摘要:
A compound of formula (I): Wherein M is a transition metal; Ar1 is a 5 or 6 membered heteroaryl ring or a polycyclic heteroaromatic group; Ar2 is a polycyclic group comprising two or more aromatic or heteroaromatic rings; Ar1 and Ar2 may be linked by a direct bond or divalent linking group; L is a ligand; x is at least 1; a, b and y are each 0 or a positive integer; R1, R2, and R3 are each independently a substituent; wherein (i) Ar1 is a polycyclic heteroaromatic group or (ii) Ar1 is a 5 or 6 membered heteroaryl ring and Ar2 is a polycyclic group comprising three or more aromatic or heteroaromatic rings. Compounds have use as light-emitting compounds in organic light emitting diodes (OLEDs). Compositions and manufacturing methods comprising the claimed compounds also disclosed.
摘要:
A compound of formula (I): Wherein M is a transition metal; Ar1 is a 5 or 6 membered heteroaryl ring or a polycyclic heteroaromatic group; Ar2 is a polycyclic group comprising two or more aromatic or heteroaromatic rings; Ar1 and Ar2 may be linked by a direct bond or divalent linking group; L is a ligand; x is at least 1; a, b and y are each 0 or a positive integer; R1, R2, and R3 are each independently a substituent; wherein (i) Ar1 is a polycyclic heteroaromatic group or (ii) Ar1 is a 5 or 6 membered heteroaryl ring and Ar2 is a polycyclic group comprising three or more aromatic or heteroaromatic rings. Compounds have use as light-emitting compounds in organic light emitting diodes (OLEDs). Compositions and manufacturing methods comprising the claimed compounds also disclosed.
摘要:
A composition comprising a first material substituted with at least one group of formula (I) and a second material substituted with at least one group selected from groups of formulae (IIa) and (IIb): wherein: Sp1 and Sp2 are spacer groups; NB independently in each occurrence is a norbornene group that may be unsubstituted or substituted with one or more substituents; n1 and n2 are 0 or 1; m1 is 1 if n1 is 0 and m1 is at least 1 if n1 is 1; m2 is 1 if n2 is 0 and m2 is at least 1 if n2 is 1; Ar1 represents an aryl or heteroaryl group; R1 independently in each occurrence is H or a substituent; and * represents a point of attachment to the first or second material. The composition may be used to form a layer of an organic electronic device, for example the hole-transporting layer of an organic light-emitting device.
摘要:
A copolymer comprising a repeat unit of Formula (I) and at least one further repeat unit: Formula (I) wherein: wherein: Ar1 and Ar2 are each independently selected from aryl and heteroaryl, each of which is independently unsubstituted or substituted with one or more substituents; each R is independently a substituent; each n is independently 0, 1 or 2; each m is independently 0, 1, 2 or 3, and at least one of the repeat units of the polymer is a partially conjugating repeat unit.
摘要:
A polymer comprising units α, β, γ and δ wherein: unit α is present at 30 mole % to 60 mole % and is an optionally substituted arylene; unit β is present at 1 mole % to 30 mole % and is a unit comprising an optionally substituted fluorene; unit γ is present at 1 mole % to 40 mole % and comprises aryl substituted nitrogen, or an optionally substituted triazine; unit δ is present at 0.5 mole % to 15 mole % and comprises an iridium complex; and optionally up to 20 mole % of other units if the total of α, β, γ and δ is less than 100 mole %.
摘要:
A polymer comprising units α, β, γ and δ wherein: unit α is present at 30 mole % to 60 mole % and is an optionally substituted arylene; unit β is present at 1 mole % to 30 mole % and is a unit comprising an optionally substituted fluorene; unit γ is present at 1 mole % to 40 mole % and comprises aryl substituted nitrogen, or an optionally substituted triazine; unit δ is present at 0.5 mole % to 15 mole % and comprises an iridium complex; and optionally up to 20 mole % of other units if the total of α, β, γ and δ is less than 100 mole %.
摘要:
A light-emitting polymer comprising a light-emitting repeat unit in a backbone of the polymer, wherein the polymer has an anisotropy of no more than 0.8 and wherein a transition dipole moment of the light-emitting repeat unit is aligned with the polymer backbone.