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    COMPLEXE METALLOCENE BOROHYDRURE D UN LANTHANIDE, SYSTEME CATALYTIQUE L INCORPORANT, PROCEDE DE POLYMERISATION L UTILISANT ET COPOLYMERE ETHYLENE/BUTADIENE OBTENU PAR CE PROCEDE
    4.
    发明公开
    COMPLEXE METALLOCENE BOROHYDRURE D UN LANTHANIDE, SYSTEME CATALYTIQUE L INCORPORANT, PROCEDE DE POLYMERISATION L UTILISANT ET COPOLYMERE ETHYLENE/BUTADIENE OBTENU PAR CE PROCEDE 有权
    配合物金属茂硼氢化合物D镧系元素催化剂L化合物聚合过程催化剂乙烯共聚物乙烯/丁二烯OBTENU PAR CE程序

    公开(公告)号：EP1957506A2

    公开(公告)日：2008-08-20

    申请号：EP06818327.6

    申请日：2006-10-31

    申请人： Société de Technologie Michelin ,  Michelin Recherche et Technique S.A. ,  Total Petrochemicals France ,  Centre National de la Recherche Scientifique ,  Ecole Superieure de Chimie Physique Electronique de Lyon

    发明人： THUILLIEZ, Julien ,  BOISSON, Christophe ,  SPITZ, Roger

    IPC分类号： C07F17/00 ,  C08F4/52 ,  C08F210/12

    CPC分类号： C08F210/02 ,  C07F17/00 ,  C08F10/00 ,  Y10S526/943 ,  C08F4/52 ,  C08F236/06

    摘要： The invention relates to a borohydride metallocene complex of a lanthanide, the preparation method thereof, a catalytic system including said borohydride metallocene complex and a method for the copolymerisation of olefins using said catalytic system. The inventive complex has one of the following formulas (A and B), wherein, in formula A, two ligands Cp1 and Cp2 are linked to the lanthanide Ln, such as Nd, said ligands each consisting of a cyclopentadienyl group, and, in formula B, a ligand molecule is linked to the lanthanide Ln, said ligand molecule consisting of two cyclopentadienyl groups Cp1 and Cp2 which are interlinked by means of a bridge P having formula MR1R2, in which M is an element from column IVA, such as Si, and R1 and R2, which may be identical or different, represent an alkyl group having between 1 and 20 carbon atoms. According to the invention, L represents an alkali metal, such as Li, N represents a molecule of a complexing solvent, such as THF, x is an integer or a non-integer which is greater than 0, p is an integer which is equal to or greater than 1 and y is an integer which is equal to or greater than 0.

    摘要翻译： 本发明涉及镧系元素的硼氢化物金属茂配合物，其制备方法，包括所述硼氢化物金属茂配合物的催化体系以及使用所述催化体系进行烯烃共聚的方法。 本发明的配合物具有下式（A和B）之一，其中在式A中，两个配体Cp1和Cp2连接至镧系元素Ln，例如Nd，所述配体各自由环戊二烯基组成，并且在式 B，配体分子与镧系元素Ln连接，所述配体分子由两个环戊二烯基Cp1和Cp2组成，它们通过具有式MR1R2的桥P相互连接，其中M是来自IVA列的元素，例如Si， 并且R1和R2可以相同或不同，表示具有1至20个碳原子的烷基。 根据本发明，L表示碱金属如Li，N表示配位溶剂例如THF的分子，x是大于0的整数或非整数，p是相等的整数 等于或大于1，并且y是等于或大于0的整数。