公开(公告)号：EP1123930A4

公开(公告)日：2002-05-08

申请号：EP99949349

申请日：1999-10-21

申请人： COSMO RES INST ,  COSMO OIL CO LTD

发明人： ODO JUNICHI ,  KAWAHARA NOBUKO ,  AKASHI KOICHI ,  MIYANO SOTARO ,  IKI NOBUHIKO ,  MOROHASHI NAOYA ,  TAKEYA HARUHIKO ,  MIYANARI SETSUKO ,  KUMAGAI HITOSHI

IPC分类号： B01J31/22 ,  C07C29/12 ,  C07C201/12 ,  C07C205/22 ,  C07D341/00 ,  C07F3/00 ,  C07F3/02 ,  C07F5/00 ,  C07F15/02 ,  C07F15/06 ,  C09B55/00 ,  G01N21/77 ,  G01N31/00 ,  G01N31/10

CPC分类号： B01J31/165 ,  B01J31/2204 ,  B01J31/226 ,  B01J2531/0241 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/22 ,  B01J2531/30 ,  B01J2531/38 ,  B01J2531/40 ,  B01J2531/50 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/72 ,  B01J2531/80 ,  B01J2531/842 ,  B01J2531/845 ,  C07C29/12 ,  C07D341/00 ,  G01N31/005 ,  G01N31/10

公开(公告)号：EP1123930A9

公开(公告)日：2001-11-14

申请号：EP99949349

申请日：1999-10-21

申请人： COSMO RES INST ,  COSMO OIL CO LTD

发明人： ODO JUNICHI ,  KAWAHARA NOBUKO ,  AKASHI KOICHI ,  MIYANO SOTARO ,  IKI NOBUHIKO ,  MOROHASHI NAOYA ,  TAKEYA HARUHIKO ,  MIYANARI SETSUKO ,  KUMAGAI HITOSHI

IPC分类号： B01J31/22 ,  C07C29/12 ,  C07C201/12 ,  C07C205/22 ,  C07D341/00 ,  C07F3/00 ,  C07F3/02 ,  C07F5/00 ,  C07F15/02 ,  C07F15/06 ,  C09B55/00 ,  G01N21/77 ,  G01N31/00 ,  G01N31/10 ,  C07B33/00 ,  C07B37/06 ,  C07D231/46 ,  G01N21/59

CPC分类号： B01J31/165 ,  B01J31/2204 ,  B01J31/226 ,  B01J2531/0241 ,  B01J2531/10 ,  B01J2531/20 ,  B01J2531/22 ,  B01J2531/30 ,  B01J2531/38 ,  B01J2531/40 ,  B01J2531/50 ,  B01J2531/60 ,  B01J2531/70 ,  B01J2531/72 ,  B01J2531/80 ,  B01J2531/842 ,  B01J2531/845 ,  C07C29/12 ,  C07D341/00 ,  G01N31/005 ,  G01N31/10

摘要： Provided is a metal complex which can be used in applications, such as catalysts for various chemical reactions, information/electronic materials, and the like, and which especially has a peroxidase-like activity and a high activity in phosphodiester hydrolysis. Also, provided is a novel method for analyzing a hydrogen peroxide using a metal complex having a peroxidase-like activity. A cyclic phenol sulfide metal complex is produced by bringing a cyclic phenol sulfide metal complex represented by the formula with at least one selected from metals of the Groups 8, 1A to 7A, 1B and 3B, and is used as a catalyst for oxidation by hydrogen peroxide or a catalyst for hydrolysis of phosphodiester. Furthermore, hydrogen peroxide is analyzed using the catalyst for hydrolysis. (wherein X
1 represents a hydrogen atom, a hydrocarbon group, a carboxyalkyl group, or a carbamoylalkyl group; Y
1 represents a hydrogen atom, a hydrocarbon group, a halogenated hydrocarbon group, a halogen atom, an acyl group, a hydroxyl group, a carboxyl group, an amido group, an amino group, a nitro group, a cyano group, a chlorosulfonic acid group, an alkoxysulfonyloxy group, or a sulfonic acid group; Z
1 represents Sm
1 , SO, or SO
2 ; m
1 is an integer of from 1 to 7; n
1 is an integer of from 4 to 8).