摘要:
According to the present disclosure, there is provided a method for producing a lithium difluorophosphate in which a difluorophosphate ester reacts with a lithium salt compound in a nonaqueous organic solvent without using water as a raw material in the reaction, a method for producing a difluoro phosphate ester which includes a step of allowing a dihalophosphate ester to react with a fluorinating agent having a concentration of contained hydrogen fluoride of 15 mol% or less in a nonaqueous organic solvent; lithium difluorophosphate in which a value of a relational expression (d90 - d10)/MV represented by d90 which is a particle size at which a volume cumulative distribution is 90%, d10 which is a particle size at which a volume cumulative distribution is 10%, and MV which is a volume average particle size is 10 or less; and a method for producing a nonaqueous electrolytic solution and a method for producing a nonaqueous secondary battery using the production method described above.
摘要:
Provided is an additive for a non-aqueous electrolyte solution that can exhibit high-temperature cycle properties at 50°C or more and low-temperature output properties at -20°C or less in a well-balanced manner for a non-aqueous electrolyte solution battery. The additive for a non-aqueous electrolyte solution is represented by formula [1]:
in formula [1], Z 1 to Z 4 are each a fluorine atom or are selected from alkyl groups having 1 to 10 carbon atoms, alkoxy groups having 1 to 10 carbon atoms, alkenyl groups having 2 to 10 carbon atoms, alkenyloxy groups having 2 to 10 carbon atoms, alkynyl groups having 2 to 10 carbon atoms, alkynyloxy groups having 2 to 10 carbon atoms, cycloalkyl groups having 3 to 10 carbon atoms, cycloalkoxy groups having 3 to 10 carbon atoms, cycloalkenyl groups having 3 to 10 carbon atoms, cycloalkenyloxy groups having 3 to 10 carbon atoms, aryl groups having 6 to 10 carbon atoms, and aryloxy groups having 6 to 10 carbon atoms. These organic groups may contain a fluorine atom, an oxygen atom, or an unsaturated bond, and at least one of Z 1 to Z 4 is a fluorine atom. M p+ is a proton, a metal cation, or an onium cation, and p is a cation valence.
摘要:
The present disclosure provides a nonaqueous electrolyte solution, containing: a compound represented by the specific Formula (1); a solute; and a nonaqueous organic solvent, a nonaqueous electrolyte solution battery, including: a positive electrode; a negative electrode; and the above nonaqueous electrolyte solution, and a method for producing a nonaqueous electrolyte solution battery, including: preparing the above nonaqueous electrolyte solution; and filling an empty cell including at least a positive electrode and a negative electrode with the nonaqueous electrolyte solution.
摘要:
According to a nonaqueous electrolytic solution containing: (I) at least one selected from the group consisting of a compound represented by General Formula (1) described in the specification (for example, a compound represented by the following Formula (1a)) and a compound represented by General Formula (2) (for example, a compound represented by the following Formula (2a)); (II) a solute; and (III) a nonaqueous organic solvent, a nonaqueous electrolytic solution and a nonaqueous electrolytic solution battery having a low initial resistance value, and a compound that can be suitably used in the above nonaqueous electrolytic solution can be provided;
摘要:
According to a nonaqueous electrolytic solution containing: a compound represented by the General Formula (1); a solute; and a nonaqueous organic solvent, a nonaqueous electrolytic solution battery, and a compound represented by General Formula (1), a nonaqueous electrolytic solution and a nonaqueous electrolytic solution battery having a low initial resistance value, and a compound that can be suitably used for the above nonaqueous electrolytic solution are provided,
in the General Formula (1), R 1 's each independently represent PO(R f ) 2 or SO 2 R f , R f 's each independently represent a fluorine atom, a linear alkyl group having 1 to 4 carbon atoms, or a branched alkyl group having 3 to 4 carbon atoms, and an oxygen atom may be included between a carbon atom-carbon atom bond in the alkyl group, any hydrogen atom of the alkyl group may be substituted with a fluorine atom, R 2 's each independently represent a hydrogen atom, a lithium ion, a sodium ion, a potassium ion, a linear alkyl group having 1 to 12 carbon atoms, or a branched alkyl group having 3 to 12 carbon atoms, and an oxygen atom may be included between a carbon atom-carbon atom bond in the alkyl group, any hydrogen atom of the alkyl group may be substituted with a fluorine atom, the alkyl group may contain an unsaturated bond, when R 2 represents a lithium ion, a sodium ion, or a potassium ion, a bond between a nitrogen atom and R 2 in the General Formula (1) represents an ionic bond, and n represents an integer of 0 to 3.
摘要:
Provided is a nonaqueous electrolytic solution containing a nonaqueous organic solvent, a solute, a specific silicon compound (A), a specific borate (B), and a specific imide salt (C), in which W B /W A , which is a ratio of a content W B of the borate (B) based on mass to a content W A of the silicon compound (A) based on mass, is 1.5 or more and 3 or less, and W C /W A , which is a ratio of a content W C of the imide salt (C) based on mass to a content W A of the silicon compound (A) based on mass, is 1 or more and 5 or less, and the nonaqueous electrolytic solution can exhibit an effect of reducing an absolute value of internal resistance at a low temperature and an effect of improving a battery capacity after a cycle test in a well-balanced manner.
摘要:
An electrolytic solution for a non-aqueous electrolyte battery is provided, which is capable of providing an excellent low-temperature output characteristic at -30°C or lower and an excellent cycle characteristic at high temperatures of 45°C or higher. For example, the electrolytic solution contains the following salt having a divalent imide anion.
wherein R 1 to R 3 represent a fluorine atom or an alkoxy group, for example, and M 1 and M 2 represent protons or metal cations, for example.
摘要:
The present invention provides an electrolyte solution for a non-aqueous electrolyte solution battery capable of exhibiting excellent high-temperature cycle characteristics and excellent high-temperature storage characteristics at high temperature of 60°C or above, and a non-aqueous electrolyte solution battery using the same. The electrolyte solution for a non-aqueous electrolyte solution battery of the present invention comprises at least: a non-aqueous solvent; a solute; at least one first compound represented by the following general formula (1); and at least one second compound represented by the following general formula (2).