 15 carbon atoms; 1 represents an integer from 1 to 10; and each of m and n independently represents 0 or 1.
摘要翻译:提供具有大的负DELTAε,低粘度,大的K33 / K11值,小的DELTAε/ε正辛醛的极少的液晶化合物,即使在极低的温度下也具有相互优异的溶解性; 由液晶化合物制备的液晶组合物; 以及由这种液晶组合物制造的液晶显示装置。 本发明的液晶性化合物是下述通式(1)表示的液晶性化合物:其中,R 1表示氢,氟,碳原子数1〜15的烷基或烯基 具有2至15个碳原子的基团; 环A 1,A 2和A 3各自独立地表示反式-1,4-亚环己基,1,4-亚环己基,反-1,4-硅亚环己基,1,4-亚苯基 2,3-二氟-1,4-亚苯基,2-氟-1,4-亚苯基,3-氟-1,4-亚苯基,嘧啶-2,5-二基,吡啶-2, 四氢吡喃-2,5-二基,1,3-二噻烷-2,5-二基或四氢噻喃-2,5-二基;四氢噻吩-2,5-二基,四氢噻喃-2,5-二基,四氢噻喃-2,5-二基, X 1表示氢或氟; Y 1表示氢或具有1至15个碳原子的烷基; 1表示1〜10的整数, m和n各自独立地表示0或1。