Imaging element containing incorporated photographically useful compounds
    5.
    发明公开
    Imaging element containing incorporated photographically useful compounds 审中-公开
    Bildaufzeichnungselement,das in der Photographie anwendbare Verbindungenenthält

    公开(公告)号:EP1324119A1

    公开(公告)日:2003-07-02

    申请号:EP02080164.3

    申请日:2002-12-09

    CPC分类号: G03C1/005 G03C1/035 G03C1/42

    摘要: A radiation sensitive imaging element is described comprising a support bearing one or more hydrophilic colloid layers, wherein a photographically useful compound is incorporated into at least one hydrophilic colloid layer in the form of a self-assembled composition comprising a substantially homogeneous and ordered array of the photographically useful compound and silver and halide atoms, wherein the average minimum distance from each Ag atom in the composition to an atom of the photographically useful compound in the composition is less than 50 Å. In a particular embodiment, the self-assembled composition is of the general unit cell formula

            Ag a X b (PUC*) c nH 2 O

    where X represents halogen atoms selected from Cl, Br, and I or any combination thereof, and PUC* is a photographically useful compound containing at least one positively charged onium ion group; and wherein a is an integer from 1- 10 and b is an integer from 2 - 18, with the proviso b is greater than a, and the silver and halide atoms form silver halide sublattice structures having a net negative charge; c is an integer such that the onium ion group containing photographically useful compound forms a positively-charged sublattice which stabilizes the negatively charged silver halide sublattice, wherein charge neutrality for the composition is upheld; and n is any number from 0 to 10. The invention provides novel materials and a method of incorporating active chemistry compounds such as developers or development inhibitors directly into a photographic imaging element. The invention further provide materials, and a method for preparing materials, comprising silver halide co-crystallized with photographic useful compound molecules thereby creating a unique crystal lattice. The invention described herein provides materials in which active chemistry and silver halide are present together in an ordered array, or crystal lattice, separated by distances measured on the atomic scale (i.e., in angstroms (Å), where 1 Å = 10 -4 µm).

    摘要翻译: 描述了辐射敏感成像元件,其包含承载一个或多个亲水胶体层的载体,其中将照相有用化合物以自组装组合物的形式并入至少一个亲水胶体层中,所述亲水胶体层包含基本上均匀且有序的阵列 相对有用的化合物和银和卤化物原子,其中组合物中每个Ag原子与组合物中照相用化合物的原子的平均最小距离小于50。 在一个具体实施方案中,自组装组合物为通式单元格式AgaXb(PUC *)cHH 2 O,其中X表示选自Cl,Br和I的任何组合的卤素原子,PUC *是含有 至少一个带正电荷的鎓离子基团; 并且其中a是1-10的整数,b是2-18的整数,条件是b大于a,银和卤素原子形成具有净负电荷的卤化银亚晶格结构; c是整数,使得含有照相用化合物的鎓离子基形成带正电荷的亚晶格,其稳定带负电的卤化银子晶格,其中维持组合物的电荷中性; 并且n是0至10的任何数字。本发明提供新颖的材料和将活性化学化合物如显影剂或显影抑制剂直接掺入照相成像元件中的方法。 本发明还提供材料和制备材料的方法,其包含与照相有用的化合物分子共结晶的卤化银,从而产生独特的晶格。 本文描述的发明提供了其中活性化学和卤化银以有序阵列或晶格一起存在的材料,所述阵列或晶格以原子尺度测量的距离(即,埃(ANGSTROM))分离,其中1 ANGSTROM = 10 -4 >亩)。

    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound
    6.
    发明公开
    Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound 审中-公开
    含有增强速度结合化合物与释放电子传输化合物的化合物的彩色照相元件

    公开(公告)号:EP1199600A2

    公开(公告)日:2002-04-24

    申请号:EP01203776.8

    申请日:2001-10-05

    IPC分类号: G03C7/392

    摘要: Disclosed is a color silver halide photographic element comprising a support bearing:

    (1) a light sensitive silver halide emulsion layer;
    (2) a nitrogen heterocycle with a minimum of three heteroatoms that does not react with oxidized developer, does not contain free thiol substituents, and has a ClogP sufficient to increase the photographic speed of said element compared to the same element without the compound, said heterocycle compound located either in said light sensitive layer or in a layer adjacent to it; and
    (3) an ETARC, in or adjacent to said light sensitive silver halide emulsion layer, that releases, upon reaction with oxidized developer, an electron transfer agent having a ClogP of at least 2.40. The invention provides improved light sensitivity.

    摘要翻译: 公开了包括支撑轴承的彩色卤化银照相元件:(1)一个光敏卤化银乳剂层; (2)氮杂环与最少三个直原子并不与氧化的显影剂反应的,不含有游离硫醇的取代基,并且具有足以增加与没有化合物,所述相同的元件,在所述元件的照相速度的ClogP 位于任一杂环化合物,所述光敏感层中或与其相邻的层; 和(3)在ETARC或邻近所述光敏感卤化银乳剂层,确实的版本中,在与氧化的显影剂反应,电子具有至少2:40的的ClogP转移剂。 本发明提供了改进的光灵敏度。

    Ink jet recording element and printing method
    8.
    发明公开
    Ink jet recording element and printing method 有权
    Tintenstrahlaufzeichnungselement und Druckverfahren

    公开(公告)号:EP1375179A2

    公开(公告)日:2004-01-02

    申请号:EP03076863.4

    申请日:2003-06-16

    IPC分类号: B41M5/00

    CPC分类号: B41M5/5218

    摘要: An ink jet recording element including a support having thereon an image-receiving layer, the ink jet recording element containing a metal hydroxide salt, (M 2+ )(OH) a (A p- ) b •xH 2 O; wherein: M 2+ is at least one metal ion having a 2+ oxidation state; A is an organic or inorganic anion; p is 1 or 2; and x is equal to or greater than 0; and a and b comprise rational numbers as follows: 0 2+ is balanced.

    摘要翻译: 一种喷墨记录元件,包括其上具有图像接收层的支撑体,所述喷墨记录元件含有金属氢氧化物盐,(M 2 +)(OH)a(A p)b·xH 2 O; 其中:M 2+是至少一种具有2+氧化态的金属离子; A是有机或无机阴离子; p为1或2; x等于或大于0; a和b包含如下有理数:0