PREPARATION OF AQUEOUS SOLUTIONS OF ACETOACETAMIDE
    6.
    发明授权
    PREPARATION OF AQUEOUS SOLUTIONS OF ACETOACETAMIDE 失效
    生产的水溶液乙酰乙酰胺。

    公开(公告)号:EP0556275B1

    公开(公告)日:1994-12-14

    申请号:EP91920400.8

    申请日:1991-10-16

    IPC分类号: C07C231/04

    CPC分类号: C07C231/04

    摘要: Disclosed is a process for the preparation of aqueous solutions of acetoacetamide wherein diketene and aqueous ammonia having an ammonia concentration of 6.0 to 9.0 weight percent are continuously fed to a reaction zone at rates which maintain in the reaction zone a pH of 7.0 to 8.2 and a residence time of 20 to 150 minutes while (i) maintaining the temperature of the reaction zone at 40 to 75 °C and (ii) subjecting the contents of the reaction zone to vigorous agitation. An aqueous product solution having an acetoacetamide concentration of 25 to 35 weight percent is continuously removed from the reaction zone.

    PROCESS FOR PREPARATION OF CYCLOHEXANEDICARBOXYLIC ACID
    10.
    发明授权
    PROCESS FOR PREPARATION OF CYCLOHEXANEDICARBOXYLIC ACID 失效
    用于生产环己烷

    公开(公告)号:EP0610248B1

    公开(公告)日:1996-01-10

    申请号:EP92920769.4

    申请日:1992-09-15

    IPC分类号: C07C51/36 C07C61/09

    CPC分类号: C07C51/36 C07C61/09

    摘要: A process for preparation of 1,3- or 1,4-cyclohexanedicarboxylic acid comprising: (A) preparing a solution comprised of the disodium salt of terephthalic acid or isophthalic acid and water, (B) continuously preparing the disodium salt of 1,3- or 1,4-cyclohexanedicarboxylic acid by continuously contacting the solution with hydrogen and the combination of ruthenium metal and a carbon support in a packed column, (C) preparing 1,3- or 1,4-cyclohexanedicarboxylic acid by contacting the disodium salt of 1,3- or 1,4-cyclohexanedicarboxylic acid with sulfuric acid or hydrochloric acid, and (D) recovering the 1,3- or 1,4-cyclohexanedicarboxylic acid by crystallization of the 1,3- or 1,4-cyclohexanedicarboxylic acid.