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公开(公告)号：EP4082659A1
公开(公告)日：2022-11-02
申请号：EP20957237.9
申请日：2020-10-16
发明人： ZHANG, Tao , YE, Mao , ZHANG, Jinling , XU, Shuliang , TANG, Hailong , WANG, Xiangao , ZHANG, Cheng , JIA, Jinming , WANG, Jing , LI, Hua , LI, Chenggong , LIU, Zhongmin
摘要： The present application discloses a regeneration device, a device for preparing low-carbon olefins, and a use thereof. The regeneration device includes a first regenerator and a second regenerator; a first activation zone of the first regenerator is connected to the second regenerator through a pipeline, such that a catalyst in the first activation zone is able to be delivered to the second regenerator; and the second regenerator is connected to a gas-solid separation zone of the first regenerator through a pipeline, such that a catalyst in the second regenerator is able to be delivered to the gas-solid separation zone. The regeneration device can adjust the coke content, coke content distribution, and coke species in a dimethyl ether/methanol to olefins (DMTO) catalyst to control an operation window of the DMTO catalyst, which improves the selectivity for low-carbon olefins and the atomic economy of a methanol-to-olefins (MTO) technology.
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公开(公告)号：EP3078651B1
公开(公告)日：2019-01-02
申请号：EP13898489.3
申请日：2013-12-03
发明人： LIU, Zhongmin , YE, Mao , ZHANG, Tao , HE, Changqing , WANG, Xiangao , ZHAO, Yinfeng
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公开(公告)号：EP3967400A1
公开(公告)日：2022-03-16
申请号：EP19928705.3
申请日：2019-05-10
发明人： ZHANG, Jinling , YE, Mao , LIU, Zhongmin , ZHOU, Jibin , ZHANG, Tao , WANG, Xiangao , TANG, Hailong , WANG, Jing
摘要： Disclosed is a method for partially regenerating a catalyst for methanol and/or dimethyl ether-to-olefin. The method comprises: introducing a mixed gas into a regenerated region containing a catalyst to be regenerated, and subjecting same to a partial regeneration reaction to obtain a regenerated catalyst, wherein the mixed gas contains water vapor and air; and in the regenerated catalyst, the coke content of at least part of the regenerated catalyst is greater than 1%. The method utilizes the coupling of a mixed gas of water vapor and air to activate a deactivated catalyst, selectively eliminate part of a coke deposit in the catalyst to be regenerated, and obtain a partially regenerated catalyst for methanol-to-olefin. Another aspect of the present invention is that further provided is a method for methanol and/or dimethyl ether-to-olefin by using the partially regenerated catalyst for methanol-to-olefin regenerated by means of the method.
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公开(公告)号：EP3530641A1
公开(公告)日：2019-08-28
申请号：EP16919298.6
申请日：2016-10-19
发明人： ZHANG, Tao , YE, Mao , HE, Changqing , ZHANG, Jinling , WANG, Xiangao , TANG, Hailong , JIA, Jinming , ZHAO, Yinfeng , LIU, Zhongmin
摘要： The present invention refers to a method and device for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. The main characteristics of the method lie in that: returning 70 wt.% or more of the light fractions in the generated product to a dense phase zone of a fast fluidized-bed reactor from a reactor feed distributor at the bottom-most of the fast fluidized-bed reactor to react ethylene and the oxygen-containing compounds to perform an alkylation reaction in presence of a catalyst to produce products of propylene and the like, and circulating 80 wt.% or more of the hydrocarbons with 5 or more carbons into a catalytic cracking lift pipe to perform a cracking reaction to generate a product containing propylene and C4 hydrocarbons, which is subsequently fed into a dilute phase zone of the fast fluidized-bed reactor. The method and device of the present invention improve the reaction rate of ethylene alkylation, and the unit volume production capacity of reactor is high.
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5.发明授权A PROCESS FOR STARTING UP FLUIDIZED CATALYTIC REACTION APPARATUS USED FOR PRODUCING LOWER OLEFIN 有权启动用于生产低级烯烃的流化催化反应设备的方法
公开(公告)号：EP2055690B1
公开(公告)日：2017-07-19
申请号：EP07800769.7
申请日：2007-08-23
发明人： LIU, Zhongmin , LV, Zhihui , HE, Changqing , LIU, Yu , QI, Yue , MIN, Xiaojian , WANG, Gongwei , WANG, Xiangao , ZHANG, Jinling
CPC分类号： C07C1/20 , C07C2529/85 , Y02P30/42 , C07C11/02
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6.发明授权A PROCESS FOR PRODUCING LOWER CARBON OLEFINS FROM METHANOL OR/AND DIMETHYL ETHER 有权用于生产NIEDERKOHLENSTOFFOLEFINEN由甲醇和/或二甲醚
公开(公告)号：EP2133319B1
公开(公告)日：2016-06-15
申请号：EP07785182.2
申请日：2007-07-27
发明人： QI, Yue , LIU, Zhongmin , LV, Zhihui , WANG, Hua , HE, Changqing , XU, Lei , ZHANG, Jinling , WANG, Xiangao
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7.发明公开A PROCESS FOR PRODUCING LOWER CARBON OLEFINS FROM METHANOL OR/AND DIMETHYL ETHER 有权VERFAHREN ZUR HERSTELLUNG VON NIEDERKOHLENSTOFFOLEFINEN AUS METHANOL UND / ODER DIMETHYLETHER
公开(公告)号：EP2133319A1
公开(公告)日：2009-12-16
申请号：EP07785182.2
申请日：2007-07-27
发明人： QI, Yue , LIU, Zhongmin , LV, Zhihui , WANG, Hua , HE, Changqing , XU, Lei , ZHANG, Jinling , WANG, Xiangao
摘要： The present invention provides a method for producing Lower olefin from the feed of methanol or/and dimethyl ether, characterized in that methanol or/and dimethyl ether are divided proportionally to be fed at 3 reaction zones; and the desired distribution of the olefin product is obtained by modulating the feeding ratio among the 3 reaction zones and the reaction conditions in each reaction zone.
摘要翻译： 本发明提供了一种从甲醇或/和二甲醚进料中制备低级烯烃的方法，其特征在于甲醇或/和二甲醚按比例分配以在3个反应区进料; 并且通过调节3个反应区中的进料比和每个反应区中的反应条件来获得所需的烯烃产物分布。
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8.发明公开
公开(公告)号：EP4082658A1
公开(公告)日：2022-11-02
申请号：EP20957236.1
申请日：2020-10-16
发明人： ZHANG, Tao , YE, Mao , ZHANG, Jinling , XU, Shuliang , TANG, Hailong , WANG, Xiangao , ZHANG, Cheng , JIA, Jinming , WANG, Jing , LI, Hua , LI, Chenggong , LIU, Zhongmin
摘要： The present application discloses a coke control reactor, a device for preparing low-carbon olefins from an oxygen-containing compound, and a use thereof. The coke control reactor includes a riser reactor and a bed reactor; the bed reactor includes a bed reactor shell, and the bed reactor shell encloses a reaction zone I, a transition zone, and a gas-solid separation zone I from bottom to top; a bed reactor distributor is arranged in the reaction zone I; a coke controlled catalyst delivery pipe is arranged outside the reaction zone I; an upper section of the riser reactor penetrates through a bottom of the bed reactor and is axially inserted in the bed reactor; and an outlet end of the riser reactor is located in the transition zone. The coke control reactor can control the conversion and generation of coke species in a catalyst. On the one hand, inactive large-molecule coke species remaining in a regenerated catalyst are converted into small-molecule coke species; and on the other hand, a riser reactor raw material and a bed reactor raw material can also enter the catalyst to generate highly-active small-molecule coke species to improve the selectivity for ethylene.
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公开(公告)号：EP3617178A1
公开(公告)日：2020-03-04
申请号：EP17907538.7
申请日：2017-11-24
发明人： YE, Mao , ZHANG, Tao , LIU, Zhongmin , ZHANG, Jinling , TANG, Hailong , JIA, Jinming , HE, Changqing , WANG, Xiangao , ZHANG, Cheng , LI, Hua , ZHAO, Yinfeng , LI, Chenggong
摘要： Disclosed are a turbulent fluidized bed reactor, device and method for preparing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and toluene, resolving or improving the competition problem between an MTO reaction and an alkylation reaction during the process of producing para-xylene and co-producing light olefins from methanol and/or dimethyl ether and toluene, and achieving a synergistic effect between the MTO reaction and the alkylation reaction. By controlling the mass transfer and reaction, competition between the MTO reaction and the alkylation reaction is coordinated and optimized to facilitate a synergistic effect of the two reactions, so that the conversion rate of toluene, the yield of para-xylene, and the selectivity of light olefins are increased. The turbulent fluidized bed reactor comprises a first reactor feed distributor and a plurality of second reactor feed distributors; the first reactor feed distributor and the plurality of second reactor feed distributions are sequentially arranged along the gas flow direction in a reaction zone of the turbulent fluidized bed reactor.
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10.发明公开
公开(公告)号：EP3530643A1
公开(公告)日：2019-08-28
申请号：EP16919195.4
申请日：2016-10-19
发明人： ZHANG, Tao , YE, Mao , HE, Changqing , ZHANG, Jinling , WANG, Xiangao , TANG, Hailong , JIA, Jinming , ZHAO, Yinfeng , LIU, Zhongmin
摘要： The present invention refers to a turbulent fluidized-bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. The device comprises the turbulent fluidized-bed reactor and a fluidized-bed regenerator for regenerating a catalyst. The method includes: a) feeding a raw material containing the oxygen-containing compounds from n reactor feed distributors to a reaction zone of the turbulent fluidized-bed reactor, and contacting the raw material with a catalyst, to generate a stream containing target product and a spent catalyst containing carbon; b) sending the stream discharged from the turbulent fluidized-bed reactor containing target product into a product separation system, obtaining propylene, C4 hydrocarbons, light fractions and the like after separation, returning 70 wt.% or more of the light fractions to the reaction zone of the turbulent fluidized-bed reactor from the reactor feed distributor at the bottom-most of the turbulent fluidized-bed reactor, and reacting ethylene and the oxygen-containing compounds to perform an alkylation reaction in presence of the catalyst, to produce products of propylene and the like. The method and device of the present invention improve the reaction rate of ethylene alkylation, and the unit volume production capacity of reactor is high.
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