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1.发明公开
公开(公告)号：EP3368499A1
公开(公告)日：2018-09-05
申请号：EP16766441.6
申请日：2016-09-07
CPC分类号： C07C1/043 , C07C11/04 , C07C11/06 , C07C2523/06 , C07C2523/26 , C07C2529/85 , C10G2/334 , C10G2400/20 , Y02P30/40
摘要： A process for preparing C2 and C3 olefins comprises contacting a feedstream including hydrogen, carbon monoxide, and a bifunctional catalyst in a reaction under certain specified conditions. The catalyst includes as components (1) chromium oxide and zinc oxide mixed metal oxides, and (2) a SAPO-34 molecular sieve. The resulting product of the reaction is relatively high in the target lower olefins and relatively low in less desirable products, including C2 and C3 paraffins, C4+ hydrocarbons, oxygenates, and methane, thereby reducing or eliminating the need for certain previously common and costly separations. The bifunctional catalyst as used in the inventive process also offers improvements in catalyst life in comparison with some methanol-to-olefins catalysts. The process may be carried out as a single unit operation.
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2.发明授权
公开(公告)号：EP3166912B1
公开(公告)日：2020-12-02
申请号：EP15744776.4
申请日：2015-07-08
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公开(公告)号：EP3368499B1
公开(公告)日：2019-08-07
申请号：EP16766441.6
申请日：2016-09-07
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4.发明公开CONVERSION OF CARBON MONOXIDE, CARBON DIOXIDE, OR A COMBINATION THEREOF OVER HYBRID CATALYST 审中-公开转换一氧化碳，二氧化碳或它们的组合上的复合催化剂
公开(公告)号：EP3166912A1
公开(公告)日：2017-05-17
申请号：EP15744776.4
申请日：2015-07-08
发明人： CHOJECKI, Adam , NIESKENS, Davy , DAVIDIAN, Thomas , GROENENDIJK, Peter E. , RUITENBEEK, Matthijs , FISH, Barry B. , TIRTOWIDJOJO, Max M. , MEIMA, Garmt R.
CPC分类号： C07C1/043 , B01J23/26 , B01J23/80 , B01J29/005 , B01J29/85 , B01J35/0006 , B01J35/026 , B01J37/031 , B01J37/04 , C07C1/12 , C07C2521/04 , C07C2523/06 , C07C2523/26 , C07C2523/72 , C07C2523/80 , C07C2529/70 , C07C2529/83 , C07C2529/85 , C07C9/06 , C07C9/08
摘要： A feedstream comprising hydrogen and a gas selected from carbon monoxide, carbon dioxide, or a combination thereof is converted to a product mixture containing a combination of saturated and unsaturated two carbon atom and three carbon atom hydrocarbons via contact with a mixed catalyst comprising a mixed metal oxide catalyst selected from a copper oxide, copper oxide/zinc oxide, copper oxide/alumina, copper oxide/zinc oxide/alumina catalyst, a zinc oxide/chromium oxide catalyst, or a combination thereof, in admixture with a molecular sieve catalyst having a CHA, AEI, AEL, AFI, BEA, or DDR framework type, or a combination of such molecular sieves. Exemplary molecular sieve catalysts include SAPO-34, SAPO-18, SAPO-5, and Beta. Advantages include reduced production of C1 hydrocarbons, C4 and higher hydrocarbons, or both; long catalyst lifetimes; desirable conversions; and desirable proportions of C2 and C3 paraffins.
摘要翻译： 进料流包含氢气和一氧化碳，二氧化碳，或它们的组合中选择的气体被转化为产物混合物通过与混合催化剂接触含有饱和和不饱和的两个碳原子和三个碳原子的烃的组合，其包含混合的金属 从氧化铜选定的氧化物的催化剂，氧化铜/氧化锌，氧化铜/氧化铝，氧化铜/氧化锌/氧化铝催化剂，氧化锌/氧化铬催化剂，或与具有分子筛催化剂及其组合，混合 CHA，AEI，AEL，AFI，BEA，或DDR骨架类型，或分子筛搜索的组合。 示例性的分子筛催化剂包括SAPO-34，SAPO-18，SAPO-5，和β。 优点包括降低了生产烃C1，C4和更高级的烃，或两者的; 催化剂寿命长; 理想的转换; 而C2和C3石蜡的理想比例。
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