CARBOHYDRATE ROUTE TO PARA-XYLENE AND TEREPHTHALIC ACID

    公开(公告)号:EP2445855B2

    公开(公告)日:2018-06-13

    申请号:EP10792466.4

    申请日:2010-02-24

    申请人: UOP LLC

    摘要: Catalytic processes for the conversion of 2,5-dimethyl furan (DMF) to para-xylene are described. Para-xylene is a key product that is currently obtained commercially from petroleum sources. However, it has now been determined that the cycloaddition of ethylene to DMF provides an alternative route to para-xylene. Advantageously, the DMF starting material for the processes may be synthesized from carbohydrates (e.g., glucose or fructose), thereby providing a pathway that relies at least partly, if not completely, on renewable feedstocks.

    METHOD FOR PRODUCING A CONCENTRATE OF AROMATIC HYDROCARBONS FROM LIGHT ALIPHATIC HYDROCARBONS, AND INSTALLATION FOR IMPLEMENTING SAME
    9.
    发明公开
    METHOD FOR PRODUCING A CONCENTRATE OF AROMATIC HYDROCARBONS FROM LIGHT ALIPHATIC HYDROCARBONS, AND INSTALLATION FOR IMPLEMENTING SAME 审中-公开
    用于生产芳烃的由轻脂肪烃履行其浓缩液和植物

    公开(公告)号:EP3124576A1

    公开(公告)日:2017-02-01

    申请号:EP15768758.3

    申请日:2015-03-25

    申请人: NGT Global AG

    摘要: The invention relates to a method and an installation for producing a concentrate of aromatic hydrocarbons from light aliphatic hydrocarbons and from mixtures thereof with oxygenates. According to the method, an initial raw material is fed into two in-series-connected reaction units, a first unit and a second unit, with zeolite catalysts based on a pentasil group; the reaction units are distinguished through the conditions for converting the hydrocarbons to aromatic hydrocarbons; a mixture obtained following the reaction units is separated into a liquid fraction and a gas fraction, and the gas fraction is fed to the inlet of the first and second reaction unit. The method is characterized in that the gas fraction obtained following the reaction units is separated into a hydrogen-containing gas and into a broad fraction of light hydrocarbons, containing olefins, and in that the hydrogen-containing gas is fed into an oxygenate synthesis unit, in that the resultant oxygenates are fed to the inlet of the first and second reaction unit, and in that the broad fraction of light hydrocarbons, containing olefins, is fed to the inlet of the first reaction unit. The use of the present invention allows for increasing the efficiency of producing concentrates of aromatic hydrocarbons and for increasing selectivity in regard to alkyl benzoles, and specifically xylenes.

    摘要翻译: 本发明涉及一种方法和设备用于从光脂肪烃类和从它们的混合物与含氧化合物生产芳族烃的浓缩物。 。根据该方法,上初始原料被送入两个同串联连接的反应单元,第一单元和第二单元,与基于硼碳烷硅酮沸石组催化剂; 反应单元通过用于将所述烃芳族烃的条件来区分; 后获得的反应单元的混合物被分离成液体馏分和气体馏分和气体馏分被馈送到第一和第二个反应单元的入口。 该方法的特征在于,没有获得在反应单元中的气体成分分离成含氢气体和进入的轻质烃的宽馏分,含有烯烃和DASS含氢气体送入至含氧化合物合成单元, DASS DER结式的含氧化合物进料至所述第一和第二个反应单元的入口,并在管芯DASS轻烃宽馏分,含烯烃,被供给到所述第一反应部的入口。 使用本发明的允许增加生产芳族烃的浓缩物的效率和关于提高选择性烷基苯系物,并且具体地二甲苯。