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    BISPHOSPHITVERBINDUNGEN, DEREN METALLKOMPLEXE UND VERWENDUNG DER VERBINDUNGEN UND KOMPLEXE IN DER OLEFINHYDROFORMYLIERUNG
    2.
    发明公开
    BISPHOSPHITVERBINDUNGEN, DEREN METALLKOMPLEXE UND VERWENDUNG DER VERBINDUNGEN UND KOMPLEXE IN DER OLEFINHYDROFORMYLIERUNG 有权
    二亚磷酸盐化合物，其金属络合物化合物的用途和复杂烯烃氢甲酰化

    公开(公告)号：EP1294731A1

    公开(公告)日：2003-03-26

    申请号：EP01956490.5

    申请日：2001-06-20

    申请人： Oxeno Olefinchemie GmbH

    发明人： RÖTTGER, Dirk ,  KADYROV, Renat ,  BÖRNER, Armin ,  SELENT, Detlef ,  HESS, Dieter

    IPC分类号： C07F9/6574 ,  C07F9/144 ,  C07F9/143 ,  C07F9/142 ,  C07F9/145

    CPC分类号： C07F15/0053 ,  C07C45/50 ,  C07F9/65744 ,  C07F9/65746 ,  C07F15/008 ,  C07F15/0093 ,  C07F15/065 ,  C07C47/02

    摘要： The invention relates to the bisphosphites of the general formula(I), wherein R?1, R2, R3, R4, R5, R6¿ represent H, an aliphatic, alicyclic, aliphatic-alicyclic, heterocyclic, aliphatic-heterocyclic, aromatic, aliphatic-aromatic hydrocarbon group with 1 to 50 carbon atoms, F, Cl, Br, I, -OR?7, -COR7 -CO¿2R7, -CO2M, -SR7, -SO2R?7, -SOR7, -SO¿3R7, -SO3M, -SO2NR?7R8, NR7R8, N=CR7R8, NH¿2, wherein R1 to R6 are the same or different and can be covalently linked with each other, R7, R8 represent H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon group with 1 to 25 carbon atoms, which are the same or different, M represents an alkali metal, alkaline earth metal, ammonium, phosphonium ion; Q represents a bivalent, aliphatic, alicyclic, aliphatic-alicyclic, heterocyclic, aliphatic-heterocyclic, aromatic, aliphatic-aromatic hydrocarbon group with 1 to 50 carbon atoms, W, X represent aliphatic, alicyclic, aliphatic-alicyclic, heterocyclic, aliphatic-heterocyclic, aromatic, aliphatic-aromatic hydrocarbon groups with 1 to 50 carbon atoms, which are the same or different or which are covalently linked with each other. The invention further relates to the metal complexes of said bisphosphites and to the use thereof in hydroformylation reactions.

    IP3 RECEPTOR LIGANDS
    6.
    发明公开
    IP3 RECEPTOR LIGANDS 有权
    IP3受体配体

    公开(公告)号：EP1188760A1

    公开(公告)日：2002-03-20

    申请号：EP00929862.1

    申请日：2000-05-25

    申请人： DAIICHI PHARMACEUTICAL CO., LTD. ,  Nagano, Testuo

    发明人： NAGANO, Tetsuo ,  KIKUCHI, Kazuya ,  INOUE, Takanari ,  IINO, Masamitsu ,  HIROSE, Kenzo

    IPC分类号： C07F9/144 ,  C07F9/655 ,  C07F9/6561 ,  C07D493/10 ,  A61K31/661 ,  A61K41/00 ,  A61P43/00

    CPC分类号： C07F9/6561 ,  C07F9/117 ,  C07F9/65522

    摘要： A compound represented by the general formula (I) or a salt thereof, wherein R represents a group represented by the following formula (A), (B) or (C) wherein R 1 and R 2 independently represent a C 1-6 alkyl group, R 3 represents an amino group, a mono(C 1-6 alkyl)amino group, a di(C 1-6 alkyl)amino group or a C 1-6 alkoxy group and X-represents an anion, and n represents an integer of 2 to 5. The compound or a salt is useful as a ligand of inositol-1,4,5-trisphosphate (IP 3 ) receptor.

    摘要翻译： 由通式（I）表示的化合物或其盐，其中R表示由下式（A），（B）或（C）表示的基团，其中R 1和R 2独立地表示C 1-6烷基，R 3 表示氨基，单（C 1-6烷基）氨基，二（C 1-6烷基）氨基或C 1-6烷氧基，X - 表示阴离子，n表示2〜5的整数。 该化合物或盐可用作肌醇-1,4,5-三磷酸（IP3）受体的配体。

    Method for the purification of triorganophosphites by treatment with a basic additive
    8.
    发明公开
    Method for the purification of triorganophosphites by treatment with a basic additive 有权
    一种三有机亚磷酸酯的纯化通过处理用碱性添加剂处理

    公开(公告)号：EP2395010A1

    公开(公告)日：2011-12-14

    申请号：EP11172673.3

    申请日：2007-03-09

    申请人： Invista Technologies S.A R.L.

    发明人： Ritter, Joachim C

    IPC分类号： C07F9/02 ,  C07F9/141 ,  C07F9/142 ,  C07F9/144 ,  C07F9/145 ,  C07F9/6574

    CPC分类号： C07F9/025 ,  C07F9/1412 ,  C07F9/142 ,  C07F9/144 ,  C07F9/145 ,  C07F9/65744

    摘要： The invention provides a method for separating one or more triorganophosphite components from a crude phosphite mixture containing acidic hydrolysis products, the method comprising: contacting said crude phosphite mixture with a basic additive to produce a second mixture comprising a first phase and a second phase, wherein said first phase comprises the basic additive and one or more components independently selected from the group consisting of (R 2 O)(R 3 O)POH, (R 1 O)(HO)PO(H) and H 3 PO 3 , wherein R 1 , R 2 R 3 are independently selected from the group consisting of C 1 to C 18 alkyl, C 6 to C 18 aryl and hydroxyaryl, and C 3 to C 18 cycloalkyl and hydroxyalkyl radicals, and wherein R 2 and R 3 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R 9 ; and said second phase comprises one or more triorganophosphite components independently selected from the group consisting of (R 4 O)(R 5 O)P(OR 6 ) and ((R 7 O)(R 8 O)PO) n A, wherein R 4 , R 5 , R 6 , R 7 and R 8 are independently selected from the group consisting of C 1 to C 18 alkyl, C 6 to C 18 aryl and C 3 to C 18 cycloalkyl radicals, wherein each of R 4 , R 5 and R 6 can optionally be connected to one or both of the other two directly by a chemical bond or through an intermediate divalent group R 10 , wherein R 7 and R 8 can optionally be connected to each other directly by a chemical bond or through an intermediate divalent group R 11 , wherein A is an optionally substituted or unsubstituted aliphatic, aromatic or heteroaromatic radical, and wherein n is an integer greater than 1; and R 9 , R 10 , and R 11 are independently selected from the group consisting of -O-, -S-, and -CH(R 12 )-, wherein R 12 is selected from the group consisting of H, C 6 to C 18 aryl, and C 1 to C 18 alkyl.

    摘要翻译： 本发明提供一种方法，用于从粗亚磷酸酯混合物含有酸性水解产物中分离一种或多种三有机亚磷酸酯组分，所述方法包括：用碱性添加剂接触所述粗亚磷酸酯混合物中以制备第二混合物，其包括第一相和第二相，worin 所述第一相包含的碱性添加剂和一种或多种组分选自（R 2 O）（R 3 O）POH，（R 1 O）（HO）PO（H）和H 3的PO 3，worin独立选择 R 1，R 2 R 3是unabhängig选自C1至C18烷基，C6至C18芳基和羟基芳基，和C 3至C 18环烷基和羟烷基，和worin R 2和R 3可以 任选地通过化学键在中间二价基团，R 9直接或通过彼此连接; 和所述第二相包括选自的（R 4 O）（R 5 O）P（OR 6）和（（R 7 O）（R 8 O）PO）N A，worin独立选择的一个或多个三有机亚磷酸酯组分 R 4，R 5，R 6，R 7和R 8独立地选自选自C 1至C 18烷基，C 6至C 18芳基和C 3至C 18环烷基基团中选择，worin每个R 4， R 5和R 6可任选地直接由化学键或通过中间二价基团R 10可连接到一个或两个其他两个的，worin直接通过化学键或R 7和R 8可以任选地连接到海誓山盟 通过向中间二价基团R 11，worin A是任选substituiertem奥德unsubstituiertem脂族，芳族或杂芳族基团，并且n是worin大于1的整数; 和R 9，R 10，和R 11独立地选自-O - ， - S-和-CH（R 12）的选择 - ，worin R 12选自下组：选自H，C 6至所选 C18芳基和C1至C18烷基。