Recovery of HF from hydrocarbon streams
    2.
    发明公开
    Recovery of HF from hydrocarbon streams 失效
    Verfahren zurZurückgewinnungvon HF ausKohlenwassersstoffströmen。

    公开(公告)号:EP0596514A1

    公开(公告)日:1994-05-11

    申请号:EP93117964.2

    申请日:1993-11-05

    申请人: CONOCO INC.

    IPC分类号: C01B7/19 C07C2/62

    摘要: Refining processes for recovering HF from acid soluble oils (ASO) generated by the HF recovery unit of an HF alkylation unit are provided. ASO containing HF is removed from the HF recovery unit and contacted with water to form a system having two phases, an aqueous HF containing phase and an organic phase. After phase separation, the aqueous HF containing phase passes through a bed of fluidized NaF crystals, where the NaF reacts with the HF to form salts having the general formula NaF·nHF. Flow of the aqueous HF containing phase to the bed continues until exhaustion of the bed, as determined by the detection of HF in the effluent. After exhaustion of the bed, the process provides for the regeneration of the bed and release of anhydrous HF which is then returned to the HF alkylation unit.

    摘要翻译: 提供了由HF烷基化单元的HF回收单元产生的酸溶性油(ASO)回收HF的精炼方法。 从HF回收单元中除去含有HF的ASO,并与水接触以形成具有两相的含HF水相和有机相的体系。 相分离后,含HF水相通过流化的NaF晶体床,其中NaF与HF反应形成具有通式NaF.nHF的盐。 通过检测流出物中的HF来确定含水HF含量相到床的流动直到床的耗尽。 在床的耗尽之后,该方法提供床的再生和无水HF的释放,然后将其返回到HF烷基化单元。