摘要:
Bulk metallic catalysts comprised of a Group VIII metal and a Group VIB metal and methods for synthesizing bulk metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic acid, such as glyoxylic acid, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要:
A catalyst composition that is the combination of or the reaction product of ingredients comprising (a) a nickel-containing compound, (b) an alkylating agent, (c) a fluorine-containing compound, and (d) a chlorine-containing compound.
摘要:
A cationic Group 3 or Lanthanide metal complex for coordination polymerization of olefins is disclosed. The precursor metal complex is stabilized by an anionic multidentate ancillary ligand and two monoanionic ligands. The ancillary ligand and the transition metal form a metallocycle having at least five primary atoms, counting any π-bound cyclopentadienyl group in the metallocycle as two primary atoms. Olefin polymerization is exemplified.
摘要:
A cyclic phenol sulfide metal complex is obtainable by bringing a cyclic phenol sulfide metal complex represented by the formula with at least one selected from metals of the Groups 8, 1A to 7A, 1B and 3B, and is used as a catalyst for hydrolysis of phosphodiester. (wherein X 1 represents a hydrogen atom, a hydrocarbon group, a carboxyalkyl group, or a carbamoylalkyl group; Y 1 represents a hydrogen atom, a hydrocarbon group, a halogenated hydrocarbon group, a halogen atom, an acyl group, a hydroxyl group, a carboxyl group, an amido group, an amino group, a nitro group, a cyano group, a chlorosulfonic acid group, an alkoxysulfonyloxy group, or a sulfonic acid group; Z 1 represents Sm 1 , SO, or SO 2 ; m 1 is an integer of from 1 to 7; n 1 is an integer of from 4 to 8).
摘要:
The invention relates to penta- and hexacoordinated ruthenium and osmium carbene catalysts, in which a sulfur, oxygen or nitrogen atom is attached to the carbene group which is coordinated with the central ruthenium or osmium atom, to their preparation and to their use for synthesizing polymers, for ring-closing metathesis of olefins and for isomerizing olefins.
摘要:
A transition metal complex represented by the formula (1) wherein M 1 is a transition metal atom of the group 4 of the periodic table of elements, A is an atom of the group 16 of the periodic table of elements, and B is an atom of the group 14 of the periodic table of elements; Cp 1 is a group having a cyclopentadiene type anionic skeleton; and X 1 , X 2 , R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each independently a hydrogen atom, halogen atom, alkyl group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, aralkyl group with the number of carbon atoms of 7-20 optionally substituted with at least one halogen atom, aryl group with the number of carbon atoms of 6-20 optionally substituted with at least one halogen atom, substituted silyl group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, alkoxy group with the number of carbon atoms of 1-20 optionally substituted with at least one halogen atom, aralkyloxy group with the number of carbon atoms of 7-20 optionally substituted with at least one halogen atom or aryloxy group with the number of carbon atoms of 6-20 optionally substituted with at least one halogen atom, or di-substituted amino group with the number of carbon atoms of 2-20, provided that R 1 , R 2 , R 3 , R 4 , R 5 and R 6 may optionally combine with each other to form a ring; a process for producing the same; an olefin polymerization catalyst containing the transition metal complex; and a process for producing olefin polymers.
摘要:
Bulk metallic catalysts comprised of a Group VIII metal and a Group VIB metal and methods for synthesizing bulk metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic acid, such as glyoxylic acid, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要:
Disclosed herein is a general method for the preparation of complexes containing a quaternary onium group in an inert ligand. Some of these complexes may be represented by formula 1: Methods for the preparation of complexes of formula 1, the preparation of intermediates and the use of complexes of formula 1 in metathesis reactions and a method for conducting an olefin metathesis reaction are also described.
摘要:
The present invention relates to a ligand compound, an organic chromium compound, a catalyst system for ethylene oligomerization, a preparation method thereof, and an ethylene oligomerization method using the same. The catalyst system for ethylene oligomerization according to the present invention is used to prepare a low-density polyethylene in one reactor by using a small amount of comonomers such as alpha-olefin or by using only ethylene without comonomers, because it maintains high catalytic activity and high alpha-olefin selectivity even though supported on a support.
摘要:
Disclosed herein is a general method for the preparation of complexes containing a quaternary onium group in an inert ligand. Some of these complexes may be represented by formula 1: Methods for the preparation of complexes of formula 1, the preparation of intermediates and the use of complexes of formula 1 in metathesis reactions and a method for conducting an olefin metathesis reaction are also described.