公开(公告)号：EP3086874B1

公开(公告)日：2018-11-28

申请号：EP14816318.1

申请日：2014-12-23

申请人： Eramet ,  IFP Energies nouvelles

发明人： BOUALLEG, Malika ,  LAFON, Olivier ,  BURDET, Fabien André Pierre ,  SOULAIROL, Romain Charles Joseph René

IPC分类号： B01J20/08 ,  B01J20/30 ,  C01D15/04 ,  C01F7/04

CPC分类号： B01J20/08 ,  B01D15/36 ,  B01J20/046 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3085 ,  B01J2220/58 ,  C01D15/04 ,  C01F7/043 ,  C01P2002/72 ,  C01P2006/12 ,  C02F1/281

公开(公告)号：EP3086874A1

公开(公告)日：2016-11-02

申请号：EP14816318.1

申请日：2014-12-23

申请人： Eramet ,  IFP Énergies nouvelles

发明人： BOUALLEG, Malika ,  LAFON, Olivier ,  BURDET, Fabien André Pierre ,  SOULAIROL, Romain Charles Joseph René

IPC分类号： B01J20/08 ,  B01J20/30 ,  C01D15/04 ,  C01F7/04

CPC分类号： B01J20/08 ,  B01D15/36 ,  B01J20/046 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3085 ,  B01J2220/58 ,  C01D15/04 ,  C01F7/043 ,  C01P2002/72 ,  C01P2006/12 ,  C02F1/281

摘要： The invention concerns a method of preparing a crystallized solid material having the formula LiCl.2Al(OH)
3 ,nH
2 O, where n is between 0.01 and 10, the method comprising at least the following steps: (a) mixing, in an aqueous medium, at least one alumina source and at least one lithium source in order to obtain a suspension; (b) filtering the suspension obtained in step (a) in order to obtain a paste; (c) drying the paste obtained at the end of step (b) at a temperature of between 20 and 80°C for a period of between 1 and 12 hours; (d) shaping by extrusion of the dried paste, immediately after drying step (c) in order to obtain extruded products, shaping step (d) being performed in the absence of binder; and (e) drying the resulting extruded products at a temperature of between 20 and 200°C for a period of between 1 and 20 hours in order to obtain the crystallized solid material having the formula LiCl.2Al(OH)
3 ,nH
2 O in the form of extruded products. The invention also concerns a method of extracting lithium from saline solutions using the material thus prepared. The invention further concerns a solid crystallized material having the formula LiCl.2Al(OH)
3 ,nH
2 O, n being between 0.01 and 10, shaped. The invention also concerns a device for performing the lithium-extraction method.

公开(公告)号：EP3134202A1

公开(公告)日：2017-03-01

申请号：EP15720043.7

申请日：2015-04-24

申请人： Eramet ,  IFP Énergies nouvelles

发明人： BOUALLEG, Malika ,  BURDET, Fabien André Pierre ,  SOULAIROL, Romain Charles Joseph René

IPC分类号： B01J20/04 ,  B01J20/08 ,  B01J20/30 ,  B01J41/10 ,  C01D15/04 ,  C01F7/00 ,  B01J39/10

CPC分类号： B01J20/046 ,  B01J20/041 ,  B01J20/08 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3085 ,  B01J39/10 ,  B01J41/10 ,  C01D15/04 ,  C01F7/002 ,  C01F7/021 ,  C01P2002/72 ,  C01P2006/12

摘要： The invention relates to a process for preparing a crystalline solid material of formula LiCl.2Al(OH)
3 .nH
2 O with n being between 0.01 and 10, said process comprising at least the following steps: a) a step of mixing, in an aqueous medium, at least one source of alumina and at least one source of lithium in order to obtain a suspension, b) a step of filtering the suspension obtained in step a) in order to obtain a paste, c) a step of drying the paste obtained at the end of step b), d) a step of shaping said dried paste, directly after the drying step c) in order to obtain a shaped solid material, said shaping step d) being carried out in the absence of binder, and e) the drying of the shaped solid material obtained, f) a step of hydrothermal treatment in order to obtain the shaped crystalline solid material of formula LiCl.2Al(OH)
3 .nH
2 O. The invention also relates to a solid material obtained according to this process and to a process for extracting lithium from saline solutions using the material thus prepared.

摘要翻译： 被包括在0.01和10之间，一种制备式LiCl.2Al（OH）3.nH2O的结晶的固体物质用正方法，包括：在wässrige介质混合，氧化铝中的至少一个源，并且为了锂中的至少一个源 以获得悬浮液，滤波获得用于获得浆料得到的悬浮液，经干燥后干燥得到的浆液，成形将干燥浆料以获得一成型固体材料，随后。 成形是在没有接着进行干燥和水热处理，得到成形的粘合剂的情况下进行结晶化的式固体材料LiCl.2Al（OH）3.nH2O。 一种用于从盐溶液中提取锂的方法使用由其制备的材料。