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    CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST HAVING SAME
    7.
    发明公开
    CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST HAVING SAME 审中-公开
    KATALYSATORBESTANDTEIL ZUR PROPYLENPOLYMERISIERUNG，HERSTELLUNGSVERFAHRENDAFÜRUND KATALYSATOR DAMIT

    公开(公告)号：EP3135699A1

    公开(公告)日：2017-03-01

    申请号：EP15782393.1

    申请日：2015-04-24

    申请人： China Petroleum&Chemical Corporation ,  Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

    发明人： WANG, Jun ,  GAO, Mingzhi ,  LIU, Haitao ,  MA, Jing ,  CHEN, Jianhua ,  CAI, Xiaoxia ,  MA, Jixing ,  LI, Changxiu ,  HU, Jianjun ,  ZHANG, Xiaofan ,  LI, Xianzhong ,  ZHANG, Zhihui ,  DUAN, Ruilin ,  YANG, Linna ,  MA, Changyou

    IPC分类号： C08F4/649 ,  C08F4/654 ,  C08F4/651 ,  C08F10/06

    CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/04 ,  C08F4/6543 ,  C08F4/6465

    摘要： The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compouns as shown in Formula I,

    in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 6 -C 30 heteroaryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl; R 1 and R 2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

    摘要翻译： 本发明公开了一种用于丙烯聚合的催化剂组分，其包括钛，镁，卤素和内电子给体A，其中所述内电子给体A选自式I中式I所示的化合物，R选自氢 羟基和取代或未取代的C 1 -C 30烃基，优选氢，羟基和取代或未取代的C 1 -C 20烷基，C 6 -C 30芳基，C 6 -C 30杂芳基，C 7 -C 30 烷基芳基和C 7 -C 30芳基烷基; R 1和R 2可以彼此相同或不同，并且选自氢和取代或未取代的C 1 -C 30烃基，优选氢和取代或未取代的C 1 -C 20烷基，C 6 -C 30 芳基，C 7 -C 30烷基芳基和C 7 -C 30芳基烷基。 根据本发明，通过使用式I所示的化合物作为内电子给体化合物进行丙烯聚合，催化剂具有较高的活性和较慢的活性延迟。 所获得的聚合物不仅具有更宽的分子量分布，而且具有高熔体指数和全同立构规整度。