公开(公告)号：EP1140740B1

公开(公告)日：2012-03-28

申请号：EP99965748.9

申请日：1999-11-04

申请人： ExxonMobil Oil Corporation

发明人： BECK, Jeffrey, Scott ,  KENNEDY, Carrie, L. ,  ROTH, Wieslaw, Jerzy ,  STERN, David, Lawrence

IPC分类号： C01B39/38

CPC分类号： C01B39/38 ,  B01J29/04 ,  B01J29/40 ,  C01B39/40 ,  C07C5/2702 ,  C07C6/123 ,  C07C2529/40 ,  C07C15/067

摘要： A synthetic porous cystalline material has the structure of ZSM-5 and a composition involving the molar relationship: X2O3:(n)YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is less than 25, and wherein the slope of the nitrogen sorption isotherm of the material at a partial pressure of nitrogen of 0,4 to 0,7 and a temperature 77 °K is greater than 30. The material has a mesoporous surface area (MSA) greater than 45 m2/g and is useful as a catalyst in the liquid phase isomerization of xylene.

公开(公告)号：EP0914308B1

公开(公告)日：2002-09-04

申请号：EP97931077.8

申请日：1997-06-09

申请人： EXXONMOBIL OIL CORPORATION

发明人： CHESTER, Arthur, Warren ,  FUNG, Shiu, Lun, Anthony ,  KRESGE, Charles, Theodore ,  ROTH, Wieslaw, Jerzy

IPC分类号： C07C2/58 ,  C07C2/66 ,  C10G11/05 ,  B01J29/04 ,  C01B39/02

CPC分类号： B01J29/80 ,  B01J29/084 ,  B01J29/70 ,  B01J29/7038 ,  B01J2229/12 ,  B01J2229/42 ,  C01B33/38 ,  C07C2/58 ,  C07C2/66 ,  C07C2529/70 ,  C10G11/05

公开(公告)号：EP1163189A1

公开(公告)日：2001-12-19

申请号：EP99949667.2

申请日：1999-09-23

申请人： EXXONMOBIL OIL CORPORATION

发明人： ROTH, Wieslaw, Jerzy

IPC分类号： C01B33/12 ,  C01B33/36

CPC分类号： C01B37/02 ,  C01P2002/72

摘要： A method for synthesizing MCM-48 includes reacting an inorganic silica reagent an alkylammonium hydroxide and halide-containing surfactant in an aqueous medium under conditions to form a crystalline MCM-48 product. Alternatively, the first two reagents are combined in an aqueous medium to form a first reaction mixture. This first reaction mixture then is combined with a halide-containing surfactant to form a second reaction mixture that is maintained under sufficient conditions to form a crystalline MCM-48 product.