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1.发明授权HYDROCYANATION OF DIOLEFINS AND ISOMERIZATION OF NONCONJUGATED 2-ALKYL-3-MONOALKENENITRILES 失效二烯烃的氢氰化和非共轭2-烷基-3- monoalkenenitriles的ISOMIERUNG
公开(公告)号：EP1000020B1
公开(公告)日：2003-04-09
申请号：EP98935733.0
申请日：1998-07-23
发明人： FOO, Thomas , GARNER, James Michael , TAM, Wilson
IPC分类号： C07C253/10 , C07C255/03 , C07F9/145 , C07F9/144
CPC分类号： C07F9/144 , C07C253/10 , C07C253/30 , C07C255/03 , C07F9/145 , C07C255/07
摘要： Improved liquid phase process useful in the hydrocyanation of diolefinic compounds to produce nonconjugated acyclic nitriles and to the liquid phase process of isomerization of the nitriles to, among other thing, 3- and/or 4-monoalkene linear nitriles. The improvement involves conducting the process in the presence of zero-valent nickel and a mutidentate phosphite ligand.
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2.发明公开HYDROCYANATION PROCESSES AND MULTIDENTATE PHOSPHITE LIGAND AND NICKEL CATALYST COMPOSITIONS THEREFOR 失效氰化及其适用的多齿亚磷酸酯配体和催化剂组合物镍
公开(公告)号：EP1000022A1
公开(公告)日：2000-05-17
申请号：EP98937046.5
申请日：1998-07-23
IPC分类号： C07C253/10 , C07C255/03 , C07F9/145 , C07F9/6574 , B01J31/18
CPC分类号： C07F9/65746 , B01J31/185 , B01J31/28 , B01J2231/323 , B01J2531/0266 , B01J2531/847 , C07C253/10 , C07F9/145 , C07C255/04
摘要： A process for hydrocyanation of an aliphatic monoethylenically unsaturated compound, in which the ethylenic double bond is not conjugated to any other unsaturated group in the molecule, or a monoethylenically unsaturated compound in which the ethylenic double bond is conjugated to an ester group, which process uses a catalyst composition comprising a zero-valent nickel and a multidentate phosphite ligand in the presence of a Lewis acid promoter.
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