公开(公告)号：EP1461401A4

公开(公告)日：2008-12-24

申请号：EP02789534

申请日：2002-11-08

申请人： EXXONMOBIL RES & ENG CO

发明人： COKER JOHN CALVIN ,  BRIGNAC GARLAND BARRY ,  HALBERT THOMAS R ,  MATRAGRANO JOHN G ,  GUPTA BRIJENDA N ,  WELCH ROBERT CHARLES WILLIAM ,  WINTER WILLIAM EDWARD JR

IPC分类号： B01J23/88 ,  C10G45/08 ,  C10G45/12 ,  C10G65/04 ,  C10G45/00 ,  C10G45/04

CPC分类号： C10G65/04 ,  C10G45/08 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/301 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/02 ,  C10L1/06

摘要： A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically bound sulfur and olefins. The olefinic naphtha stream is selectively hydrodesulfurized in a first sulfur removal stage and resulting product stream, which contains hydrogen sulfide and organosulfur is fractionated at a temperature to produce a light fraction containing less than about 100 wppm organically bound sulfur and a heavy fraction containing greater than about 100 wppm organically bound sulfur. The light fraction is stripped of at least a portion ofits hydrogen sulfide and can be collected or passed to gasoline blending. The heavy fraction is passed to a second sulfur removal stage wherein at least a portion of any remaining organically bound sulfur is removed.

公开(公告)号：EP1169127A4

公开(公告)日：2012-03-14

申请号：EP00914815

申请日：2000-03-03

申请人： EXXONMOBIL RES & ENG CO

发明人： BRIGNAC GARLAND BARRY ,  KOCISCIN JOSEPH JOHN ,  MCKNIGHT CRAIG A

IPC分类号： B01J27/02 ,  B01J23/00 ,  B01J23/882 ,  B01J27/043 ,  B01J27/047 ,  B01J27/049 ,  B01J27/051 ,  B01J37/20 ,  C10G45/04 ,  C10G45/08 ,  C10G45/60

CPC分类号： B01J37/20 ,  B01J23/882 ,  C10G45/08 ,  C10G65/04 ,  C10G65/12 ,  C10G69/04 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/703 ,  C10G2400/02

摘要： An improved catalyst activation process for olefinic naphtha hydrodesulfurization. This process maintains the sulfur removal activity of the catalyst while reducing the olefin saturation activity.

公开(公告)号：EP1285047A4

公开(公告)日：2003-07-23

申请号：EP01926706

申请日：2001-04-06

申请人： EXXONMOBIL RES & ENG CO

发明人： HALBERT THOMAS RISHER ,  MCKNIGHT CRAIG ALLAN ,  GREELEY JOHN PETER ,  COOK BRUCE RANDALL ,  BRIGNAC GARLAND BARRY ,  GREANEY MARK ALAN ,  WELCH ROBERT CHARLES WILLIAM

IPC分类号： C10G67/02 ,  C10G11/04 ,  C10G11/05 ,  C10G11/06 ,  C10G19/02 ,  C10G19/08 ,  C10G45/02 ,  C10G67/04 ,  C10G67/06 ,  C10G67/12 ,  C10G69/04 ,  C10G69/06 ,  C10L1/02 ,  C10G19/00 ,  C10G19/04 ,  C10G67/00 ,  C10G67/10

CPC分类号： C10G67/0418 ,  C10G67/12 ,  C10L1/02

摘要： A gasoline blendstock is produced having a decreased amount of sulfur by first selectively hydrodesulfurizing a cracked naphtha that contains both non-mercaptan and mercaptan sulfur to produce a first product having a decreased amount of non-mercaptan sulfur. The mercaptan sulfur in the first product is then converted or removed to obtain a second product having a decreased amount of mercaptan sulfur.

摘要翻译： 通过首先对含有非硫醇和硫醇硫的裂化石脑油进行选择性加氢脱硫以生产具有减少量的非硫醇硫的第一产物，生产具有减少量的硫的汽油混合物料。 然后转化或除去第一种产品中的硫醇硫，得到硫醇含量降低的第二种产品。

公开(公告)号：EP1238042A4

公开(公告)日：2011-03-09

申请号：EP00979181

申请日：2000-11-16

申请人： EXXONMOBIL RES & ENG CO

发明人： MCKNIGHT CRAIG A ,  HALBERT THOMAS RISHER ,  GREELEY JOHN PETER ,  BRIGNAC GARLAND BARRY ,  DEMMIN RICHARD ALAN ,  WINTER WILLIAM EDWARD JR ,  COOK BRUCE RANDALL

IPC分类号： B01J23/882 ,  B01J35/10 ,  C10G7/00 ,  C10G45/06 ,  C10G45/08 ,  C10G63/04 ,  C10G65/04 ,  C10G1/00

CPC分类号： C10G45/08 ,  B01J23/85 ,  B01J23/882 ,  B01J35/0006 ,  C10G65/04 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4018 ,  C10G2400/02

公开(公告)号：EP1246891A4

公开(公告)日：2004-02-18

申请号：EP00989629

申请日：2000-12-05

申请人： EXXONMOBIL RES & ENG CO

发明人： BRIGNAC GARLAND BARRY ,  GREELEY JOHN PETER ,  HALBERT THOMAS RISHER ,  MC KNIGHT CRAIG ALLAN ,  DEMMIN RICHARD ALAN ,  CLARK JANET RENEE

IPC分类号： B01J23/88 ,  B01J23/882 ,  B01J23/94 ,  B01J35/10 ,  B01J38/10 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/02

CPC分类号： C10G45/06 ,  B01J23/882 ,  B01J35/0073 ,  B01J35/023 ,  B01J35/1061 ,  C10G45/08 ,  C10G2400/02

摘要： A high temperature naphtha desulfurization process with reduced olefin saturation employs a partially spent and low metals content hydrodesulfurization catalyst having from 2-40 % the activity of a new catalyst. The catalytic metals preferably include Co and Mo in an atomic ratio of from 0.1 to 1. The catalyst is preferably at least partially regenerable, has less than 500 wppm of a total of one or more of nickel, iron and vanadium and preferably has no more than 12 wt. % catalytic metal calculated as the oxide. This permits selective deep desulfurization, with reduced olefin saturation, low product mercaptan levels and little or need for downstream mercaptan removal.

公开(公告)号：EP1097109A4

公开(公告)日：2001-12-12

申请号：EP99924444

申请日：1999-05-21

申请人： EXXONMOBIL RES & ENG CO

发明人： BRIGNAC GARLAND BARRY ,  KAUFMAN JEFFREY LAWRENCE ,  COKER JOHN CALVIN

IPC分类号： B01J23/88 ,  B01J23/882 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  C10G45/08 ,  C10G65/04 ,  C01G45/08 ,  C10G25/00

CPC分类号： B01J23/882 ,  B01J35/0073 ,  B01J35/023 ,  B01J35/1061 ,  B01J35/1066 ,  C10G2400/02

摘要： A process for hydrodesulfurizing naphtha feedstreams wherein the reactor inlet temperature is below the dew point of the feedstock at the reactor inlet so that the naphtha will completely vaporize within the catalyst bed. It is preferred to use a catalyst comprised of about 1 to about 10 wt.% MoO3, about 0.1 to about 5wt.%CoO supported on a suitable support material. They are also characterized as having an average medium pore diameter from about 60 Å to 200 Å, a Co/Mo atomic ratio of about 0.1 to about 1.0, a MoO3 surface concentration of about 0.5 x 10-4 to about 3.0 x 10-4g MoO3/m2, and an average particle size of less than about 2.0mm in diameter.

摘要翻译： 一种加氢脱硫石脑油原料流的方法，其中反应器入口温度低于原料在反应器入口的露点，以使石脑油在催化剂床内完全汽化。 优选使用由约1至约10重量％的MoO 3，约0.1至约5重量％的CoO负载在合适的载体材料上的催化剂。 它们的特征还在于具有约60至200的平均中孔直径，约0.1至约1.0的Co / Mo原子比，约0.5×10 -4至约3.0×10 -4 g的MoO 3表面浓度 MoO3 / m2，平均粒径小于约2.0mm。