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    METHOD FOR PREPARING Y-TYPE MOLECULAR SIEVE HAVING HIGH SILICA-ALUMINA RATIO
    1.
    发明公开
    METHOD FOR PREPARING Y-TYPE MOLECULAR SIEVE HAVING HIGH SILICA-ALUMINA RATIO 审中-公开
    制备具有高硅铝比的Y型分子筛的方法

    公开(公告)号：EP3187463A1

    公开(公告)日：2017-07-05

    申请号：EP14900724.7

    申请日：2014-12-05

    申请人： Dalian Institute Of Chemical Physics Chinese Academy of Sciences

    发明人： YUAN, Danhua ,  HE, Dawei ,  SONG, Zhijia ,  XU, Yunpeng ,  LIU, Zhongmin

    IPC分类号： C01B39/24

    CPC分类号： C01B39/24 ,  C01B39/205 ,  C01P2002/72 ,  C01P2002/86 ,  C01P2004/03

    摘要： Provided is a method for preparing a Y type molecular sieve having a high silica-to-alumina ratio, comprising: mixing deionized water, a silicon source, an aluminum source, an alkali source, and a tetraalkylammoniumcation source as a template agent to obtain an initial gel mixture; after aging the initial gel mixture at an appropriate temperature, feeding the gel mixture into a high pressure synthesis kettle for crystallization; separating a solid product, and drying to obtain the Y type molecular sieve having a high silica-to-alumina ratio. The method provides a phase-pure Y type molecular sieve having a high crystallinity, the SiO 2 /Al 2 O 3 thereof being not less than 6.

    摘要翻译： 本发明提供一种制备氧化硅铝比高的Y型分子筛的方法，包括将去离子水，硅源，铝源，碱源和四烷基铵阳离子源作为模板剂混合，得到 初始凝胶混合物; 将初始凝胶混合物在适当温度下老化后，将凝胶混合物加入高压合成釜中进行结晶; 分离固体产物，并干燥以获得具有高氧化硅/氧化铝比的Y型分子筛。 该方法提供了结晶度高的纯相Y型分子筛，其SiO2 / Al2O3不小于6。

    METHOD FOR PREPARING NAY MOLECULAR SIEVE OF HIGH SILICA-ALUMINA RATIO AND PRODUCT THEREOF
    2.
    发明公开
    METHOD FOR PREPARING NAY MOLECULAR SIEVE OF HIGH SILICA-ALUMINA RATIO AND PRODUCT THEREOF 审中-公开
    用于生产的NaY分子筛具有高硅铝-SHARE及其产品

    公开(公告)号：EP3081532A1

    公开(公告)日：2016-10-19

    申请号：EP13899055.1

    申请日：2013-12-09

    申请人： Dalian Institute Of Chemical Physics, Chinese Academy of Sciences

    发明人： YUAN, Danhua ,  DONG, Xinglong ,  XU, Yunpeng ,  LIU, Zhongmin ,  WANG, Kunyuan ,  HUANG, Wei

    IPC分类号： C01B39/24

    CPC分类号： C01B39/24

    摘要： The present invention relates to a method for preparing a NaY molecular sieve having a high silica-to-alumina ratio, wherein deionized water, a silicon source, an aluminum source, an alkali source, and ILs as a template agent are mixed to obtain an initial gel mixture; the initial gel mixture is maintained at a proper temperature and aged, then fed into a high pressure synthesis kettle for crystallization; the solid product is separated and dried, to obtain the NaY molecular sieve having a high silica-to-alumina ratio, wherein the ILs is a short-chain alkylimidazolium ionic liquid. The template agent used in the method of the invention is less volatile, and the resultant high-silicon Y molecular sieve has a high crystallinity and a silica-to-alumina ratio of 6 or more.

    METHOD FOR PREPARATION OF HIERARCHICAL TS-1 MOLECULAR SIEVE
    4.
    发明公开
    METHOD FOR PREPARATION OF HIERARCHICAL TS-1 MOLECULAR SIEVE 审中-公开

    公开(公告)号：EP3862320A1

    公开(公告)日：2021-08-11

    申请号：EP18940105.2

    申请日：2018-11-15

    申请人： Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences

    发明人： YUAN, Danhua ,  XING, Jiacheng ,  XU, Yunpeng ,  LIU, Zhongmin

    IPC分类号： C01B39/08 ,  B01J29/89 ,  C01B37/00

    摘要： The present application discloses a method for preparing a hierarchical porous TS-1 molecular sieve, which uses a silicon-titanium ester polymer as both titanium source and silicon source. In the method, silicon and titanium are uniformly connected to a same polymer, and the hydrolysis rates thereof are equivalent during hydrolysis, which can prevent TiO 2 precipitation and reduce the generation of non-framework titanium. Further, the silicon-titanium ester polymer is not only used as both silicon source and titanium source, but also can be used as mesoporous template in the synthesis process. The obtained TS-1 molecular sieve has mesoporous structure with narrow pore size distribution, which plays an important role in promoting the application of TS-1 molecular sieve in the field of catalysis.

    METHOD FOR PREPARING TS-1 MOLECULAR SIEVE WITH HIERARCHICAL PORES
    8.
    发明公开
    METHOD FOR PREPARING TS-1 MOLECULAR SIEVE WITH HIERARCHICAL PORES 审中-公开

    公开(公告)号：EP3862319A1

    公开(公告)日：2021-08-11

    申请号：EP18939988.4

    申请日：2018-11-15

    申请人： Dalian Institute of Chemical Physics, Chinese Academy of Sciences

    发明人： YUAN, Danhua ,  XING, Jiacheng ,  XU, Yunpeng ,  LIU, Zhongmin

    IPC分类号： C01B39/08 ,  B01J29/89

    摘要： The present application discloses a method for preparing a hierarchical porous TS-1 molecular sieve comprising using a silicon-titanium ester polymer as both titanium source and silicon source. In the method, silicon and titanium are uniformly connected to a same polymer, and the hydrolysis rates thereof are equivalent during hydrolysis, which can prevent TiO 2 precipitation and reduce the generation of non-framework titanium. Further, the silicon-titanium ester polymer is not only used as both silicon source and titanium source, but also can be used as a mesoporous template in the synthesis process. The obtained TS-1 molecular sieve has mesoporous structure with narrow pore size distribution.

    METHOD FOR PREPARING HIERARCHICAL POROUS TITANOSILICATE TS-1 MOLECULAR SIEVE
    9.
    发明公开
    METHOD FOR PREPARING HIERARCHICAL POROUS TITANOSILICATE TS-1 MOLECULAR SIEVE 审中-公开

    公开(公告)号：EP3862082A1

    公开(公告)日：2021-08-11

    申请号：EP18940476.7

    申请日：2018-11-15

    申请人： Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences

    发明人： YUAN, Danhua ,  XING, Jiacheng ,  XU, Yunpeng ,  LIU, Zhongmin

    IPC分类号： B01J29/89 ,  C01B39/08

    摘要： The present application discloses a method for preparing hierarchical porous titanium-silicon TS-1 molecular sieve, wherein a titanate polyester polyol is used as titanium source. In the method, titanium is connected to a polymer, which makes titanium more difficult to hydrolyze, prevent the TiO 2 precipitation and reduce the formation of non-framework titanium. In addition that such new type of the titanate polyester polyol acts as the titanium source during the synthesis process, the titanate polyester polyol can also be used as mesoporous template. Therefore, the TS-1 molecular sieve obtained by this method has mesoporous structure, which plays an important role in promoting the application of TS-1 molecular sieve in the field of catalysis.