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1.发明公开Process for hydroxylating olefins using osmium-halogen compound catalysts 失效Verfahren zur Hydroxylierung von Olefinen mit Osmium-Halogen-Verbindung enthaltendem Katalysator。
公开(公告)号：EP0077202A2
公开(公告)日：1983-04-20
申请号：EP82305381.4
申请日：1982-10-08
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Michaelson, Robert Charles , Austin, Richard Graham
Abstract: Olefins are hydroxylated by reaction with water and an oxidant, particularly an organo-hydroperoxide, in the presence of an osmium-halogen compound hydroxylation catalyst such as OsCl 3 and optionally in the presence of a co-catalyst such as a transition metal halide.
Abstract translation: 在锇 - 卤素化合物羟基化催化剂如OsCl 3存在下，任选地在助催化剂如过渡金属卤化物存在下，通过与水和氧化剂，特别是有机氢过氧化物反应来使烯烃羟基化。
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2.发明公开Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper co-catalyst, and an aromatic amine based promoter 失效一种使用含锇催化剂，Kupfercokatalysators和芳族胺促进羟基化烯烃与分子氧的过程。
公开(公告)号：EP0139498A1
公开(公告)日：1985-05-02
申请号：EP84306679.6
申请日：1984-09-28
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
CPC classification number: B01J31/04 , B01J23/466 , B01J31/0231 , B01J31/0244 , B01J31/20 , B01J31/26 , B01J31/28 , B01J31/30 , B01J2231/32 , B01J2531/0222 , B01J2531/825 , C07C29/04 , C07C45/35 , C07C31/205
Abstract: A process directed to the hydroxylation of olefins by reacting said olefins in the presence of oxygen, water, and a catalyst composition comprising (i) a catalytically active osmium containing compound, (ii) a Co-catalyst I comprising a copper containing compound such as CuBr 2 , and (iii) a Co-catalyst II capable of increasing the rate and/or selectivity of the hydroxylation reaction, such as pyridine is disclosed.
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公开(公告)号：EP0053023B1
公开(公告)日：1985-04-17
申请号：EP81305501.9
申请日：1981-11-20
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Austin, Richard Graham , Michaelson, Robert Charles
CPC classification number: C07C29/03 , C07C29/132 , C07C29/48 , Y02P20/52 , C07C31/20 , C07C31/202 , C07C31/205 , C07C31/12
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4.发明公开Process for hydroxylating olefins in the presence of an osmium containing catalyst and organic halogenated hydrocarbon co-catalyst 失效一种用于在含锇催化剂和卤化烃作为助催化剂的存在下羟基化烯烃的方法。
公开(公告)号：EP0101167A1
公开(公告)日：1984-02-22
申请号：EP83303673.4
申请日：1983-06-24
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Austin, Richard Graham , Michaelson, Robert Charles
CPC classification number: B01J31/0202 , B01J23/466 , B01J31/0231 , B01J31/0239 , B01J31/0268 , B01J31/26 , B01J31/28 , B01J31/30 , B01J2231/32 , Y02P20/52 , C07C29/48 , C07C31/20 , C07C31/202 , C07C31/205
Abstract: A process for hydroxylating olefins with an organic hydroperoxide and water in the presence of an osmium containing catalyst (e.g. OsO 4 ) and an organic halogenated hydrocarbon co-catalyst (e.g., n-butyl iodide) is disclosed.
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公开(公告)号：EP0077201A2
公开(公告)日：1983-04-20
申请号：EP82305380.6
申请日：1982-10-08
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Michaelson, Robert Charles , Austin, Richard Graham
CPC classification number: C07C31/20 , B01J23/8926 , B01J27/08 , B01J31/0239 , B01J31/28 , B01J2231/32 , C07C29/03 , C07C29/50 , Y02P20/52 , C07C31/202 , C07C31/205
Abstract: A process for the hydroxylation of olefins comprises reacting the olefin with an oxygen containing gas and water in the presence of a defined catalyst composition. The catalyst composition comprises (i) a catalytically active oxide of a specified metal such as OsO 4 , (ii) a co-catalyst I being a specified transition metal salt such as CuBr 2 , and (iii) optionally a co-catalyst ll being a salt such as tetra ethyl ammonium bromide.
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Patent Agency Ranking6.发明公开Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper cocatalyst, and a cycloaliphatic amine based promoter 失效一种用于使用分子氧，含锇催化剂，Kupfercokatalysators和基于脂环族胺的启动子的系统烯烃的羟基化过程。
公开(公告)号：EP0160148A1
公开(公告)日：1985-11-06
申请号：EP84307417.0
申请日：1984-10-26
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
CPC classification number: B01J31/0231 , B01J23/466 , B01J31/0237 , B01J31/04 , B01J31/26 , B01J31/28 , B01J31/30 , B01J2231/32 , C07C29/04 , C07C45/35 , Y02P20/52 , C07C31/202 , C07C31/205
Abstract: A process directed to the hydroxylation of olefins by reacting said olefins in the presence of oxygen, water, and a catalyst composition comprising (i) a catalytically active osmium containing compound, (ii) a Co-catalyst I comprising a copper containing compound such as CuBr 2 , and (iii) a Co-catalyst II capable of increasing the rate and/or selectivity of the hydroxylation reaction, such as 1,4-diazabicyclo [2.2.2] octane is disclosed.
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公开(公告)号：EP0104873A3
公开(公告)日：1985-06-19
申请号：EP83305538
申请日：1983-09-20
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
CPC classification number: B01J31/0201 , B01J31/0202 , B01J31/0204 , B01J31/0209 , B01J31/0214 , B01J31/0252 , B01J31/04 , B01J31/1805 , B01J31/20 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J2231/70 , B01J2531/825 , C07C29/03 , C07C31/20 , Y10S526/943 , C07C31/205
Abstract: A process for hydroxylating olefins, such as ethylene or propylene, using an oxidant selected from organic hydroperoxides, H 2 0 2 , and oxygen and a catalyst composition comprising at least one osmium carbonyl catalyst, such as Os 3 (CO) 12 , and optionally at least one co-catalyst such as Nal, is disclosed.
Abstract translation: 使用选自有机氢过氧化物，H 2 O 2和氧气的氧化剂和包含至少一种羰基锇催化剂如Os 3（CO）12的催化剂组合物和任选的至少一种助催化剂的催化剂组合物来使烯烃如乙烯或丙烯进行羟基化的方法 例如NaI，被公开。
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8.发明公开Process for hydroxylating olefins using osmium-halogen compound catalysts 失效使用OSMUM-HALOGEN化合物催化剂氢氧化烯烃的方法
公开(公告)号：EP0077202A3
公开(公告)日：1983-06-22
申请号：EP82305381
申请日：1982-10-08
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Michaelson, Robert Charles , Austin, Richard Graham
Abstract: Olefins are hydroxylated by reaction with water and an oxidant, particularly an organo-hydroperoxide, in the presence of an osmium-halogen compound hydroxylation catalyst such as OsCl 3 and optionally in the presence of a co-catalyst such as a transition metal halide.
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9.发明授权
公开(公告)号：EP0077202B1
公开(公告)日：1986-04-09
申请号：EP82305381.4
申请日：1982-10-08
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Inventor： Michaelson, Robert Charles , Austin, Richard Graham
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10.发明公开A process for hydroxylating olefins using an osmium carbonyl catalyst 失效维生素Zur Hydroxylierung von Olefinen mit Hilfe eines Osmiumkatalysatoren。
公开(公告)号：EP0104873A2
公开(公告)日：1984-04-04
申请号：EP83305538.7
申请日：1983-09-20
Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
CPC classification number: B01J31/0201 , B01J31/0202 , B01J31/0204 , B01J31/0209 , B01J31/0214 , B01J31/0252 , B01J31/04 , B01J31/1805 , B01J31/20 , B01J31/2295 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J2231/70 , B01J2531/825 , C07C29/03 , C07C31/20 , Y10S526/943 , C07C31/205
Abstract: A process for hydroxylating olefins, such as ethylene or propylene, using an oxidant selected from organic hydroperoxides, H 2 0 2 , and oxygen and a catalyst composition comprising at least one osmium carbonyl catalyst, such as Os 3 (CO) 12 , and optionally at least one co-catalyst such as Nal, is disclosed.
Abstract translation: 使用选自有机氢过氧化物，H 2 O 2和氧气的氧化剂和包含至少一种羰基锇催化剂如Os 3（CO）12的催化剂组合物和任选的至少一种助催化剂的催化剂组合物来使烯烃如乙烯或丙烯进行羟基化的方法 例如NaI，被公开。
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