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    VERFAHREN ZUR DURCHFÜHRUNG EINER GLEICHGEWICHTSREAKTION
    9.
    发明公开
    VERFAHREN ZUR DURCHFÜHRUNG EINER GLEICHGEWICHTSREAKTION 审中-公开
    VERFAHREN ZUR DURCHFHHREN EINER GLEICHGEWICHTSREAKTION

    公开(公告)号：EP1064248A1

    公开(公告)日：2001-01-03

    申请号：EP99913234.3

    申请日：1999-03-06

    申请人： Cognis Deutschland GmbH

    发明人： BLUM, Stephan ,  FALKOWSKI, Jürgen ,  VIER, Jens-Joachim ,  GUTSCHE, Bernhard ,  KAWA, Rolf ,  TESMANN, Holger

    IPC分类号： C07C67/08 ,  C07C41/50 ,  C07C69/675 ,  C07C69/704 ,  C07C69/70 ,  C07C69/36 ,  C07C69/60 ,  C07C69/80 ,  C07C69/716 ,  C07C69/72 ,  C07C69/708 ,  C07C43/303 ,  C07C43/305

    CPC分类号： C07C67/08 ,  C07B2200/07 ,  C07C41/56 ,  C07C2601/14 ,  C07C43/303 ,  C07C43/305

    摘要： The invention relates to a method for carrying out a balanced reaction, comprising the following steps: a) a low-boiling educt (E2) which is gaseous in the reaction conditions is guided through a separate, liquid, higher-boiling educt (E1) in a bubble reactor and b) unreacted educt (E2) is conveyed to a membrane module together with the product to be separated (P1), which is also in gaseous form, as feed. Said membrane module is located outside of the reactor and is suitable for vapour permeation. In said membrane module, P1 is separated off as permeate whilst E2 is recovered as retentate and returned to the reactor in a circuit until the desired quantity of educt (E1) has been converted into the target product. The method is characterised in that carbonyl compounds of formula (I) R1-(CO)¿n1?-(B)m-(CO)n2-R?2¿ are used as (E1), B representing an optionally hydroxy- and/or carboxy-substituted alk(en)yl radical with 1 to 12 carbon atoms which is also optionally interrupted by an ether oxygen, a phenyl radical or a carbonyl group, R?1 and R2¿ representing hydrogen or a hydroxyl or alkyl radical with 1 to 12 carbon atoms independently of each other or forming a saturated or unsaturated aliphatic C¿5? or C6 ring together with at least one carbonyl group, said ring being optionally substituted with C1-C4 alkyl and/or hydroxy and the sum of n1 and n2 being either 1 or 2 and m being 0 or 1, and in that aliphatic alcohols with 2 to 8 carbon atoms are used as (E2).

    摘要翻译： 本发明涉及一种进行平衡反应的方法，包括以下步骤：a）在反应条件下为气态的低沸点离子（E2）通过分开的液体，高沸点离子（E1）引导， 在气泡反应器中和b）将未反应的离子（E2）与待分离的产物（P1）一起输送到膜模块（P1），其也是气体形式，作为进料。 所述膜组件位于反应器外部，适用于蒸汽渗透。 在所述膜组件中，将P1作为渗透物分离，同时将E2作为保留物回收，并在回路中返回到反应器中，直到所需量的离析物（E1）已经转化为目标产物。 该方法的特征在于使用式（I）R 1 - （CO）n 1-（B）m - （CO）n 2 -R 2的羰基化合物作为（E1），B表示任选的羟基 - 和/或具有1至12个碳原子的羧基取代的烷（烯）基，其也任选被醚氧，苯基或羰基中断，R 1和R 2表示氢或羟基 或具有1至12个碳原子的烷基彼此独立地或与至少一个羰基一起形成饱和或不饱和的脂族C 5或C 6环，所述环任选被C 1 -C 4烷基和/或羟基取代， n1和n2为1或2，m为0或1，并且使用具有2至8个碳原子的脂族醇作为（E2）。