PRODUCTION METHOD FOR LITHIUM SULFAMATE, AND NOVEL LITHIUM SULFAMATE

    公开(公告)号:EP3778565A1

    公开(公告)日:2021-02-17

    申请号:EP19777318.7

    申请日:2019-03-11

    摘要: Provided is a method for producing a lithium sulfamate. The method for producing a lithium sulfamate includes (1) reacting a compound (1) represented by the following formula (1):

    wherein X is fluorine, chlorine, bromine, or iodine, with a compound (2) represented by the following formula (2) :

    wherein R 1 and R 2 are each individually a substituent that is:
    -H;
    a group represented by the formula: -O p -(SiR 3 2 O) n -SiR 4 3 wherein R 3 and R 4 are each individually an alkyl group in which at least one hydrogen atom is optionally replaced with a fluorine atom, an alkenyl group in which at least one hydrogen atom is optionally replaced with a fluorine atom, an alkynyl group in which at least one hydrogen atom is optionally replaced with a fluorine atom, or an aryl group in which at least one hydrogen atom is optionally replaced with a fluorine atom; n is an integer of 0 or greater; and p is 0 or 1;
    a C1-C7 alkyl group;
    a C2-C7 alkenyl group;
    a C2-C7 alkynyl group;
    a C6-C15 aryl group;
    -SO 2 X 1 wherein X 1 is -H, -F, or an alkyl group in which at least one hydrogen atom is optionally replaced with a fluorine atom;
    -SO 3 X 2 wherein X 2 is -H, -F, or an alkyl group in which at least one hydrogen atom is optionally replaced with a fluorine atom; or
    a C2-C7 hydrocarbon group that forms a cyclic structure by bonding of R 1 and R 2 , in which the cyclic structure optionally contains a multiple bond,
    the substituent optionally containing at least one bi- to hexavalent heteroatom in the structure and being a substituent in which at least one hydrogen atom is optionally replaced with a fluorine atom or a CO-C7 functional group, to obtain a compound (3) represented by the following formula (3):

    wherein R 1 and R 2 are defined as above.