公开(公告)号：EP2498908A2

公开(公告)日：2012-09-19

申请号：EP10829029.7

申请日：2010-11-03

申请人： ExxonMobil Chemical Patents Inc.

发明人： HOLTCAMP, Matthew, W. ,  BEDOYA, Matthew, S. ,  FALER, Catherine, A. ,  HUFF, Caol, P. ,  HAGADORN, John, R.

IPC分类号： B01J31/12 ,  C07F15/00 ,  C07C1/213 ,  C07C11/00

CPC分类号： C07F15/0046 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/543 ,  B01J2531/0261 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/04 ,  C07C2531/22 ,  C07F15/002 ,  C07C11/02 ,  C07C11/08

摘要： This invention relates to a metathesis catalyst compound comprising an asymmetrically substituted N-heterocyclic carbene (NHC) metathesis catalyst and a process to make linear alpha-olefms comprising contacting a feed material and an optional alkene (such as ethylene) with said catalyst, where the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from biodiesel.

公开(公告)号：EP2866936A1

公开(公告)日：2015-05-06

申请号：EP13810862.6

申请日：2013-06-12

申请人： ExxonMobil Chemical Patents Inc.

发明人： HOLTCAMP, Matthew, W. ,  FALER, Catherine, A. ,  HUFF, Caol, P. ,  BEDOYA, Matthew, S. ,  HAGADORN, John, R.

IPC分类号： B01J31/22 ,  B01J31/02 ,  C07F15/00

CPC分类号： B01J31/2265 ,  B01J31/1805 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/2404 ,  B01J31/2447 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2540/10 ,  B01J2540/22 ,  C07C6/04 ,  C07C67/293 ,  C07F15/0046 ,  C07C11/02 ,  C07C69/533

摘要： This invention relates to a catalyst compound for the metathesis of olefins represented by the formula: (I) wherein M is a Group 8 metal; X and X
1 are anionic ligands; L is a neutral two electron donor; L
1 is N or P, preferably N; R is a C
1 to C
30 hydrocarbyl or a C
1 to C
30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C
1 to C
30 hydrocarbyl, and a C
1 to C
30 substituted hydrocarbyl; R
1 is selected from the group consisting of hydrogen, a C
1 to C
30 hydrocarbyl, and a C
1 to C
30 substituted hydrocarbyl; R
2 is hydrogen, a C
1 to C
30 hydrocarbyl or a C
1 to C
30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C
1 to C
30 hydrocarbyls, and C
1 to C
30 substituted hydrocarbyls. This invention also relates to process to make alphaolefins comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.

公开(公告)号：EP2533899A2

公开(公告)日：2012-12-19

申请号：EP10845952.0

申请日：2010-12-09

申请人： ExxonMobil Chemical Patents Inc.

发明人： HOLTCAMP, Matthew, W. ,  FALER, Catherine, A. ,  HUFF, Caol, P. ,  BEDOYA, Matthew, S. ,  HAGADORN, John, R.

IPC分类号： B01J31/22 ,  C07F15/00 ,  C07C6/06 ,  C07C11/02 ,  C07B37/00

CPC分类号： C07F15/0046 ,  B01J31/2208 ,  B01J31/2252 ,  B01J31/2273 ,  B01J31/2278 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2540/22 ,  C07C6/04 ,  C07C67/03 ,  C07C67/333 ,  C07C2531/24 ,  C11C3/00 ,  Y02E50/13 ,  C07C11/02 ,  C07C69/52 ,  C07C69/533

摘要： This invention relates to a catalyst compound for the metathesis of olefins represented by the formula (I): wherein M is a Group 8 metal; X and X
1 are anionic ligands; L is a neutral two electron donor; L
1 is N, O, P, or S, preferably N or O; R is a C
1 to C
30 hydrocarbyl or a C
1 to C
30 substituted hydrocarbyl; G* is selected from the group consisting of hydrogen, a C
1 to C
30 hydrocarbyl, and a C
1 to C
30 substituted hydrocarbyl; R
1 is selected from the group consisting of hydrogen, a C
1 to C
30 hydrocarbyl, and a C
1 to C
30 substituted hydrocarbyl; and G is independently selected from the group consisting of hydrogen, halogen, C
1 to C
30 hydrocarbyls and C
1 to C
30 substituted hydrocarbyls. This invention also relates to process to make alphaolefms comprising contacting an olefin, such as ethylene, with a feed oil containing a triacylglyceride (typically a fatty acid ester (such as methyl oleate)) with the catalyst compound described above. The fatty acid ester may be a fatty acid methyl ester derived from biodiesel.

摘要翻译： 本发明涉及由式（I）表示的用于烯烃复分解反应的催化剂化合物：其中M是第8族金属; X和X 1是阴离子配体; L是中性的两个电子供体; L 1是N，O，P或S，优选N或O; R为C 1至C 30烃基或C 1至C 30取代的烃基; G *选自氢，C 1至C 30烃基和C 1至C 30取代的烃基; R 1选自由氢，C 1至C 30烃基和C 1至C 30取代的烃基组成的组; 并且G独立地选自由氢，卤素，C 1至C 30烃基和C 1至C 30取代的烃基组成的组。 本发明还涉及制备α-烯烃的方法，包括使烯烃如乙烯与含有三酰基甘油酯（通常为脂肪酸酯（如油酸甲酯））的进料油与上述催化剂化合物接触。 脂肪酸酯可以是衍生自生物柴油的脂肪酸甲酯。

公开(公告)号：EP2785763A1

公开(公告)日：2014-10-08

申请号：EP12854390.7

申请日：2012-10-08

申请人： ExxonMobil Chemical Patents Inc.

发明人： HOLTCAMP, Matthew, W. ,  CROWTHER, Donna, J. ,  HUFF, Caol, P. ,  BRANT, Patrick ,  LOVELL, Jacqueline, A.

IPC分类号： C08G61/00 ,  C08G61/12 ,  C08F32/00 ,  C08F4/60

CPC分类号： C08G61/08 ,  C08F297/00 ,  C08G61/12 ,  C08G2261/3324 ,  C08G2261/3342 ,  C08G2261/418

摘要： This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.

公开(公告)号：EP2742074A1

公开(公告)日：2014-06-18

申请号：EP12824641.0

申请日：2012-06-25

申请人： ExxonMobil Chemical Patents Inc.

发明人： HOLTCAMP, Matthew, W. ,  HAGADORN, John, R. ,  HUFF, Caol, P. ,  BEDOYA, Matthew, S. ,  FALER, Catherine, A.

IPC分类号： C08F32/00 ,  C08F32/02 ,  C08F4/60 ,  C08G61/02

CPC分类号： C08G61/08 ,  C08F4/80 ,  C08G2261/164 ,  C08G2261/1642 ,  C08G2261/3324 ,  C08G2261/3325 ,  C08G2261/418 ,  C08G2261/724

摘要： This invention relates to a process for producing a polymer of a cyclic olefin and a linear mono-olefin, the process comprising contacting at least one C
5 based cyclic olefin with at least one linear mono-olefin having from two to twenty carbon atoms in the presence of an alkene metathesis catalyst, and the polymer so produced.