公开(公告)号：EP2241552B1

公开(公告)日：2018-11-14

申请号：EP09708203.6

申请日：2009-02-05

申请人： National University Corporation Nagoya University ,  Ube Industries, Ltd.

发明人： ISHIHARA, Kazuaki ,  FUKUDA, Yasuhisa ,  SUGIMOTO, Tsunemi ,  KUGIMOTO, Junichi

IPC分类号： C07D201/04 ,  B01J31/02 ,  C07D201/02 ,  C07D225/02 ,  C07D251/26 ,  C07B61/00

CPC分类号： C07D201/02 ,  B01J31/0244 ,  C07D201/04 ,  C07D225/02 ,  C07D251/26 ,  Y02P20/52

摘要： Process for producing lactam compounds and Beckmann rearrangement catalysts There is provided a catalyst which is highly active, stable and safe and forms less byproducts for a process for producing a lactam, and a production process. A cycloalkylidene-aminoaxy-1,3,5-triazine compound is provided as a Beckmann rearrangement catalyst and/or a reaction starting material in a reaction process for producing a lactam compound.

公开(公告)号：EP3212602A1

公开(公告)日：2017-09-06

申请号：EP15802226.9

申请日：2015-10-28

申请人： The Regents of the University of California ,  BP Corporation North America Inc.

发明人： SANKARANARAYANAPILLAI, Shylesh ,  SREEKUMAR, Sanil ,  TOSTE, F., Dean ,  BELL, Alexis, T. ,  GOKHALE, Amit, A. ,  GRIPPO, Adam

IPC分类号： C07C45/71 ,  C10L1/02 ,  B01J31/02

CPC分类号： C07C45/71 ,  B01J31/0237 ,  B01J31/0244 ,  C07C49/04 ,  C10L1/02 ,  C10L1/04

摘要： Provided herein are methods for producing ketone(s) from the condensation of methyl ketone(s) and alcohol(s) in the presence of an amine catalyst and a metal catalyst. Such amine catalysts may be supported, for example, on a silica-alumina support. Such ketones may be suitable for use in producing fuels, gasoline additives, and/or lubricants, or precursors thereof. The methyl ketone(s) and/or alcohol(s) may be obtained from renewable sources, such as by fermentation of biomass.

摘要翻译： 本文提供了在胺催化剂和金属催化剂的存在下由甲基酮和醇的缩合反应制备酮的方法。 这种胺催化剂可以负载在例如二氧化硅 - 氧化铝载体上。 这种酮可适用于生产燃料，汽油添加剂和/或润滑剂或其前体。 甲基酮和/或醇可以从可再生资源获得，例如通过发酵生物质。

公开(公告)号：EP3212328A1

公开(公告)日：2017-09-06

申请号：EP15802225.1

申请日：2015-10-28

申请人： The Regents of the University of California ,  BP Corporation North America Inc.

发明人： SANKARANARAYANAPILLAI, Shylesh ,  SREEKUMAR, Sanil ,  TOSTE, F., Dean ,  BELL, Alexis, T. ,  GOKHALE, Amit, A. ,  GRIPPO, Adam ,  ARAB, George, E.

IPC分类号： B01J31/02 ,  C07C45/74 ,  C10L1/02

CPC分类号： C07C45/74 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0222 ,  B01J31/0225 ,  B01J31/0237 ,  B01J31/0238 ,  B01J31/0244 ,  B01J31/0251 ,  B01J31/0254 ,  B01J31/0259 ,  B01J31/0271 ,  B01J31/04 ,  B01J2231/342 ,  C07C1/2076 ,  C07C49/203 ,  C10G3/50 ,  C10L1/02 ,  C10M105/04 ,  C10M2203/022 ,  C12P7/26 ,  Y02P30/20

摘要： Provided herein are methods for producing α,β-unsaturated ketones from the condensation of methyl ketones in the presence of an amine catalyst. Such amine catalysts may be supported, for example, on a silica-alumina support. Such amine catalysts may be used in the presence of an additional acid. The α,β-unsaturated ketones may be produced by dimerization and/or timerization of the methyl ketones. Such α,β-unsaturated ketones may be suitable for use in producing fuels, gasoline additives, and/or lubricants, or precursors thereof. The methyl ketones may be obtained from renewable sources, such as by the fermentation of biomass.

摘要翻译： 本文提供了在胺催化剂的存在下由甲基酮的缩合生产α，β-不饱和酮的方法。 这种胺催化剂可以负载在例如二氧化硅 - 氧化铝载体上。 这种胺催化剂可以在另外的酸存在下使用。 α，β-不饱和酮可以通过甲基酮的二聚和/或三聚来制备。 这种α，β-不饱和酮可适用于生产燃料，汽油添加剂和/或润滑剂或其前体。 甲基酮可以从可再生资源获得，例如通过发酵生物质。

公开(公告)号：EP3133058A4

公开(公告)日：2017-09-06

申请号：EP15780003

申请日：2015-03-10

申请人： TOAGOSEI CO LTD

发明人： HASHIMOTO NAOKI ,  YAMAGUCHI SHUUHEI ,  OOTSUKA MOTOO

IPC分类号： C07C67/03 ,  C07B61/00 ,  C07C69/54

CPC分类号： C07C67/03 ,  B01J31/0237 ,  B01J31/0244 ,  B01J31/04 ,  B01J35/0006 ,  B01J2231/49 ,  B01J2531/002 ,  B01J2531/26 ,  C07C213/06 ,  C07D251/30 ,  C07C69/54

摘要： [Problem] The purpose of the present invention is to obtain a multifunctional (meth)acrylate with good yield by an ester exchange reaction of a polyhydric alcohol such as pentaerythritol or dipentaerythritol with a monofunctional (meth)acrylate. [Solution] A multifunctional (meth)acrylate manufacturing method characterized in that when manufacturing a multifunctional (meth)acrylate by an ester exchange reaction of a polyhydric alcohol with a monofunctional (meth) acrylate, catalyst (A) and catalyst (B) are used together. Catalyst (A) : One or more kinds of compounds selected from a group consisting of cyclic tertiary amines with an azabicyclo structure or salts or complexes thereof, amidines or salts or complexes thereof, and compounds with a pyridine ring or salts or complexes thereof. Catalyst (B): One or more kinds of compounds selected from a group consisting of zinc-containing compounds.

摘要翻译： [课题]本发明的目的在于，通过季戊四醇，二季戊四醇等多元醇与单官能（甲基）丙烯酸酯的酯交换反应，得到收率良好的多官能（甲基）丙烯酸酯。 多官能（甲基）丙烯酸酯的制造方法，其特征在于，在通过多元醇与单官能（甲基）丙烯酸酯的酯交换反应制造多官能（甲基）丙烯酸酯时，使用催化剂（A）和催化剂（B） 一起。 催化剂（A）：一种或多种选自具有氮杂双环结构的环状叔胺或其盐或络合物，脒或其盐或络合物，以及具有吡啶环的化合物或其盐或络合物。 催化剂（B）：一种或多种选自含锌化合物的化合物。

公开(公告)号：EP2559711B1

公开(公告)日：2017-06-14

申请号：EP11769058.6

申请日：2011-04-12

申请人： Lotte Chemical Corporation

发明人： LEE, Bun-Yeoul ,  PARK, Ji-Hae ,  DO, Seung-Hyun ,  KIM, Young-Kook ,  KIM, Hwa-Kyu ,  NAM, In-Sung ,  YOON, Seung-Woong

IPC分类号： C08F110/02 ,  C07F17/00 ,  B01J31/02 ,  C07D409/04 ,  C07F7/28 ,  C08F4/659

CPC分类号： C07D409/04 ,  B01J31/0244 ,  C07F7/28 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/76 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F236/04 ,  C08F2420/02 ,  C08F2420/06 ,  Y10S526/943 ,  C08F210/14

公开(公告)号：EP3068533A1

公开(公告)日：2016-09-21

申请号：EP14796126.2

申请日：2014-11-11

申请人： Evonik Degussa GmbH

发明人： DYBALLA, Katrin Marie ,  HAHN, Hanna ,  FRANKE, Robert ,  FRIDAG, Dirk

IPC分类号： B01J31/18 ,  B01J31/02 ,  B01J31/16

CPC分类号： B01J31/185 ,  B01J31/0244 ,  B01J31/0284 ,  B01J31/1616 ,  B01J2231/321 ,  B01J2531/007 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845

摘要： The invention relates to a composition, comprising: a) at least one carrier material; b) at least one ionic liquid; c) at least one metal, selected from the subgroup VIII of the periodic table of the elements; d) at least one organic compound containing phosphorus, which compound has the structural element of formula (I); and e) optionally one or more organic amines. The invention further relates to a method for producing such a composition, to the use of the composition as a catalytically active composition, and to a method for hydroformylation, wherein the composition is used as a catalytically active composition.

公开(公告)号：EP2563511B1

公开(公告)日：2016-09-14

申请号：EP11719117.1

申请日：2011-04-21

申请人： Chevron Phillips Chemical Company LP

发明人： SYDORA, Orson L

IPC分类号： B01J31/18 ,  B01J31/14

CPC分类号： B01J31/181 ,  B01J31/0244 ,  B01J31/122 ,  B01J31/143 ,  B01J31/1608 ,  B01J2231/20 ,  B01J2531/0288 ,  B01J2531/62 ,  C07C2/32 ,  C07C2531/14 ,  C07C2531/18 ,  C07C2531/34 ,  Y02P20/582 ,  C07C11/107

公开(公告)号：EP2845922A1

公开(公告)日：2015-03-11

申请号：EP14183347.5

申请日：2014-09-03

申请人： Rohm and Haas Electronic Materials LLC

发明人： Milum, Kristen M. ,  Rzeznik, Maria Anna ,  Cleary, Donald E. ,  Kozhukh, Julia ,  Niazimbetova, Zuhra I.

IPC分类号： C23C18/18 ,  C23C18/20 ,  B01J31/02 ,  C23C18/30 ,  H05K3/42

CPC分类号： C23C18/30 ,  B01J31/0244 ,  C23C18/1844 ,  C23C18/1893 ,  C23C18/2086 ,  H05K3/422

摘要： Pyrimidine derivatives which contain one or more electron donating groups on the ring are used as catalytic metal complexing agents in aqueous alkaline environments to catalyze electroless metal plating on metal clad and un-clad substrates. The catalysts are monomers and free of tin and antioxidants.

摘要翻译： 在环状碱性环境中含有一个或多个给电子基团的嘧啶衍生物用作催化金属络合剂，用于催化在金属包覆和非包覆衬底上的无电镀金属。 催化剂是单体，不含锡和抗氧化剂。

公开(公告)号：EP2694469A2

公开(公告)日：2014-02-12

申请号：EP12717879.6

申请日：2012-04-04

申请人： Commissariat à l'Énergie Atomique et aux Énergies Alternatives

发明人： CANTAT, Thibault ,  GOMES, Christophe ,  JACQUET, Olivier

IPC分类号： C07C233/03 ,  C07C231/10 ,  C07D231/12 ,  C07D233/58 ,  C07D295/104

CPC分类号： C07C231/10 ,  B01J31/0244 ,  B01J31/0245 ,  B01J31/0251 ,  B01J31/122 ,  B01J31/2409 ,  B01J2231/625 ,  B01J2531/0247 ,  B01J2531/842 ,  C07B59/00 ,  C07B2200/05 ,  C07C241/04 ,  C07C249/02 ,  C07C249/16 ,  C07D231/12 ,  C07D233/06 ,  C07D233/58 ,  C07D241/04 ,  C07D243/28 ,  C07D249/02 ,  C07D249/08 ,  C07D249/16 ,  C07D251/28 ,  C07D295/185 ,  C07C233/03 ,  C07C243/28 ,  C07C251/28 ,  C07C251/86

摘要： The present invention relates to a method for preparing formamide compounds using carbon dioxide, and to the use of said method for manufacturing vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, pesticides and fertilisers. The invention also relates to a method for manufacturing vitamins, pharmaceutical products, adhesives, acrylic fibres, synthetic leathers, pesticides and fertilisers which includes a step of preparing formamide compounds by the method according to the invention.

公开(公告)号：EP2606048A4

公开(公告)日：2014-01-15

申请号：EP11818823

申请日：2011-08-19

申请人： UNIV ILLINOIS

发明人： HARTWIG JOHN F ,  MORIMOTO HIROYUKI ,  FIER PATRICK

IPC分类号： C07D471/04 ,  C07C29/32 ,  C07C41/30 ,  C07C45/68

CPC分类号： C07C17/32 ,  B01J31/0231 ,  B01J31/0235 ,  B01J31/0244 ,  C07B39/00 ,  C07C17/263 ,  C07C22/08 ,  C07C29/32 ,  C07C37/11 ,  C07C41/30 ,  C07C41/48 ,  C07C45/63 ,  C07C45/68 ,  C07C67/293 ,  C07C67/343 ,  C07C201/12 ,  C07C209/68 ,  C07C231/12 ,  C07C253/30 ,  C07D209/08 ,  C07D209/10 ,  C07D213/26 ,  C07D213/61 ,  C07D215/12 ,  C07D215/18 ,  C07D239/22 ,  C07D239/54 ,  C07F1/08 ,  C07C43/225 ,  C07C33/46 ,  C07C47/55 ,  C07C49/80 ,  C07C69/63 ,  C07C43/1742 ,  C07C69/76 ,  C07C43/313 ,  C07C255/50 ,  C07C25/13 ,  C07C205/11 ,  C07C211/52 ,  C07C233/15

摘要： A method of forming a fluorinated molecular entity includes reacting in a reaction mixture an aromatic halide, copper, a fluoroalkyl group, and a ligand. The aromatic halide includes an aromatic group and a halogen substituent bonded to the aromatic group. The ligand includes at least one group-V donor selected from phosphorus and an amine. The overall molar ratio of copper to aromatic halide in the reaction mixture is from 0.2 to 3. The method further includes forming a fluoroalkylarene including the aromatic group and the fluoroalkyl group bonded to the aromatic group. A composition, which may be used in the method, consists essentially of copper, the fluoroalkyl group, and the ligand, where the molar ratio of copper to the fluoroalkyl group is approximately 1.