公开(公告)号：EP0751155A2

公开(公告)日：1997-01-02

申请号：EP96107090.1

申请日：1996-05-06

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano

IPC分类号： C08F210/16 ,  C08F210/18 ,  C08F2/14 ,  C08F4/68

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F210/18 ,  Y10S526/904 ,  Y10S526/905 ,  C08F4/6292 ,  C08F4/68 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/25

摘要： Process for the polymerization of ethylene with C 3 -C 10 alpha-olefins in suspension of liquid monomer in the presence of a catalyst containing Vanadium obtained by the precipitation, in an atmosphere of ethylene or alpha-olefins, of:

a) a compound of Vanadium in the oxidation state of 3 to 5, with
b) a basically hydrocarbon solution of a compound selected from those having general formula R n AlX m wherein R is a C 1 -C 20 alkyl radical, X is a halogen, m+n = 3 , n is an integer from 0 to 2.

摘要翻译： 在含有钒的催化剂存在下，在乙烯或α-烯烃气氛中沉淀出的液体单体悬浮液中乙烯与C 3 -C 10α-烯烃的聚合方法为：a）将钒的化合物 氧化态为3〜5，b）选自具有通式RnAlXm的化合物的基本烃溶液，其中R为C1-C20烷基，X为卤素，m + n = 3，n为整数 从0到2。

公开(公告)号：EP0544340A1

公开(公告)日：1993-06-02

申请号：EP92202085.4

申请日：1992-07-08

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano ,  Foschi, Sergio

IPC分类号： C08F210/02 ,  C08F4/655

CPC分类号： C08F210/16 ,  C08F210/02 ,  C08F210/18 ,  Y10S526/905 ,  C08F4/6555 ,  C08F210/06 ,  C08F2500/24 ,  C08F2500/21 ,  C08F2500/17

摘要： Process for the preparation of elastomeric copolymers of ethylene, wherein ethylene is copolymerized with an α-olefin, and possibly with a diene as termonomer, in the presence of a Ziegler-Natta catalyst including a solid component of catalyst based on titanium and aluminium, supported on magnesium chloride and obtained, in accordance with a special procedure, in the form of a spherical granular solid. This process produces elastomeric copolymers having a low crystallinity even with a high content of linked ethylene.

摘要翻译： 制备乙烯的弹性体共聚物的方法，其中乙烯与α-烯烃共聚，并且可能与二烯作为反应单体共聚，在齐格勒 - 纳塔催化剂存在下，包括基于钛和铝的催化剂的固体组分，负载 在氯化镁上，按照特殊程序，以球形颗粒状固体的形式获得。 该方法即使具有高含量的连接乙烯，也产生具有低结晶度的弹性体共聚物。

公开(公告)号：EP0751155A3

公开(公告)日：1998-01-14

申请号：EP96107090.1

申请日：1996-05-06

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano

IPC分类号： C08F210/16 ,  C08F210/18 ,  C08F2/14 ,  C08F4/68

CPC分类号： C08F10/00 ,  C08F210/16 ,  C08F210/18 ,  Y10S526/904 ,  Y10S526/905 ,  C08F4/6292 ,  C08F4/68 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/25

摘要： Process for the polymerization of ethylene with C 3 -C 10 alpha-olefins in suspension of liquid monomer in the presence of a catalyst containing Vanadium obtained by the precipitation, in an atmosphere of ethylene or alpha-olefins, of:
a) a compound of Vanadium in the oxidation state of 3 to 5, with b) a basically hydrocarbon solution of a compound selected from those having general formula R n AlX m wherein R is a C 1 -C 20 alkyl radical, X is a halogen, m+n = 3 , n is an integer from 0 to 2.

公开(公告)号：EP0717050A1

公开(公告)日：1996-06-19

申请号：EP95117437.4

申请日：1995-11-06

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano ,  Loberti, Gianni

IPC分类号： C08F4/68 ,  C08F210/16

CPC分类号： C08F210/16 ,  C08F4/68

摘要： Catalytic component for the polymerization of ethylene with propylene prepared by:

a) impregnation of an inert support with a solution of a compound of Vanadium having an oxidation state of between 3 and 5;
b) subsequent treatment with a solution of a compound having general formula (I) R n AlX m wherein R is a C₁-C₂₀ alkyl radical, X is a halogen, n + m = 3 , and m is an integer between 0 and 2, the molar ratio between Aluminium in step (b) and Vanadium in step (a) being from 1/1 to 6/1.

摘要翻译： 通过以下方法制备乙烯与丙烯聚合的催化组分：a）用氧化态为3至5的钒化合物的溶液浸渍惰性载体; b）随后用具有通式（I）RnAlXm的化合物的溶液进行后处理，其中R是C1-C20烷基，X是卤素，n + m = 3，m是0和2之间的整数， 步骤（b）中的铝与步骤（a）中的钒的比例为1/1至6/1。

公开(公告)号：EP0619327A1

公开(公告)日：1994-10-12

申请号：EP94200869.9

申请日：1994-03-31

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano ,  Banzi, Viviano ,  Zecchi, Elisa

IPC分类号： C08F210/16 ,  C08F4/68

CPC分类号： C08F210/16 ,  C08F4/68

摘要： In an improved process for producing elastomeric ethylene-propylene copolymers with a propylene content comprised within the range of from 22 to 38 % by weight and a content of residual chlorine, coming from the co-catalyst, lower than 300 parts per million parts, the polymerization is carried out in suspension in the monomers in the liquid state, with vanadium triacetylacetonate and alkyl-Al compounds, and the obtained polymer is recovered without any washing steps.

摘要翻译： 在制备丙烯含量为22-38％（重量）和来自助催化剂的残余氯含量低于300ppm的乙烯 - 丙烯共聚物的改进方法中， 在液态的单体中以三乙酰丙酮钒和烷基铝化合物的悬浮液进行聚合，并且在没有任何洗涤步骤的情况下回收得到的聚合物。

公开(公告)号：EP0763551A3

公开(公告)日：1998-01-07

申请号：EP96202467.5

申请日：1996-09-05

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano

IPC分类号： C08F210/16 ,  C08F210/18 ,  C08F2/14 ,  C08F4/685 ,  C08F2/44

CPC分类号： C08F210/16 ,  Y10S526/904 ,  C08F2/44 ,  C08F4/685 ,  C08F210/06 ,  C08F2500/17

摘要： Process for the preparation in liquid phase of copolymers of ethylene with propylene and optionally another diene, in the presence of a catalyst selected from (a) Titanium salt supported on magnesium salt and (b) compound of Vanadium soluble in hydrocarbon solvents either supported on an inert material or prepolymerized, and a co-catalyst essentially consisting of an organic compound of Aluminium, and a possible chlorinated activator, characterized in that:
1) when the polymerization is almost complete, a solid material insoluble in the reaction environment and having an average diameter of between 0.001 and 200 microns is added to the reaction mixture; 2) the suspension of polymer and solid material are kept in contact for a sufficient time to obtain perfectly free-flowing polymeric particles; 3) the perfectly free-flowing polymeric particles of step (2) are recovered.

公开(公告)号：EP0763551A2

公开(公告)日：1997-03-19

申请号：EP96202467.5

申请日：1996-09-05

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano

IPC分类号： C08F210/16 ,  C08F210/18 ,  C08F2/14 ,  C08F4/685 ,  C08F2/44

CPC分类号： C08F210/16 ,  Y10S526/904 ,  C08F2/44 ,  C08F4/685 ,  C08F210/06 ,  C08F2500/17

摘要： Process for the preparation in liquid phase of copolymers of ethylene with propylene and optionally another diene, in the presence of a catalyst selected from (a) Titanium salt supported on magnesium salt and (b) compound of Vanadium soluble in hydrocarbon solvents either supported on an inert material or prepolymerized, and a co-catalyst essentially consisting of an organic compound of Aluminium, and a possible chlorinated activator, characterized in that:

1) when the polymerization is almost complete, a solid material insoluble in the reaction environment and having an average diameter of between 0.001 and 200 microns is added to the reaction mixture;
2) the suspension of polymer and solid material are kept in contact for a sufficient time to obtain perfectly free-flowing polymeric particles;
3) the perfectly free-flowing polymeric particles of step (2) are recovered.

摘要翻译： 在乙烯与丙烯和任选的另一种二烯共聚物的液相中在催化剂存在下制备方法，所述催化剂选自（a）负载在镁盐上的钛盐和（b）可溶于烃溶剂的钒的化合物， 惰性材料或预聚合物，以及主要由铝的有机化合物组成的助催化剂和可能的氯化活化剂，其特征在于：1）当聚合几乎完成时，不溶于反应环境并具有平均值的固体材料 将直径为0.001至200微米的直径加入到反应混合物中; 2）聚合物和固体材料的悬浮液保持接触足够的时间以获得完全自由流动的聚合物颗粒; 3）回收步骤（2）的完全自由流动的聚合物颗粒。

公开(公告)号：EP0544340B1

公开(公告)日：1996-10-02

申请号：EP92202085.4

申请日：1992-07-08

申请人： ENICHEM ELASTOMERI S.r.l.

发明人： Tanaglia, Tiziano ,  Foschi, Sergio

IPC分类号： C08F210/02 ,  C08F4/655

CPC分类号： C08F210/16 ,  C08F210/02 ,  C08F210/18 ,  Y10S526/905 ,  C08F4/6555 ,  C08F210/06 ,  C08F2500/24 ,  C08F2500/21 ,  C08F2500/17