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    OXYGEN-CURABLE MERCAPTOORGANOSILOXANE COMPOSITIONS CONTAINING BOTH REDOX AND IRON CARBONYL COMPOUNDS AND METHOD OF FORMING HIGHER MOLECULAR WEIGHT PRODUCTS THEREFROM.
    1.
    发明公开
    OXYGEN-CURABLE MERCAPTOORGANOSILOXANE COMPOSITIONS CONTAINING BOTH REDOX AND IRON CARBONYL COMPOUNDS AND METHOD OF FORMING HIGHER MOLECULAR WEIGHT PRODUCTS THEREFROM. 失效
    SAUERSTOFFHÄRTBAREMERCAPTOORGANOSILOXENZUSAMMENSETZUNGEN包含制造较高分子量物的氧化还原和羰基铁和方法。

    公开(公告)号：EP0041558A4

    公开(公告)日：1982-05-10

    申请号：EP81900163

    申请日：1980-11-19

    申请人： DOW CORNING

    发明人： HOMAN GARY REX ,  CHI-LONG LEE

    IPC分类号： B01J31/20 ,  C08G75/04 ,  C08K3/18 ,  C08K3/22 ,  C08K3/30 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04 ,  C08L83/08 ,  C08G77/06

    CPC分类号： C08K3/30 ,  C08K3/18 ,  C08K3/22 ,  C08K5/56 ,  C08L83/08

    摘要： Compositions, stable in the absence of oxygen, are formed by mixing the following substantially in the absence of oxygen: (A) 100 parts by weight of at least one mercapto-functional organosiloxane containing at least two mercapto-functional substituents per molecule; (B) a catalytic amount of an iron carbonyl compound catalyst selected from the group consisting of Fe(CO)5, Fe2(CO)9, Fe3(CO)12, dicyclopentadienyldiiron tetracarbonyl, butadieneiron tricarbonyl and cyclohexadieneiron tricarbonyl, preferably from 0.1 to 6 parts by weight of catalyst per 100 parts by weight of part (A); (C) optionally, at least one filler; and (D) 0.1 to 6 parts by weight per 100 parts by weight of redox compound such as copper (II) sulfate or iron (III) oxide. The compositions polymerize or cure to form higher molecular weight products upon exposure to oxygen. The use of a redox compound appears to increase the cross-link density of the cured composition and results in harder resins and more durable elastomers. An important novel feature of the redox compounds is that their use enables one to formulate compositions which cure to low-modulus elastomers possessing excellent unprimed adhesion to many common substrates such as glass, metal and concrete. Such low-modulus elastomeric compositions are very desirable for use as building sealants.

    CURABLE MERCAPTO-FUNCTIONAL ORGANOSILICON COMPOSITIONS.
    4.
    发明公开
    CURABLE MERCAPTO-FUNCTIONAL ORGANOSILICON COMPOSITIONS. 失效
    HÄRTBAREMERCAPTOFUNKTIONELLE ORGANOSILIKONZUSAMMENSETZUNGEN。

    公开(公告)号：EP0041545A4

    公开(公告)日：1982-05-10

    申请号：EP81900116

    申请日：1980-11-19

    申请人： DOW CORNING

    发明人： HOMAN GARY REX ,  CHI-LONG LEE

    IPC分类号： C08G75/04 ,  C08G75/14 ,  C08K3/18 ,  C08K5/04 ,  C08K5/56 ,  C08L83/00 ,  C08L83/04 ,  C08L83/08 ,  C08L83/10 ,  C08G77/06

    CPC分类号： C08L83/10 ,  C08G75/14 ,  C08K3/18 ,  C08K5/56 ,  C08L83/08

    摘要： Compositions which are stable in the absence of oxygen are obtained by mixing the following substantially in the absence of oxygen: (A) 100 parts by weight of an ingredient selected from either (1) at least one mercapto-functional copolymer, containing both silicon-free organic segments and organosiloxane segments or (2) a mixture of at least two different types of components selected from the following types (a) at least one copolymer as described in (A) (1) above, (b) at least one silicon-free mercapto-functional organic compound and (c) at least one mercapto-functional organosilane or organosiloxane; (B) 0-200 parts of at least one filler; and (C) a catalytic amount, preferably from 0.1 to 6 parts, of a metal carbonyl catalyst selected from the group consisting of Fe(CO)5, Fe2(CO)9, Fe3(CO)12, dicyclopentadienyldiiron tetracarbonyl, butadieneiron tricarbonyl, cyclohexadieneiron tricarbonyl, Ni(CO)4, dicyclopentadienyldinickel dicarbonyl, Mn2(CO)10, methylcyclopentadienylmanganese tricarbonyl and dicyclopentadienylcobalt dicarbonyl. Such compositions polymerize or cure to form higher molecular weight products upon exposure to oxygen at room temperature. The higher molecular weight products formed are useful as coatings, impregnants for porous materials and elastomeric sealans. Cured products possessing a combination of some of the advantages possessed by organosiloxanes and some of the advantages possessed by organic polymers are easily obtained by exposing these compositions to oxygen.

    摘要翻译： （A）100重量份的选自（1）至少一种巯基官能共聚物，同时含有硅氧烷官能团的成分， （2）选自以下类型的至少两种不同类型组分的混合物：（a）至少一种如上文（A）（1）中所述的共聚物，（b）至少一种硅 无巯基官能有机化合物和（c）至少一种巯基官能有机硅烷或有机硅氧烷; （B）0-200份至少一种填料; 和（C）催化量，优选0.1至6份选自Fe（CO）5，Fe 2（CO）9，Fe 3（CO）12，四羰基二环戊二烯基铁，三羰基丁二烯铁， Ni（CO）4，二环戊二烯基二羰基二羰基，Mn2（CO）10，三羰基甲基环戊二烯基锰和二羰基二环戊二烯基钴。 这种组合物在室温下暴露于氧气时聚合或固化以形成更高分子量的产物。 所形成的较高分子量的产物可用作涂层，用于多孔材料和弹性体密封层的浸渍剂。 具有有机硅氧烷所具有的一些优点的组合和具有有机聚合物所具有的一些优点的固化产物很容易通过将这些组合物暴露于氧气而获得。