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    Photographic recording material for accelerated development
    1.
    发明公开
    Photographic recording material for accelerated development 审中-公开
    摄影师Aufzeichnungsmaterial zur beschleunigten Entwicklung

    公开(公告)号：EP1398664A2

    公开(公告)日：2004-03-17

    申请号：EP03077794.0

    申请日：2003-09-04

    申请人： EASTMAN KODAK COMPANY

    发明人： Keevert, John E., Jr., c/o Eastman Kodak Company ,  Singer, Stephen P., c/o Eastman Kodak Company ,  Reed, Kenneth J., c/o Eastman Kodak Company ,  Lushington, Kenneth J., c/o Eastman Kodak Company ,  Brick, Mary C., c/o Eastman Kodak Company ,  Friday, James A., c/o Eastman Kodak Company

    IPC分类号： G03C7/30

    CPC分类号： G03C7/30594 ,  G03C1/0051 ,  G03C1/04 ,  G03C7/3022 ,  G03C7/3029 ,  G03C7/30541 ,  G03C2007/3034 ,  Y10S430/156

    摘要： This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising an electron transfer agent releasing compound represented by the formula (I): CAR 1 -(L) n -ETA wherein:

    CAR 1 is a carrier moiety which is capable of releasing -(L)n-ETA on reaction with oxidized developing agent;
    L is a divalent linking group, n is 0, 1 or 2; and
    ETA is a releasable 1 -aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2.40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0.51 or less, the ETA being bonded to L or CAR 1 through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring;
    and a development accelerator releasing compound represented by the formula (II): CAR 2 -(SAM)-NX 1 -NX 2 X 3 wherein:

    CAR 2 is a carrier moiety which is capable of releasing -(SAM)-NX 1 -NX 2 X 3 on reaction with oxidized developing agent;
    SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and
    -NX 1 -NX 2 X 3 is a hydrazine group wherein X 1 , X 2 and X 3 are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X 1 , X 2 and X 3 is hydrogen.

    摘要翻译： 本发明涉及一种照相元件，其包括载体和至少两个卤化银乳剂层，其还包含由式（I）表示的电子转移剂释放化合物： CAR 1 L）n-ETA 其中：CAR 1是能够与氧化的显影剂反应释放 - （L）n-ETA的载体部分; L是二价连接基团，n是0,1或2; 并且ETA是具有大于或等于2.40的计算的对数分配系数（c log P）的可释放的1-芳基-3-吡唑烷酮电子转移剂，并且1位上的取代基的哈米特σ（对）值的总和） 芳基环为0.51以下，ETA通过2-位的氮原子或与吡唑烷酮环的3-位相连的氧键与L或CAR 1键合; 和由式（II）表示的显影促进剂释放化合物： CAR 2 - （SAM）-NX 1 -XX 2 X 3 / 其中：CAR 2是能够与氧化显影剂反应释放 - （SAM）-NX 1 -NX 2 X 3的载体部分。 SAM是与载体部分连接的银可吸收部分，与氧化显影剂反应释放; 和-NX 1 -XX 2 X 3是其中X 1，X 2和X 3独立地为氢或选自烷基，芳基，羰基或磺酰基的取代基的肼基团 条件是X 1，X 2和X 3中的至少一个是氢。

    Color photographic element exhibiting increased red speed
    2.
    发明公开
    Color photographic element exhibiting increased red speed 审中-公开
    的彩色照相元件，具有改进的灵敏度为红色

    公开(公告)号：EP1199598A2

    公开(公告)日：2002-04-24

    申请号：EP01203777.6

    申请日：2001-10-05

    申请人： EASTMAN KODAK COMPANY

    发明人： Bringley, Joseph F., c/o Eastman Kodak Company ,  Friday, James A., c/o Eastman Kodak Company ,  Vitale, Marcello, c/o Eastman Kodak Company

    IPC分类号： G03C7/30

    CPC分类号： G03C7/3029 ,  G03C2007/3032 ,  G03C2007/3037 ,  G03C2200/35

    摘要： A color photographic element containing a support bearing:

    (a) a red record comprising, in order from the support, a less and a more red light sensitive silver halide emulsion layer, each having associated therewith at least one cyan dye-forming coupler;
    (b) further from the support a green record comprising, in order from the support, a less and a more green light sensitive silver halide emulsion layer, each having associated therewith at least one magenta dye-forming coupler, and
    (c) still further from the support, a blue record comprising in order from the support, a less and a more blue light sensitive silver halide emulsion layer, each having associated therewith at least one yellow dye-forming coupler,
    wherein:
    (d) there is located below and only below the most red light sensitive layer of the red record a relatively non-light sensitive "small 3-D emulsion layer" that is substantially free of red light absorbing dye.

    Color photographic film exhibiting increased blue speed
    3.
    发明公开
    Color photographic film exhibiting increased blue speed 审中-公开
    Farbphotographischer Film mit verbesserter Empfindlichkeit im Blau

    公开(公告)号：EP1041437A1

    公开(公告)日：2000-10-04

    申请号：EP00201001.5

    申请日：2000-03-20

    申请人： EASTMAN KODAK COMPANY

    发明人： Bringley, Joseph F., c/0 Eastman Kodak Company ,  Friday, James A., c/o Eastman Kodak Company ,  Bryant, Roger A., c/o Eastman Kodak Company

    IPC分类号： G03C7/30

    CPC分类号： G03C7/3022 ,  G03C1/0051 ,  G03C7/3029 ,  G03C7/3041 ,  G03C2001/0055 ,  G03C2001/03511 ,  G03C2007/3025 ,  G03C2200/11 ,  G03C2200/19 ,  G03C2200/42

    摘要： A color photographic element is disclosed containing in its blue recording layer unit a blue light reflective layer positioned to receive light from a layer in the blue recording layer unit containing latent image forming silver halide grains of maximum sensitivity. The blue light reflective layer is free of blue absorbing dye and contains tabular silver halide grains having a thickness in the range of from 0.12 to 0.15 µm, an average aspect ratio of greater than 15, and a coating coverage of 0.4 to 1.5 g/m 2 , and formed of greater than 50 mole percent bromide, based on silver, and the layer containing latent image forming silver halide grains of maximum sensitivity contains from 0.00 to 0.5 g/m 2 of randomly oriented silver halide grains of greater than 50 mole percent bromide, based on silver, having equivalent circular diameters in the range of from 0.05 to 0.5 µm and free of adsorbed blue absorbing dye, where the combined coating coverage of the tabular silver halide grains in the blue light reflective layer and the randomly oriented silver halide grains in the layer containing latent image forming silver halide grains of maximum sensitivity is at least 0.5 g/m 2 , based on silver.

    摘要翻译： 公开了一种彩色照相元件，其蓝色记录层单元中包含蓝光反射层，该蓝色光反射层定位成接收来自蓝色记录层单元中含有最高灵敏度的潜像形成卤化银颗粒的层的光。 蓝光反射层不含蓝色吸收染料，并且含有厚度在0.12至0.15μm，平均长宽比大于15，涂层覆盖率为0.4至1.5g / m 2的片状卤化银颗粒， m 2，并且由基于银的大于50mol％的溴化物形成，并且包含潜影形成的具有最大灵敏度的卤化银颗粒的层包含0.00-0.5g / m 2的随机取向的卤化银颗粒 基于银的大于50摩尔％的溴化物，具有在0.05至0.5μm范围内的等效圆直径并且没有吸附的蓝色吸收染料，其中蓝色光反射层中的片状卤化银颗粒的组合涂层覆盖 并且含有潜影形成卤化银颗粒的层中无规取向的卤化银颗粒最大灵敏度为银，至少为0.5g / m 2。

    Color photographic element containing a fragmentable electron donor in combination with a one equivalent coupler
    5.
    发明公开
    Color photographic element containing a fragmentable electron donor in combination with a one equivalent coupler 审中-公开
    含在组合的裂解电子给体用1当量的成色剂的彩色照相元件

    公开(公告)号：EP1111448A1

    公开(公告)日：2001-06-27

    申请号：EP00204390.9

    申请日：2000-12-08

    申请人： EASTMAN KODAK COMPANY

    发明人： Pepe, Joseph Philip, c/o Eastman Kodak Company ,  Hansen, Jeffrey Christen, c/o Eastman Kodak Comp. ,  Friday, James A., c/o Eastman Kodak Company ,  Muenter, Annabel Adams, c/o Eastman Kodak Company ,  Southby, David Thomas, c/o Eastman Kodak Company

    IPC分类号： G03C1/10 ,  G03C1/12 ,  G03C7/305 ,  G03C7/392

    CPC分类号： G03C1/0051 ,  G03C1/04 ,  G03C1/10 ,  G03C1/12 ,  G03C7/3022 ,  G03C7/30511 ,  G03C7/30547 ,  G03C7/392 ,  G03C2200/24 ,  Y10S430/156

    摘要： This invention provides a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises large tabular grains having an average equivalent circular diameter of greater than 3 µm and contains a one equivalent image dye-forming coupler and a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y'; wherein
       X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is covalently linked directly or indirectly to X, and wherein:

    1) X-Y' has an oxidation potential between 0 and about 1.4V; and
    2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X • and the leaving fragment Y'; and, optionally,
    3) the radical X • has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).

    摘要翻译： 本发明提供了一种多色照相材料包括承载青色染料成像单元，其包括具有与至少一个青色成色剂相关联的有至少一个感红卤化银乳剂层，品红色染料成像单元，包括 具有与至少一种形成品红染料的成色剂，黄色染料成像单元，包括至少一层感蓝的卤化银乳剂层与至少一种形成黄色染料的成色剂相关联的存在相关联的至少一个感绿卤化银乳剂层有 ，所述乳液层中的至少worin一个包括具有上的大于3微米的平均等效圆直径大的片状颗粒，并含有一个当量的图像形成染料的成色剂和下式的片段能够给电子化合物：XY“或化合物 含有式-X-Y“的一个部分; worin X是电子给体部分，Y“是离去质子H或离去基团Y，条件做如果Y”是质子，碱，β< - >，共价直接或间接连接到X，和 大约为1）XY“具有0和1.4 V的氧化电势; worin 和2）X-Y的氧化形式“下进了键裂反应，给出游离基X <•>和离去片段Y”; 和，任选地，3）基团X <•>有氧化电位≤-0.7V（即，等于或大于约-0.7V更负）。

    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound
    6.
    发明公开
    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound 审中-公开
    含有增强速度结合化合物与释放电子传输化合物的化合物的彩色照相元件

    公开(公告)号：EP1199600A2

    公开(公告)日：2002-04-24

    申请号：EP01203776.8

    申请日：2001-10-05

    申请人： EASTMAN KODAK COMPANY

    发明人： Bringley, Joseph F., c/o Eastman Kodak Company ,  Friday, James A., c/o Eastman Kodak Company ,  Singer, Stephen Paul, c/o Eastman Kodak Company ,  Vitale, Marcello, c/o Eastman Kodak Company

    IPC分类号： G03C7/392

    CPC分类号： G03C7/3924 ,  G03C7/3005 ,  G03C7/30558 ,  Y10S430/156

    摘要： Disclosed is a color silver halide photographic element comprising a support bearing:

    (1) a light sensitive silver halide emulsion layer;
    (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and
    (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a ClogP of at least 2.40. The invention provides improved light sensitivity.

    摘要翻译： 公开了包括支撑轴承的彩色卤化银照相元件：（1）一个光敏卤化银乳剂层; （2）氮杂环与最少三个直原子并不与氧化的显影剂反应的，不含有游离硫醇的取代基，并且具有足以增加与没有化合物，所述相同的元件，在所述元件的照相速度的ClogP 位于任一杂环化合物，所述光敏感层中或与其相邻的层; 和（3）在ETARC或邻近所述光敏感卤化银乳剂层，确实的版本中，在与氧化的显影剂反应，电子具有至少2:40的的ClogP转移剂。 本发明提供了改进的光灵敏度。

    Fragmentable electron donor compounds in combination with high bromide tabular grain emulsions
    8.
    发明公开
    Fragmentable electron donor compounds in combination with high bromide tabular grain emulsions 审中-公开
    v ination v alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt alt

    公开(公告)号：EP1022613A2

    公开(公告)日：2000-07-26

    申请号：EP00200120.4

    申请日：2000-01-13

    申请人： EASTMAN KODAK COMPANY

    发明人： Friday, James A., c/o Eastman Kodak Company ,  Bryant, Roger A., c/o Eastman Kodak Company ,  Muenter, Annabel A., c/o Eastman Kodak Company ,  Lenhard, Jerome R., c/o Eastman Kodak Company

    IPC分类号： G03C7/30 ,  G03C1/10 ,  G03C7/392

    CPC分类号： G03C1/10 ,  G03C1/0051 ,  G03C7/3022 ,  G03C7/392 ,  G03C2200/24

    摘要： A multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said silver halide emulsion layers contains a tabular grain silver halide emulsion having a halide content of at least 95% bromide and less than about 5% iodide, said iodide being substantially uniformly distributed in the silver halide grains of said emulsion, and said emulsion is sensitized with a fragmentable electron donor of the formula X-Y' or an electron donor which contains an -XY' moiety;
    wherein

    X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is covalently linked directly or indirectly to X, and wherein:

    1) X-Y' has an oxidation potential between 0 and about 1.4 V; and
    2) the oxidized form of X-Y' fragments to give the radical X • and the leaving fragment Y';
    and, optionally,
    3) the radical X • has an oxidation potential ≤-0.7V.

    摘要翻译： 一种多色照相元件，其特征在于，包含支持青色染料成像单元的载体，所述载体包括至少一种具有至少一种形成青色染料的成色剂的红色感光卤化银乳剂层，品红染料影像形成单元包括至少一种绿色 感光卤化银乳剂层，其具有与其相关的至少一种品红色染料形成成色剂，黄色染料影像形成单元，其包含至少一种蓝色感光卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中在 所述卤化银乳剂层中的至少一种含有卤化物含量为至少95％溴化物和小于约5％碘化物的片状颗粒卤化银乳剂，所述碘化物基本均匀地分布在所述乳液的卤化银颗粒中，所述 用式XY'的可裂解电子给体或含有-XY'部分的电子给体使乳液敏化; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则基团β - 直接或间接地共价连接到X和 其中：1）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'片段的氧化形式，得到基团X 1和离去片段Y'; 和任选地，3）基团X 1具有≤-0.7V的氧化电位。