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    Polymers having broad molecular weight distributions and methods of making the same
    1.
    发明公开
    Polymers having broad molecular weight distributions and methods of making the same 有权
    具有宽分子量分布的聚合物及其制备方法

    公开(公告)号：EP2281846A3

    公开(公告)日：2012-02-22

    申请号：EP10075408.4

    申请日：2005-03-24

    申请人： Chevron Phillips Chemical Company LP

    发明人： McDaniel, Max P. ,  Benham, Elizabeth A. ,  Secora, Steven J. ,  Jensen, Michael D. ,  Collins, Kathy S.

    IPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/69 ,  C08F4/623 ,  C08F4/22 ,  C08F4/63

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/623 ,  C08F4/24 ,  C08F4/69 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/13 ,  C08F2500/12

    摘要： Catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl (Cp) compound. The catalyst also comprises an inorganic oxide support. Methods of preparing a catalyst comprise contacting a support with chromium and with a non-transition metal Cp compound. The support can be contacted with a solution comprising the non-transition metal Cp compound prior to entry into a reaction zone. Methods of polymerizing at least one olefin include contacting the olefin with a catalyst comprising chromium and with a cocatalyst comprising a non-transition metal Cp. The polymerization can be performed in the presence of hydrogen. Using the cocatalyst in conjunction with the catalyst increases several properties of the polymers produced by this method. Polymer compositions produced by such methods have various unique properties, including a PDI greater than 30.

    摘要翻译： 用于聚合烯烃的催化剂体系包括含铬的催化剂和含有取代或未取代的非过渡金属环戊二烯基（Cp）化合物的助催化剂。 催化剂还包含无机氧化物载体。 制备催化剂的方法包括使载体与铬和非过渡金属Cp化合物接触。 载体在进入反应区之前可以与包含非过渡金属Cp化合物的溶液接触。 聚合至少一种烯烃的方法包括使烯烃与包含铬的催化剂和包含非过渡金属Cp的助催化剂接触。 聚合可以在氢存在下进行。 将助催化剂与催化剂一起使用增加了由该方法生产的聚合物的几个性质。 通过这种方法生产的聚合物组合物具有各种独特的性质，包括大于30的PDI。

    Polymers having broad molecular weight distributions and methods of making the same
    7.
    发明公开
    Polymers having broad molecular weight distributions and methods of making the same 审中-公开
    Polymere mit breiter Molekulargewichtsverteilung und deren Herstellungsverfahren

    公开(公告)号：EP2264076A1

    公开(公告)日：2010-12-22

    申请号：EP10075405.0

    申请日：2005-03-24

    申请人： Chevron Phillips Chemical Company LP

    发明人： McDaniel, Max P. ,  Benham, Elizabeth A. ,  Secora, Steven J. ,  Jensen, Michael D. ,  Collins, Kathy S.

    IPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/69 ,  C08F4/623 ,  C08F4/22 ,  C08F4/63

    CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F4/623 ,  C08F4/24 ,  C08F4/69 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/13 ,  C08F2500/12

    摘要： Catalyst systems for polymerizing olefins include a catalyst comprising chromium and a cocatalyst comprising a substituted or unsubstituted non-transition metal cyclopentadienyl (Cp) compound. The catalyst also comprises an inorganic oxide support. Methods of preparing a catalyst comprise contacting a support with chromium and with a non-transition metal Cp compound. The support can be contacted with a solution comprising the non-transition metal Cp compound prior to entry into a reaction zone. Methods of polymerizing at least one olefin include contacting the olefin with a catalyst comprising chromium and with a cocatalyst comprising a non-transition metal Cp. The polymerization can be performed in the presence of hydrogen. Using the cocatalyst in conjunction with the catalyst increases several properties of the polymers produced by this method. Polymer compositions produced by such methods have various unique properties, including a PDI greater than 30.

    摘要翻译： 用于聚合烯烃的催化剂体系包括包含铬的催化剂和包含取代或未取代的非过渡金属环戊二烯基（Cp）化合物的助催化剂。 催化剂还包含无机氧化物载体。 制备催化剂的方法包括将载体与铬和非过渡金属Cp化合物接触。 在进入反应区之前，载体可以与包含非过渡金属Cp化合物的溶液接触。 聚合至少一种烯烃的方法包括使烯烃与包含铬的催化剂和包含非过渡金属Cp的助催化剂接触。 聚合可以在氢的存在下进行。 使用助催化剂与催化剂结合增加了通过该方法生产的聚合物的几种性质。 通过这种方法生产的聚合物组合物具有各种独特的性质，包括大于30的PDI。