摘要:
The present disclosure describes hybrid binary catalysts (HBCs) that can be used as engine aftertreatment catalyst compositions. The HBCs provide solutions to the challenges facing emissions control. In general, the HBCs include a porous primary catalyst and a secondary catalyst. The secondary catalyst partial coats the surfaces (e.g., the internal porous surface and/or the external surface) of the primary catalyst resulting in a hybridized composition. The synthesis of the HBCs can provide a primary catalyst whose entire surface, or portions thereof, can be coated with the secondary catalyst.
摘要:
The present disclosure describes hybrid binary catalysts (HBCs) that can be used as engine aftertreatment catalyst compositions, specifically 4-way catalyst compositions. The HBCs provide solutions to the challenges facing emissions control. In general, the HBCs include a porous primary catalyst and a secondary catalyst. The secondary catalyst partial coats the surfaces (e.g., the internal porous surface and/or the external surface) of the primary catalyst resulting in a hybridized composition. The synthesis of the HBCs can provide a primary catalyst whose entire surface, or portions thereof, can be coated with the secondary catalyst.
摘要:
A catalyst composition that comprises a non-over flocculated molecular sieve and an over flocculated molecular sieve. A method of preparing a catalyst composition that comprises a non-over flocculated molecular sieve and an over flocculated molecular sieve.
摘要:
Described are catalysts effective to abate NOx, hydrocarbons, and carbon monoxide from a gasoline engine exhaust gas. Such catalysts include a substrate having a first and second material disposed thereon, the first material effective to catalyze selective catalytic reduction of nitrogen oxides in the presence of ammonia and the second material effective to abate hydrocarbons and carbon monoxide, the first material comprising a molecular sieve promoted with copper and/or iron in a low loading, the second material comprising at least one oxide of Ni, Fe, Mn, Co, and Cu on a support selected from oxides of Ce, Ce—Zr, Zr, Mn, Pr and combinations thereof. Also described are gasoline engine exhaust gas treatment systems and methods of treating exhaust gas from a gasoline engine.
摘要:
The present application provides a method for preparing acetal carbonyl compound used as a mediate for producing ethylene glycol, which comprises a step in which a raw material acetal and a raw gas carbon monoxide go through a reactor loaded with a catalyst containing an acidic microporous silicoaluminophosphate molecular sieve, for carrying out a carbonylation reaction. In the method of the present invention, the conversion rate of the raw material acetal is high, and the selectivity of acetal carbonylation is high, and the catalyst life is long, and no additional solvent is needed in the reaction process, and the reaction condition is relatively mild, and the process is continuous, showing the potential for industrial application. Moreover, the product of acetal carbonyl compound can be used for producing ethylene glycol by hydrogenation followed by hydrolysis.
摘要:
Disclosed are stable catalysts, and methods for their use, that are capable of producing an olefin from an alkyl halide. The catalysts include a phosphorus-treated silicoalummophosphate (SAPO) having a structure of X/SAPO or X/Z-SAPO, where X includes a non-framework phosphorus and Z is one or more elements from Groups 2A, 3A, IVB, VIB, VIIB, VIII, IB of the Periodic Table, or compounds thereof comprised in the SAPO framework.
摘要:
An exhaust system (10) for a vehicular lean burn internal combustion engine (12), which system comprising a conduit (14) for carrying a flowing exhaust gas, a source of nitrogenous reductant (26), an alumino silicate small pore zeolite catalyst containing a maximum ring size of eight tetrahedral atoms having the CHA Framework Type Code and containing at least one transition metal which consists of copper and is coated on a monolith substrate disposed in a flow path of the exhaust gas and means (22, 28, 30) for metering the nitrogenous reductant from the source of nitrogenous reductant (26) into a flowing exhaust gas upstream of the aluminosilicate zeolite catalyst (20), wherein an oxidation catalyst (16) comprising at least one platinum group metal for oxidising nitrogen monoxide to nitrogen dioxide is located upstream of the means (22) for metering the nitrogenous reductant into a flowing exhaust gas.