DENTAL COMPOSITION
    3.
    发明公开
    DENTAL COMPOSITION 审中-公开
    DENTALE ZUSAMMENSETZUNG

    公开(公告)号:EP3122311A1

    公开(公告)日:2017-02-01

    申请号:EP15711503.1

    申请日:2015-03-20

    IPC分类号: A61K6/083 A61K6/00

    摘要: (i) 5 to 80 percent by weight based on the total weight of the composition of a polymerizable matrix containing polymerizable monomers; (ii) a polymerization initiator system containing (a) an alpha-diketone photoinitiator compound having a light absorption maximum in the range from 300 to 500 nm; (b) a coinitiator compound of the following formula (I): A-H (I) wherein A is a moiety of the following formula (II) R
    1 R
    2 R
    3 X (II) wherein X represents Si, Ge, or Sn and R
    1 represents a hydrogen atom, an organic moiety or a different moiety A; R
    2 and R
    3 which are independent from each other, represent an organic moiety; and (c) one or more compounds selected from the following group: (1) an iodonium compound of the following formula (III): R
    4 -l
    + -R
    5 Y
    - (III) wherein R
    4 and R
    5 which are independent from each other represent an organic moiety, and Y
    - is an anion; (2) a sulfonium compound of the following formula (IV): R
    6 R
    7 R
    8 S+ Y
    - (IV) wherein R
    6 , R
    7 and R
    8 which are independent from each other, represent an organic moiety or wherein any two of R
    6 , R
    7 and R
    8 form a cyclic structure together with the sulfur atom to which they are bound, and Y
    - is an anion; (3) a phosphonium compound of the following formula (V): R
    9 R
    10 R
    11 P
    + Y
    - (V) wherein R
    9 , R
    10 and R
    11 which are independent from each other, represent an organic moiety, and Y
    - is an anion; and (4) a pyridinium salt.

    摘要翻译: 牙科组合物,其包含(i)基于组合物的总重量为5-80重量%的含可聚合单体的可聚合基质; (ii)含有(a)光吸收最大值在300〜500nm范围内的α-二酮光引发剂化合物的聚合引发剂体系; 和(b)下式(I)的共引发剂化合物:ƒ€ƒ€ƒ€ƒ€ƒ€ƒA-H€ƒ€ƒ€ƒ€ƒ(I)其中A是 以下公式(II)的部分€ƒ€ƒ€ƒ€ƒ€ƒ€ƒR1 R 2 R 3 X€ƒ€ƒ€ƒ€ƒ(II)其中X表示Si,Ge ,或Sn和R 1表示氢原子,有机部分或不同的部分A; R 2和R 3彼此独立地表示有机部分。

    AQUEOUS DENTAL GLASS IONOMER COMPOSITION
    6.
    发明公开
    AQUEOUS DENTAL GLASS IONOMER COMPOSITION 审中-公开
    水性牙科玻璃离聚体组合物

    公开(公告)号:EP3307229A1

    公开(公告)日:2018-04-18

    申请号:EP16728697.0

    申请日:2016-06-13

    IPC分类号: A61K6/083

    摘要: The present invention relates to an aqueous dental glass ionomer composition comprising (A) a reactive particulate glass, (B) a water-soluble, polymerizable polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the polymerizable polymer has a polymer backbone and hydrolysis-stable pendant groups having one or more polymerizable carbon-carbon double bonds, wherein the polymerizable polymer is obtainable by a process comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step , wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acid group after step a) or step b), for obtaining a polymerizable polymer; (C) a hydrolysis-stable, water-soluble monomer having one polymerizable double bond and optionally a carboxylic acid group, said monomer having a molecular weight of at most 200 Da; and (D) a polymerization initiator system.

    AQUEOUS DENTAL GLASS IONOMER COMPOSITION
    7.
    发明公开

    公开(公告)号:EP3231412A2

    公开(公告)日:2017-10-18

    申请号:EP16169725.5

    申请日:2016-05-13

    IPC分类号: A61K6/083

    摘要: The present invention relates to an aqueous dental glass ionomer composition comprising
    (A) a reactive particulate glass,
    (B) a water-soluble, polymerizable polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the polymerizable polymer has a polymer backbone and pendant groups having one or more polymerizable carbon-carbon double bonds, wherein the polymerizable polymer is obtainable by a process comprising
    a) a step of polymerizing a mixture comprising
    (i) a first polymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and optionally
    (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary hydroxyl and/or amino group(s) and a second polymerizable organic moiety, for obtaining an water-soluble polymer;

    b) a step of coupling to the water-soluble polymer a compound having a polymerizable moiety and a functional group reactive with an optionally protected carboxylic acid group of repeating units derived from the first polymerizable monomer or an optionally protected hydroxyl and/or amino group of repeating units derived from the second copolymerizable monomer in the water-soluble polymer obtained in step a), wherein the optionally protected carboxylic acid group and the optionally protected hydroxyl and/or amine group are deprotected, so that polymerizable pendant groups are linked to the backbone by ester groups, urethane groups and/or amide groups,
    and, optionally, a step of deprotecting the protected carboxylic acid group after step a) or step b), for obtaining a polymerizable polymer;
    (C) a hydrolysis-stable, water-soluble monomer having a single polymerizable double bond and optionally a carboxylic acid group or hydroxyl group; and
    (D) a polymerization initiator system.

    POLYMER FOR A GLASS IONOMER CEMENT
    8.
    发明公开
    POLYMER FOR A GLASS IONOMER CEMENT 审中-公开
    聚合物的标准离子水门汀

    公开(公告)号:EP2655427A1

    公开(公告)日:2013-10-30

    申请号:EP11804499.9

    申请日:2011-12-20

    IPC分类号: C08F8/00 C08F8/46 A61K6/083

    摘要: A process for producing a water-soluble, hydrolysis-stable, polymerizable polymer, comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acid group after step (a) or step (b), for obtaining a polymerizable polymer.