公开(公告)号：EP2834210B1

公开(公告)日：2018-07-18

申请号：EP13717640.0

申请日：2013-04-02

申请人： Saudi Arabian Oil Company ,  King Fahd University of Petroleum and Minerals

发明人： WANG, Yuguo ,  ERCAN, Cemal ,  ALI, Mohammed Ashraf ,  AL-KHATTAF, Sulaiman S. ,  AITANI, Abdullah Mohammed ,  ALI, Syed Ahmed

IPC分类号： C07C5/27 ,  C07C15/08 ,  C07C11/02 ,  C07C4/04 ,  C10G45/64 ,  B01J29/80 ,  B01J29/00 ,  B01J29/06 ,  B01J29/076 ,  B01J29/068 ,  B01J29/072 ,  B01J29/70 ,  B01J29/72 ,  B01J29/74 ,  B01J29/76

CPC分类号： C07C6/06 ,  B01J29/005 ,  B01J29/061 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/40 ,  B01J29/405 ,  B01J29/42 ,  B01J29/44 ,  B01J29/46 ,  B01J29/48 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/72 ,  B01J29/7215 ,  B01J29/74 ,  B01J29/7415 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/78 ,  B01J29/7815 ,  B01J29/80 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0201 ,  B01J37/04 ,  B01J2029/062 ,  B01J2229/18 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/40 ,  C07C2529/70 ,  C07C2529/80 ,  C07C2529/85 ,  C10G9/36 ,  C10G29/205 ,  C10G45/64 ,  C10G69/06 ,  C10G69/123 ,  Y02P20/52 ,  C07C15/08

摘要： A method for the transalkylation of a heavy reformate is provided. The heavy reformate is contacted with a transalkylation catalyst and hydrogen gas in a transalkylation reactor to selectively convert the heavy reformate to a xylenes-rich product stream. Light alkanes produced during the reaction can be supplied to a steam cracker where they are converted to light olefins.

公开(公告)号：EP2582626A4

公开(公告)日：2016-04-06

申请号：EP10853784

申请日：2010-06-21

申请人： UOP LLC

发明人： MOSCOSO JAIME G ,  JAN DENG-YANG

IPC分类号： C01B39/02 ,  B01J29/40 ,  B01J29/70 ,  C01B39/48 ,  C07C2/58 ,  C10G47/20 ,  C10G50/00

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/50 ,  B01J29/70 ,  C01B39/36 ,  C01B39/48 ,  C07C2/58 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  C07C2529/70 ,  C10G29/205 ,  C10G47/20 ,  C10G50/00 ,  C10G2400/02

公开(公告)号：EP2321238A4

公开(公告)日：2012-04-11

申请号：EP09808700

申请日：2009-08-18

申请人： FINA TECHNOLOGY

发明人： BUTLER JAMES R ,  HALL ROSA ,  XIAO XIN

IPC分类号： C07C5/22

CPC分类号： B01J29/26 ,  B01J29/076 ,  C07C6/123 ,  C07C2529/26 ,  Y02P20/52 ,  C07C15/06 ,  C07C15/04

公开(公告)号：EP1447395B1

公开(公告)日：2011-12-21

申请号：EP02776641.9

申请日：2002-10-18

申请人： China Petroleum & Chemical Corporation ,  Shanghai Research Institute of Petrochemical Technology SINOPEC

发明人： XIE, Zaiku ,  YANG, Weisheng ,  KONG, Dejin ,  ZHU, Dongmao

IPC分类号： C07C15/08 ,  C07C6/12

CPC分类号： C07C15/08 ,  C07C6/123 ,  C07C6/126 ,  C07C15/04 ,  C07C2529/26 ,  C07C2529/44 ,  C07C2529/48 ,  C07C2529/78 ,  Y02P20/52

摘要： The invention relates to a selective dismutation process of toluene and to a dismutation and transalkylation process of toluene and aromatic hydrocarbons of C9 and 9C+, which solve the problems in the prior art, such as large circulation in aromatics disposal, high energy consumption and critical requirement of raw materials, etc. In this invention, toluene is selectively dismutated to produce the mixed xylene with high concentration of p-xylene, toluene and aromatic hydrocarbons of C9 and C9+ are dismutated and transalkylated to obtain benzene and mixed xylene in thermodynamic equilibrium, by which the problems mentioned above can be overcame. These processes can be carried out in commercial scale.

公开(公告)号：EP2334601A1

公开(公告)日：2011-06-22

申请号：EP09790481.7

申请日：2009-07-15

申请人： ExxonMobil Chemical Patents Inc.

发明人： HELTON, Terry, E. ,  VINCENT, Matthew J.

IPC分类号： C01B39/46 ,  C01B39/48 ,  B01J29/00

CPC分类号： B01J29/70 ,  B01J29/7038 ,  B01J2229/42 ,  C01B39/46 ,  C01B39/48 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  C07C29/36 ,  C07C37/11 ,  C07C37/20 ,  C07C41/06 ,  C07C45/53 ,  C07C51/235 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/14 ,  C07C2523/02 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02 ,  C07C15/107 ,  C07C33/20 ,  C07C39/06 ,  C07C39/16 ,  C07C43/04 ,  C07C49/10 ,  C07C57/30

摘要： This disclosure relates to a process for manufacturing a mono-alkylaromatic compound, said process comprising contacting a feedstock comprising an alkylatable aromatic compound and an alkylating agent under alkylation reaction conditions with a catalyst comprising EMM-12, wherein said EMM-12 is a molecular sieve having, in its as-synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms, and non-discrete scattering between about 8.85 to 11.05 Angstroms or exhibit a valley in between the peaks having a d-spacing maximum in the range of 10.14 to 12.0 Angstroms and a d-spacing maximum in the range from 8.66 to 10.13 Angstroms with measured intensity corrected for background at the lowest point being not less than 50% of the point at the same XRD d-spacing on the line connecting maxima in the range of 10.14 to 12.0 Angstroms and in the range from 8.66 to 10.13 Angstroms.

摘要翻译： 本公开涉及一种制备单烷基芳族化合物的方法，所述方法包括在烷基化反应条件下将包含可烷基化芳族化合物和烷基化剂的原料与包含EMM-12的催化剂接触，其中所述EMM-12是分子筛 具有其合成后的形式和煅烧形式的X射线衍射图，其包括在d =间距最大值在14.17至12.57埃范围内的峰，d间距最大值在12.1至12.56埃的范围内， 和在约8.85至11.05埃之间的非离散散射或在具有10.14至12.0埃范围内的d间距最大值的峰之间或在具有测量强度的8.66至10.13埃的范围内的d间距最大值之间呈现谷底 在最低点处的背景校正不小于在连接最大值在10.14至12.0埃范围内的线上的相同XRD d间距上的点的50％，并且在r 从8.66到10.13埃。

公开(公告)号：EP2321222A1

公开(公告)日：2011-05-18

申请号：EP09790482.5

申请日：2009-07-15

申请人： ExxonMobil Chemical Patents Inc.

发明人： ROTH, Wieslaw, J. ,  DORSET, Douglas, L. ,  KENNEDY, Gordon, J. ,  YORKE, Thomas ,  HELTON, Terry, E.

IPC分类号： C01B39/46 ,  C01B39/48 ,  B01J29/06

CPC分类号： B01J29/70 ,  B01J29/7038 ,  B01J2229/42 ,  C01B39/46 ,  C01B39/48 ,  C07C2/66 ,  C07C6/123 ,  C07C6/126 ,  C07C29/36 ,  C07C37/11 ,  C07C37/20 ,  C07C41/06 ,  C07C45/53 ,  C07C51/235 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/14 ,  C07C2523/02 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02 ,  C07C15/107 ,  C07C33/20 ,  C07C39/06 ,  C07C39/16 ,  C07C43/04 ,  C07C49/10 ,  C07C57/30

摘要： This disclosure relates to a process for manufacturing a mono-alkylaromatic compound, said process comprising contacting a feedstock comprising an alkylatable aromatic compound and an alkylating agent under alkylation reaction conditions with a catalyst comprising EMM-12, wherein said EMM-12 is a molecular sieve having, in its as-synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms, and non-discrete scattering between about 8.85 to 11.05 Angstroms or exhibit a valley in between the peaks having a d-spacing maximum in the range of 10.14 to 12.0 Angstroms and a d-spacing maximum in the range from 8.66 to 10.13 Angstroms with measured intensity corrected for background at the lowest point being not less than 50% of the point at the same XRD d-spacing on the line connecting maxima in the range of 10.14 to 12.0 Angstroms and in the range from 8.66 to 10.13 Angstroms.

摘要翻译： 本公开涉及一种EMM-12分子筛，其以其合成形式和煅烧形式具有X射线衍射图，该X-射线衍射图包括d-间距最大值在14.17至12.57埃范围内的峰，d-间距 在12.1至12.56埃范围内的最大值，以及约8.85至11.05埃之间的非离散散射，或在具有10.14至12.0埃范围内的d间距最大值的峰之间呈现出谷值， 在最低点处校正背景的测量强度的8.66至10.13埃的范围不小于连接最大值在10.14至12.0埃范围内的线上相同XRD d间距处的点的50％ 从8.66到10.13埃。

公开(公告)号：EP2170509A4

公开(公告)日：2010-09-01

申请号：EP08754707

申请日：2008-05-23

申请人： SAUDI BASIC IND CORP

发明人： KHANMAMEDOVA ALLA K ,  STEVENSON SCOTT A ,  MITCHELL SCOTT F ,  FARMER DUSTIN B ,  VARTULI JIM

IPC分类号： B01J29/04

CPC分类号： C07C1/20 ,  B01J29/047 ,  B01J29/405 ,  B01J29/44 ,  B01J29/86 ,  B01J2229/183 ,  B01J2229/186 ,  C07C2/24 ,  C07C2/66 ,  C07C2/76 ,  C07C6/08 ,  C07C6/123 ,  C07C6/126 ,  C07C2521/02 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/58 ,  C07C2523/62 ,  C07C2529/44 ,  C07C2529/86 ,  C10G1/04 ,  C10G11/05 ,  C10G25/03 ,  C10G35/085 ,  C10G35/095 ,  C10G45/00 ,  C10G45/10 ,  C10G45/12 ,  C10G45/62 ,  C10G45/64 ,  C10G47/18 ,  C10G50/00 ,  C10G2400/20 ,  C10G2400/30 ,  Y02P30/42 ,  C07C15/02

公开(公告)号：EP1140740A4

公开(公告)日：2008-04-09

申请号：EP99965748

申请日：1999-11-04

申请人： EXXONMOBIL OIL CORP

发明人： BECK JEFFREY SCOTT ,  KENNEDY CARRIE L ,  ROTH WIESLAW JERZY ,  STERN DAVID LAWRENCE

IPC分类号： B01J29/04 ,  B01J29/40 ,  C01B39/38 ,  C01B39/40 ,  C07B61/00 ,  C07C2/76 ,  C07C5/22 ,  C07C5/27 ,  C07C6/12 ,  C07C15/04 ,  C07C15/08

CPC分类号： C01B39/38 ,  B01J29/04 ,  B01J29/40 ,  C01B39/40 ,  C07C5/2702 ,  C07C6/123 ,  C07C2529/40 ,  C07C15/067

摘要： A synthetic porous cystalline material has the structure of ZSM-5 and a composition involving the molar relationship: X2O3:(n)YO2, wherein X is a trivalent element; Y is a tetravalent element; and n is less than 25, and wherein the slope of the nitrogen sorption isotherm of the material at a partial pressure of nitrogen of 0,4 to 0,7 and a temperature 77 °K is greater than 30. The material has a mesoporous surface area (MSA) greater than 45 m2/g and is useful as a catalyst in the liquid phase isomerization of xylene.

公开(公告)号：EP1640066B1

公开(公告)日：2008-03-05

申请号：EP05022191.0

申请日：1999-10-14

申请人： SK Energy Co., Ltd.

发明人： Oh, Seung Hoon ,  Lee, Sang II ,  Seong, Kyoung Hak ,  Park, Sang Hoon

IPC分类号： B01J29/80 ,  B01J37/00 ,  C07C6/12

CPC分类号： C07C5/2737 ,  B01J23/626 ,  B01J29/18 ,  B01J29/22 ,  B01J29/40 ,  B01J29/44 ,  B01J29/7007 ,  B01J29/80 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/26 ,  B01J2229/42 ,  C07C5/2775 ,  C07C6/123 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/12 ,  C07C2529/18 ,  C07C2529/22 ,  C07C2529/40 ,  C07C2529/44 ,  C07C2529/70 ,  C07C2529/74 ,  Y02P20/52 ,  Y02P20/588 ,  C07C15/08

公开(公告)号：EP1775277A1

公开(公告)日：2007-04-18

申请号：EP05774297.5

申请日：2005-05-25

申请人： CONSEJO SUPERIOR DE INVESTIGACIONES CIENT FICAS ,  UNIVERSIDAD POLITECNICA DE VALENCIA

发明人： CORMA CANÓS, A., Instituto de Tecnología Química ,  SERRA ALFARO, J.M., Instituto de Tecn. Quimica ,  FORN S SEGUÍ, V., Instituto de Tecnología Química ,  CASTAÑEDA SÁNCHEZ, R., Instituto de Tecn. Quimica

IPC分类号： C07C5/27 ,  B01J29/04 ,  B01J29/80

CPC分类号： B01J29/80 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/78 ,  B01J2229/123 ,  B01J2229/126 ,  B01J2229/186 ,  B01J2229/32 ,  C07C6/123 ,  C07C6/126 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/60 ,  C07C2529/70 ,  C07C2529/74 ,  C07C2529/76 ,  C07C2529/78 ,  C07C2529/80 ,  Y02P20/52 ,  C07C15/08

摘要： The invention relates to a catalytic method for the transalkylation/dealkylation of organic compounds, consisting in bringing a supply comprising organic compounds into contact with a catalyst containing a first zeolitic component that is selected from among: a) one or more zeolites having crystalline structure ITQ-13; b) one or more zeolites having crystalline structure ITQ-13, which are modified either by means of selectivation or with the incorporation of one or more metals, or both; and c) a mixture of a) and b). The invention also relates to a catalyst comprising one or more modified zeolites having crystalline structure ITQ-13.

摘要翻译： 本发明涉及一种用于有机化合物的烷基转移/脱烷基化的催化方法，其包括使包含有机化合物的供体与含有第一沸石组分的催化剂接触，所述催化剂选自以下之一：a）一种或多种具有结晶结构的沸石 -13; b）具有结晶结构ITQ-13的一种或多种沸石，其通过选择性或通过掺入一种或多种金属或两者来改性; 和c）a）和b）的混合物。 本发明还涉及包含一种或多种具有结晶结构ITQ-13的改性沸石的催化剂。