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1.发明公开AQUEOUS ALKANOLAMINE SOLUTION AND PROCESS FOR THE REMOVAL OF H2S FROM GASEOUS MIXTURES 有权WÄSSRIGEALKANOLAMINLÖSUNGUND VERFAHREN ZUR ENTFERNUNG VON H2S AUS GASGEMISCHEN
公开(公告)号：EP2866919A1
公开(公告)日：2015-05-06
申请号：EP13730424.2
申请日：2013-06-06
IPC分类号： B01D53/14
CPC分类号： B01D53/1468 , B01D53/1493 , B01D2252/103 , B01D2252/20405 , B01D2252/20431 , B01D2252/20489 , C10L3/102 , C10L3/103
摘要： The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms and (ii) an acid or acid-forming material having a pKa equal to or less than 8, optionally (iii) another amino compound, and optionally (iv) a physical solvent. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.
摘要翻译： 本发明涉及用于从气体混合物中除去硫化氢的链烷醇胺水溶液。 所述链烷醇胺水溶液包含（i）具有下式的氨基化合物：R1R2NCH2CH（OH）CH2OH其中R1和R2独立地表示1至3个碳原子的低级烷基，和（ii）具有pKa相等的酸或酸形成材料 至少8，任选地（ⅲ）另一种氨基化合物，和任选地（ⅳ）物理溶剂。 此外，本发明涉及从气态混合物，优选硫化氢中除去酸性气体的方法，其包括使气态混合物与烷基醇胺水溶液接触的步骤，优选其中烷醇胺水溶液的温度等于或大于 气体混合物的实例包括天然气，合成气，尾气和炼厂气。
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公开(公告)号：EP2867345B1
公开(公告)日：2018-08-01
申请号：EP13730752.6
申请日：2013-06-06
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1462 , B01D53/1468 , B01D2252/103 , B01D2252/2023 , B01D2252/2025 , B01D2252/20405 , B01D2252/2041 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2252/504 , C10G21/20 , C10G29/20 , C10G70/00 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/143 , C10L3/102 , C10L3/103 , C10L3/104 , C10L2290/12 , C10L2290/541 , C10L2290/545
摘要： The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures containing hydrogen sulfide. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms, (ii) piperazine, and (iii) optionally a physical solvent, wherein said solution does not contain a strong acid. Further, the present invention relates to a process for removing hydrogen sulfide from a gaseous mixture containing hydrogen sulfide, and additionally other acid gases, if present, for example carbon dioxide, comprising the step of contacting the gaseous mixture contain hydrogen sulfide with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.
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3.发明授权AQUEOUS ALKANOLAMINE SOLUTION AND PROCESS FOR THE REMOVAL OF H2S FROM GASEOUS MIXTURES 有权水性烷醇胺溶液和从气相混合物中除去H2S的方法
公开(公告)号：EP2866919B1
公开(公告)日：2018-05-09
申请号：EP13730424.2
申请日：2013-06-06
IPC分类号： B01D53/14
CPC分类号： B01D53/1468 , B01D53/1493 , B01D2252/103 , B01D2252/20405 , B01D2252/20431 , B01D2252/20489 , C10L3/102 , C10L3/103
摘要： The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms and (ii) an acid or acid-forming material having a pKa equal to or less than 8, optionally (iii) another amino compound, and optionally (iv) a physical solvent. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.
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4.发明公开AQUEOUS ALKANOLAMINE ABSORBENT COMPOSITION COMPRISING PIPERAZINE FOR ENHANCED REMOVAL OF HYDROGEN SULFIDE FROM GASEOUS MIXTURES AND METHOD FOR USING THE SAME 审中-公开水性组合物ALKANOLAMINABSORBIERENDE哌嗪，以加强从GAS MIX和它们的使用方法除去硫化氢
公开(公告)号：EP2867345A1
公开(公告)日：2015-05-06
申请号：EP13730752.6
申请日：2013-06-06
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1462 , B01D53/1468 , B01D2252/103 , B01D2252/2023 , B01D2252/2025 , B01D2252/20405 , B01D2252/2041 , B01D2252/20421 , B01D2252/20426 , B01D2252/20431 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2252/504 , C10G21/20 , C10G29/20 , C10G70/00 , C10K1/003 , C10K1/004 , C10K1/005 , C10K1/143 , C10L3/102 , C10L3/103 , C10L3/104 , C10L2290/12 , C10L2290/541 , C10L2290/545
摘要： The present invention relates to an aqueous alkanolamine solution for the removal of hydrogen sulfide from gaseous mixtures containing hydrogen sulfide. The aqueous alkanolamine solution comprises (i) an amino compound with the formula: R1R2NCH2CH(OH)CH2OH wherein R1 and R2 independently represent lower alkyl groups of 1 to 3 carbon atoms, (ii) piperazine, and (iii) optionally a physical solvent, wherein said solution does not contain a strong acid. Further, the present invention relates to a process for removing hydrogen sulfide from a gaseous mixture containing hydrogen sulfide, and additionally other acid gases, if present, for example carbon dioxide, comprising the step of contacting the gaseous mixture contain hydrogen sulfide with the aqueous alkanolamine solution, preferably wherein the temperature of the aqueous alkanolamine solution is equal to or greater than 140° F. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.
摘要翻译： 本发明涉及在用于从含硫化氢的气体混合物中除去硫化氢的wässrige链烷醇胺溶液中。 水性链烷醇胺溶液包含（i）与氨基化合物与式：R1R2NCH2CH（OH）CH 2 OH，其中R1和R2独立地代表具有1-3个碳原子的低级烷基，（ⅱ）哌嗪，和（iii）任选的物理溶剂， worin所述溶液不包含强酸。 此外，本发明涉及一种用于从气体混合物中含有硫化氢除去硫化氢，并且另外其它酸性气体，如果存在的话，例如二氧化碳，包括使所述气体混合物的步骤包含具有wässrige烷醇胺硫化氢 溶液，优选worin的wässrige链烷醇胺溶液的温度等于或大于140°的气体混合物的F.实例包括天然气，合成气，尾气，和炼厂气。
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