A HYDROGENATION CATALYST FOR CONVERTING A MIXTURE COMPRISING ACETIC ACID AND ETHYL ACETATE TO ETHANOL
    2.
    发明公开
    A HYDROGENATION CATALYST FOR CONVERTING A MIXTURE COMPRISING ACETIC ACID AND ETHYL ACETATE TO ETHANOL 审中-公开
    水ER OR OR UR UM UM UNG UNG UNG UNG UNG UNG OL OL OL OL OL OL OL OL OL OL OL OL OL OL OL OL OL

    公开(公告)号:EP2812112A1

    公开(公告)日:2014-12-17

    申请号:EP12799419.2

    申请日:2012-11-27

    摘要: A hydrogenation catalyst and process using the catalyst for converting a mixture comprising acetic acid and ethyl acetate to ethanol at a first temperature, and the catalyst desorbs ethyl acetate, in the absence of hydrogen, at a second temperature that is greater than the first temperature. The catalyst has a suitable chemisorption of ethyl acetate at the first temperature in the absence of hydrogen. In one embodiment, the first temperature ranges from 125°C to 350°C and the second temperature ranges from 300°C to 600°C. The catalyst comprises one or more active metals or oxide thereof on a support that comprises tungsten or an oxide thereof. The one or more active metals are selected from the group consisting of cobalt, copper, gold, iron, nickel, palladium, platinum, iridium, osmium, rhenium, rhodium, ruthenium, tin, zinc, lanthanum, cerium, manganese, chromium, vanadium, and molybdenum.

    摘要翻译: 一种氢化催化剂和使用催化剂的方法,该催化剂在第一温度下将包含乙酸和乙酸乙酯的混合物转化为乙醇,并且催化剂在不存在氢气的情况下在大于第一温度的第二温度下解吸乙酸乙酯。 在不存在氢气的情况下,催化剂在第一温度下具有适当的乙酸乙酯化学吸附。 在一个实施方案中,第一温度为125℃至350℃,第二温度范围为300℃至600℃。催化剂在包含钨的载体上包含一种或多种活性金属或其氧化物 或其氧化物。 一种或多种活性金属选自钴,铜,金,铁,镍,钯,铂,铱,锇,铼,铑,钌,锡,锌,镧,铈,锰,铬,钒 ,和钼。