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    Aluminum trichloride catalyzed hydrogenation of high-boiling residue from direct process
    2.
    发明公开
    Aluminum trichloride catalyzed hydrogenation of high-boiling residue from direct process 失效
    Durch Aluminumtrichlorid katalysierte Hydrierung von hochsiedendenRückständender Direktsynthese

    公开(公告)号：EP0709389A1

    公开(公告)日：1996-05-01

    申请号：EP95307516.5

    申请日：1995-10-23

    申请人： DOW CORNING CORPORATION

    发明人： Ferguson, Stephen Paul ,  Jarvis, Robert Frank Jr. ,  Naasz, Bryan Michael ,  Oltmanns, Kimberley K. ,  Warrick, Gordon L. ,  Whiteley, Darrel Leslie

    IPC分类号： C07F7/12 ,  C07F7/08

    CPC分类号： C07F7/0896 ,  C07F7/128

    摘要： A process is described for the production of monosilanes from the high-boiling residue resulting from the reaction of organohalides with silicon metalloid in a process typically referred to as the "direct process." This process comprises forming a mixture comprising an organotrihalosilane and the high-boiling residue in the presence of both hydrogen gas and a catalytic amount of aluminum trichloride. The process results in the consumption of the organotrihalosilane rather than an increase which typically occurs in processes for hydrogenation of the high-boiling residue. At least a portion of the catalytic amount of aluminum trichloride may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

    摘要翻译： 要求保护高沸点残余物转化为单硅烷的方法。 当有机卤化物与硅准金属反应时，残留物在“直接法”期间形成。 转化过程包括将残余物与式RSiX 3（I）的有机三卤硅烷混合并接触混合物。 在三氯化铝催化剂存在下，氢气为50-10,000psig。 温度 的过程是150-500℃。 R = 1-6C烷基，芳基，1-6C烷氧基，三甲基甲硅烷基或三氟丙基; 和X =卤素。