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    A process for the epoxydation of olefinic compounds
    5.
    发明公开
    A process for the epoxydation of olefinic compounds 失效
    烯烃化合物的环氧化方法

    公开(公告)号：EP0230949A3

    公开(公告)日：1989-05-31

    申请号：EP87100625.0

    申请日：1987-01-19

    申请人： ENIRICERCHE S.p.A. ,  ENICHEM SYNTHESIS S.p.A.

    发明人： Clerici, Mario Gabriele ,  Romano, Ugo

    IPC分类号： C07D301/12 ,  B01J29/04

    CPC分类号： C07D301/12 ,  B01J29/89 ,  C07D303/04

    摘要： A process for the epoxidation of olefinic compounds comprising reacting said compounds with hydrogen peroxide introduced as such or produced by substances under the reaction conditions, in the presence of synthetic zeolites containing titanium atoms corresponding to the general formula:
    wherein x is in the range of from about 0.0001 to about 0.04, and optionally, in presence of one or more solvents, at a temperature in the range of from about 0 to about 150°C. and at a pressure of from about 1 to about 100 atm. The synthetic zeolites are treated with alkaline substances before and/or during their use in the reaction, or alternatively the synthetic zeolites are acid neutralized with a compound such as X-Si-(R) 3 where X is selected from Cl, Br, I, CH 3 CON-Si-(CH 3 ) 3 , CF 3 COON-Si-(CH 3 ) 3 , (R) 3 -Si-NH, and an imidazolyl group wherein R is selected from an alkyl, aryl or alkylaryl group.

    A process for the epoxydation of olefinic compounds
    7.
    发明公开
    A process for the epoxydation of olefinic compounds 失效
    一种用于烯烃化合物的环氧化方法。

    公开(公告)号：EP0230949A2

    公开(公告)日：1987-08-05

    申请号：EP87100625.0

    申请日：1987-01-19

    申请人： ENIRICERCHE S.p.A. ,  ENICHEM SYNTHESIS S.p.A.

    发明人： Clerici, Mario Gabriele ,  Romano, Ugo

    IPC分类号： C07D301/12 ,  B01J29/04

    CPC分类号： C07D301/12 ,  B01J29/89 ,  C07D303/04

    摘要： A process for the epoxidation of olefinic compounds comprising reacting said compounds with hydrogen peroxide introduced as such or produced by substances under the reaction conditions, in the presence of synthetic zeolites containing titanium atoms corresponding to the general formula:
    wherein x is in the range of from about 0.0001 to about 0.04, and optionally, in presence of one or more solvents, at a temperature in the range of from about 0 to about 150°C. and at a pressure of from about 1 to about 100 atm. The synthetic zeolites are treated with alkaline substances before and/or during their use in the reaction, or alternatively the synthetic zeolites are acid neutralized with a compound such as X-Si-(R) 3 where X is selected from Cl, Br, I, CH 3 CON-Si-(CH 3 ) 3 , CF 3 COON-Si-(CH 3 ) 3 , (R) 3 -Si-NH, and an imidazolyl group wherein R is selected from an alkyl, aryl or alkylaryl group.

    Procedure for the production of alkyl carbonates
    10.
    发明公开
    Procedure for the production of alkyl carbonates 失效
    Verfahren zur Herstellung von Alkylcarbonaten。

    公开(公告)号：EP0534545A2

    公开(公告)日：1993-03-31

    申请号：EP92202878.2

    申请日：1992-09-19

    申请人： ENICHEM SYNTHESIS S.p.A.

    发明人： Rivetti, Franco ,  Romano, Ugo

    IPC分类号： C07C68/00

    CPC分类号： C07C68/005 ,  Y02P20/584 ,  C07C69/96

    摘要： Dialkyl carbonate is prepared by reacting an alcohol with a gaseous mixture of carbon monoxide and oxygen in the presence of cuprous chloride as catalyst and hydrochloric acid as in situ regenerator of the catalyst.

    摘要翻译： 在作为催化剂的氯化亚铜和作为催化剂的原位再生器的盐酸存在下，使醇与一氧化碳和氧气的气体混合物反应制备碳酸二烷基酯。