SOLUTION PHASE PROCESSING OF POLYARYLENE SULFIDE
    1.
    发明公开
    SOLUTION PHASE PROCESSING OF POLYARYLENE SULFIDE 有权
    液相加工的聚芳

    公开(公告)号:EP2758454A1

    公开(公告)日:2014-07-30

    申请号:EP12769841.3

    申请日:2012-09-21

    IPC分类号: C08G75/02

    摘要: Provided are methods for obtaining modified polyarylene sulfide compositions having improved thermal and thermo-oxidative stability, the compositions so obtained, and articles comprising the compositions. The method comprises the steps of contacting, in the presence of a suitable solvent, a polyarylene sulfide with at least one reducing agent and at least base to form a first mixture. The reducing agent comprises zinc(0), tin(0), tin(II), bismuth (0), bismuth(III), or a combination thereof. The first mixture is heated to form a second mixture in which the polyarylene sulfide is dissolved. The polyarylene sulfide is then precipitated to obtain a modified polyarylene sulfide.