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公开(公告)号：EP4151598A1
公开(公告)日：2023-03-22
申请号：EP20935270.7
申请日：2020-10-28
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , FU, Wenhua , WANG, Zhendong , YUAN, Zhiqing , TENG, Jiawei , QIAO, Jian , TAO, Weichuan
摘要： The present invention discloses a SCM-33 molecular sieve, and the preparation method therefor and the application thereof. The SCM-33 molecular sieve has a schematic chemical composition as shown in the formula "SiO 2 ·1/x XO 1.5 ·m MO 0.5 ", wherein X is a framework trivalent element, the Si/X molar ratio x is ≥ 5, M is a framework equilibrium cation, and the M/Si molar ratio is 0
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2.发明公开
公开(公告)号：EP4342875A1
公开(公告)日：2024-03-27
申请号：EP22804050.7
申请日：2022-05-20
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , LI, Xiangcheng , WANG, Zhendong , HAN, Xiao , FENG, Xinqiang , YUAN, Zhiqing , QIAO, Jian , LIU, Chuang , LAN, Dawei
摘要： The present invention discloses a biphasic solvent system for converting biomass to prepare 2,5-hexanedione and a one-pot process for catalytically converting biomass to prepare 2,5-hexanedione with said biphasic solvent system. The process comprises: contacting and reacting a biomass raw material with a hydrogenation catalyst using hydrogen gas as a hydrogen source in a heterogeneous system formed from an organic solvent, an inorganic salt and water to obtain 2,5-hexanedione; the hydrogenation catalyst comprises a hydrogenation active component and a support, wherein said support is selected from one or more of hydrophobic active carbon and graphene. The process of the present invention can achieve efficient conversion of biomass without the participation of acid catalysts, and have a very high selectivity for the product 2,5-hexanedione.
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公开(公告)号：EP4421039A1
公开(公告)日：2024-08-28
申请号：EP22882943.8
申请日：2022-10-20
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , SHAO, Shengli , QIAO, Jian , YUAN, Zhiqing , WANG, Zhendong , FU, Wenhua , TAO, Weichuan
摘要： The present invention discloses a SCM-38 molecular sieve and preparation process and use thereof. The SCM-38 molecular sieve is a phosphorus-aluminium or silicon-phosphorus-aluminium molecular sieve, the SCM-38 molecular sieve shows the following diffraction peak feature in its XRD spectrum: X-ray diffraction peaks appear at 2θ of 7.20±0.1, 10.81±0.1, 11.60±0.1, 14.32±0.1, 21.39±0.1, 21.83±0.1, 27.31±0.1, 28.72±0.1, wherein the most intense peak appears at 2θ of 7.20±0.1. The SCM-38 molecular sieve of the present invention can be used in catalysts.
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公开(公告)号：EP4421039A8
公开(公告)日：2024-10-16
申请号：EP22882943.8
申请日：2022-10-20
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , ZHAO, Shengli , QIAO, Jian , YUAN, Zhiqing , WANG, Zhendong , FU, Wenhua , TAO, Weichuan
摘要： The present invention discloses a SCM-38 molecular sieve and preparation process and use thereof. The SCM-38 molecular sieve is a phosphorus-aluminium or silicon-phosphorus-aluminium molecular sieve, the SCM-38 molecular sieve shows the following diffraction peak feature in its XRD spectrum: X-ray diffraction peaks appear at 2θ of 7.20±0.1, 10.81±0.1, 11.60±0.1, 14.32±0.1, 21.39±0.1, 21.83±0.1, 27.31±0.1, 28.72±0.1, wherein the most intense peak appears at 2θ of 7.20±0.1. The SCM-38 molecular sieve of the present invention can be used in catalysts.
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公开(公告)号：EP4342872A1
公开(公告)日：2024-03-27
申请号：EP22804051.5
申请日：2022-05-20
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , LI, Xiangcheng , WANG, Zhendong , FENG, Xinqiang , HAN, Xiao , XU, Rui , LIU, Chuang , YUAN, Zhiqing , QIAO, Jian
摘要： Disclosed is a method for preparing paraxylene by biomass conversion, comprising the following steps: (1) contacting a biomass starting material with a hydrogenation catalyst for reaction in a multiphase system formed by an organic solvent, an inorganic salt and water, in the presence of hydrogen as a hydrogen source, and separating the resulting product to obtain an organic phase comprising 2,5-hexanedione; and (2) contacting the organic phase comprising 2,5-hexanedione obtained in the step (1) and ethylene with a molecular sieve catalyst for reaction to obtain paraxylene, wherein the molecular sieve catalyst is at least one selected from the group consisting of aluminophosphate molecular sieves and SCM-14 molecular sieves. The method is simple in operation, has the advantages of high product selectivity, good catalyst stability, easy product separation, few reaction steps and short time, and can realize green and efficient conversion from biomass to pX.
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公开(公告)号：EP4197971A1
公开(公告)日：2023-06-21
申请号：EP21866019.9
申请日：2021-09-09
申请人： China Petroleum & Chemical Corporation , Shanghai Research Institute of Petrochemical Technology, SINOPEC
发明人： YANG, Weimin , QIAO, Jian , YUAN, Zhiqing , WANG, Zhendong , TENG, Jiawei , TAO, Weichuan , FU, Wenhua , LIU, Songlin
摘要： The present invention discloses a SCM-34 molecular sieve, preparation method therefor and use thereof. The SCM-34 molecular sieve comprises aluminum, phosphorus, oxygen and optionally silicon. In the XRD diffraction data of the molecular sieve, a 2θ degree of the strongest peak within the range of 5-50° is 7.59 ± 0.2. The SCM-34 molecular sieve has a new skeleton structure and can be used to prepare a metal-containing AFI type molecular sieve or an SAPO-17 molecular sieve, meeting the different needs for catalysts in the chemical production.
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