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公开(公告)号：EP3135697B1
公开(公告)日：2019-08-14
申请号：EP15782847.6
申请日：2015-04-24
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： GAO, Mingzhi , WANG, Jun , LIU, Haitao , MA, Jing , CHEN, Jianhua , MA, Jixing , CAI, Xiaoxia , LI, Changxiu , HU, Jianjun , ZHANG, Xiaofan , LI, Xianzhong , ZHANG, Zhihui , DUAN, Ruilin , YANG, Linna , MA, Changyou
IPC分类号： C08F4/00 , C08F110/06 , C08F4/651
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2.发明授权SOLID CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS, CATALYST COMPRISING THE SAME AND USE THEREOF 有权用于烯烃聚合的固体催化剂组分，包含其的催化剂及其用途
公开(公告)号：EP1472293B1
公开(公告)日：2017-04-26
申请号：EP03704180.3
申请日：2003-01-30
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation
发明人： GAO, Mingzhi , LIU, Haitao , LI, Zhulan , WANG, Jun , YANG, Juxiu , LI, Tianyi , WANG, Xiaodong , LI, Changxiu , DING, Chunming
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6494 , C08F4/6492 , C08F4/6465 , C08F2500/18 , C08F2500/12 , C08F2500/15 , C08F2500/04
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3.发明授权
公开(公告)号：EP1746110B1
公开(公告)日：2015-03-11
申请号：EP05754877.8
申请日：2005-04-29
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation
发明人： GAO, Mingzhi , LIU, Haitao , LI, Tianyi , LI, Xianzhong , LI, Changxiu , LI, Jiyu , XING, Lingyan , YANG, Juxiu , MA, Jing , WANG, Xiaodong , DING, Chunmin
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/04 , C08F2500/15
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4.发明公开CATALYST COMPONENT FOR OLEFIN POLYMERIZATION REACTION AND CATALYST COMPRISING SAME 有权KATALYSATONEOMPONENTEFÜREINE OLEFINPOLYMERISIERUNGSREAKTION UND KATALYSATOR DAMIT
公开(公告)号：EP2562189A1
公开(公告)日：2013-02-27
申请号：EP11771486.5
申请日：2011-04-22
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： GAO, Mingzhi , LI, Changxiu , LIU, Haitao , ZHANG, Xiaofan , CHEN, Jianhua , MA, Jing , CAI, Xiaoxia , LI, Xianzhong , MA, Jixing
CPC分类号： C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/651
摘要： A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.
摘要翻译： 一种用于烯烃聚合的催化剂组分，包括镁，钛，卤素和电子给体，其中当二醇二酯包含一定量的具有Fischer投影配方的异构体时，电子给体选自至少一种二醇二酯化合物，如 式（II）中，催化剂的活性和立体定向性大大提高，特别是在熔体指数高的聚合物的生产中，得到的聚合物的全同立构指数大幅提高。
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5.发明公开POLYOL ESTER COMPOUNDS USEFUL IN PREPARATION OF A CATALYST FOR OLEFINS POLYMERIZATION, PROCESS FOR PREPARING THE SAME AND USE THEREOF 审中-公开一个合适的烯烃聚合催化剂POLYOLESTERVERBINDUNGEN的制备中，用于生产及其用途
公开(公告)号：EP1478617A1
公开(公告)日：2004-11-24
申请号：EP03739422.8
申请日：2003-01-30
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum &Chemical Corporation
发明人： GAO, Mingzhi , WANG, Jun , LI, Changxiu , LI, Jiyu , LI, Tianyi , LI, Xianzhong , MA, Jing , XING, Lingyan , LIU, Haitao
IPC分类号： C07C69/78 , C07C69/82 , C07C69/16 , C07C69/28 , C07D305/10 , C07C69/54 , C07C69/618 , C07C69/04 , C07C67/00 , C08F4/654
CPC分类号： C07D307/42 , C07C69/007 , C07C69/16 , C07C69/28 , C07C69/618 , C07C69/76 , C07C69/78 , C07C2603/18 , C07D307/68 , C08F110/06 , C08F4/651 , C08F2500/15 , C08F2500/04
摘要： The present application relates to polyol ester compounds, having general formula (I): R1CO-O-CR3R4-A-CR5R6-O-CO-R2 (I) wherein, R, and R2 groups, which may be identical or different, can be substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R3-R6 groups, which may be identical or different, can be selected from the group consisting of hydrogen, halogen or substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms, R1-R6 groups optionally contain one or more hetero-atoms replacing carbon, hydrogen atom or the both, said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen atom, two or more of R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring; A is a single bond or bivalent linking group with chain length between two free radicals being 1-10 atoms, wherein said bivalent linking group is selected from the group consisting of aliphatic, alicyclic and aromatic bivalent radicals, and can carry C1-C20 linear or branched substituents; one or more of carbon atom and/or hydrogen atom on the substituents can be replaced by a hetero-atom selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus, and halogen atom, and two or more said substituents on the linking group as well as above-mentioned R3-R6 groups can be linked to form saturated or unsaturated monocyclic or polycyclic ring. The compounds of formula (I) find use in preparing a catalyst for olefin polymerization.
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6.发明公开
公开(公告)号：EP3517553A1
公开(公告)日：2019-07-31
申请号：EP17852431.0
申请日：2017-09-22
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： WANG, Jun , GAO, Mingzhi , MA, Jing , LIU, Haitao , CHEN, Jianhua , CAI, Xiaoxia , MA, Jixing , HU, Jianjun , LI, Changxiu , ZHANG, Zhihui , MA, Changyou
摘要： Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high long-term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.
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公开(公告)号：EP3053935B1
公开(公告)日：2019-05-08
申请号：EP14848074.2
申请日：2014-09-28
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： LI, Changxiu , GAO, Mingzhi , LIU, Haitao , MA, Jing , CHEN, Jianhua , LI, Xianzhong , CAI, Xiaoxia , MA, Jixing , WANG, Jun , HU, Jianjun
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8.发明公开
公开(公告)号：EP3517555A1
公开(公告)日：2019-07-31
申请号：EP17852430.2
申请日：2017-09-22
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： WANG, Jun , GAO, Mingzhi , LIU, Haitao , MA, Jing , MA, Jixing , CAI, Xiaoxia , CHEN, Jianhua , HU, Jianjun , LI, Changxiu , ZHANG, Zhihui , DUAN, Ruilin , MA, Changyou
IPC分类号： C08F110/06 , C08F4/649 , C08F4/651
摘要： Disclosed is a catalyst component for olefin polymerization. The catalyst component comprises magnesium, titanium, halogen and an internal electron donor. The internal electron donor includes an imine compound with a ketone group as shown in Formula I. Disclosed further is a method of preparing the catalyst component, and a catalyst for olefin polymerization containing the catalyst component. When the catalyst is used in olefin polymerization reaction especially propene polymerization reaction, the catalyst has a high activity and a long term activity and good hydrogen response, and the obtained polymer has characteristics of an adjustable isotactic index and a relatively wide molecular weight distribution.
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公开(公告)号：EP2562189B9
公开(公告)日：2018-09-26
申请号：EP11771486.5
申请日：2011-04-22
申请人： China Petroleum & Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： GAO, Mingzhi , LI, Changxiu , LIU, Haitao , ZHANG, Xiaofan , CHEN, Jianhua , MA, Jing , CAI, Xiaoxia , LI, Xianzhong , MA, Jixing
CPC分类号： C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/651
摘要： A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially.
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10.发明公开CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST HAVING SAME 审中-公开KATALYSATORBESTANDTEIL ZUR PROPYLENPOLYMERISIERUNG，HERSTELLUNGSVERFAHRENDAFÜRUND KATALYSATOR DAMIT
公开(公告)号：EP3135699A1
公开(公告)日：2017-03-01
申请号：EP15782393.1
申请日：2015-04-24
申请人： China Petroleum&Chemical Corporation , Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
发明人： WANG, Jun , GAO, Mingzhi , LIU, Haitao , MA, Jing , CHEN, Jianhua , CAI, Xiaoxia , MA, Jixing , LI, Changxiu , HU, Jianjun , ZHANG, Xiaofan , LI, Xianzhong , ZHANG, Zhihui , DUAN, Ruilin , YANG, Linna , MA, Changyou
CPC分类号： C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F2500/04 , C08F4/6543 , C08F4/6465
摘要： The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compouns as shown in Formula I,
in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 6 -C 30 heteroaryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl; R 1 and R 2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.摘要翻译： 本发明公开了一种用于丙烯聚合的催化剂组分，其包括钛，镁，卤素和内电子给体A，其中所述内电子给体A选自式I中式I所示的化合物，R选自氢 羟基和取代或未取代的C 1 -C 30烃基，优选氢，羟基和取代或未取代的C 1 -C 20烷基，C 6 -C 30芳基，C 6 -C 30杂芳基，C 7 -C 30 烷基芳基和C 7 -C 30芳基烷基; R 1和R 2可以彼此相同或不同，并且选自氢和取代或未取代的C 1 -C 30烃基，优选氢和取代或未取代的C 1 -C 20烷基，C 6 -C 30 芳基，C 7 -C 30烷基芳基和C 7 -C 30芳基烷基。 根据本发明，通过使用式I所示的化合物作为内电子给体化合物进行丙烯聚合，催化剂具有较高的活性和较慢的活性延迟。 所获得的聚合物不仅具有更宽的分子量分布，而且具有高熔体指数和全同立构规整度。
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