专利检索 ap:("EASTMAN CHEMICAL COMPANY") AND inv:"ELLIOT, Matthew, L." 第 1 页

1.

发明公开
PROCESS FOR THE PREPARATION OF METHYL P-VINYLBENZOATE AND P-VINYL BENZOIC ACID, AND THEIR USE IN LATEX COMPOSITIONS 审中-公开
标题翻译：方法制造甲基P-苯甲酸和P-VINYLBENZÖESÄURE及其在LATEXCOMPOSITIONEN应用

公开(公告)号：EP1140771A1

公开(公告)日：2001-10-10

申请号：EP99966180.4

申请日：1999-12-14

申请人： EASTMAN CHEMICAL COMPANY

发明人： HEIDT, Philip, C. , ELLIOT, Matthew, L. , SHARMA, Mahendra, Kumar

IPC分类号： C07C67/46 , C07C69/76 , C07C63/64 , C07C51/09 , C08L35/06

CPC分类号： C07C51/09 , C07C67/46 , C08F212/14 , C07C63/64 , C07C69/76 , C08F212/08 , C08F2220/281 , C08F220/14 , C08F2220/1825

摘要： The present invention describes a process for the direct preparation of methyl p-vinylbenzoate from methyl p-formylbenzoate using keten in the presence of potassium acetate. The chief products obtained from the process are about a five to two ratio of methyl p-vinylbenzoate to p-carbomethoxycinnamic acid. The latter may be thermally decarboxylated, especially in the presence of copper powder, to produce additional quantities of methyl p-vinylbenzoate. Methyl p-vinylbenzoate may further undergo hydrolysis to form p-vinyl benzoic acid. Both methyl p-vinyl benzoate and p-vinyl benzoic acid may be polymerized with ethylenically unsaturated monomers to form useful latex compositions of the present invention.