Aminopolycarboxylic acid-series chelating agent, heavy metal compound thereof, photographic additive, and processing method
    1.
    发明公开
    Aminopolycarboxylic acid-series chelating agent, heavy metal compound thereof, photographic additive, and processing method 失效
    氨基多羧酸螯合剂,它们的重金属化合物,感光添加剂和加工方法

    公开(公告)号:EP0851287A3

    公开(公告)日:1999-06-09

    申请号:EP97122858.0

    申请日:1997-12-23

    摘要: There is disclosed a compound represented by the following formula (I):
       wherein R 1 and R 2 each represent a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, a carboxyl group, an amino group, an alkoxy group, a sulfo group, a nitro group, a phosphono group, an acylamino group, a sulfonylamino group, an aryloxy group, a sulfamoyl group, a carbamoyl group, an alkylthio group, an arylthio group, an acyl group, a hydroxamic acid group, or a hydroxyl group; R 3 represents a hydrogen atom, an alkyl group substituted with at least one selected from a group consisting of an alkoxy group, an aryl group and a heterocyclic group, an unsubstituted alkyl group, an aryl group, or a heterocyclic group; W represents a divalent linking group having a carbon atom(s); m and n are each an integer of 1 to 3, with the proviso that when n = 1, R 3 does not represent a hydrogen atom, when n = 2 or 3, at least one of nR 3 's represents an alkyl group, an aryl group, or a heterocyclic group, and when m and n are each 2 or more, mR 1 's are the same or different and nR 3 's are the same or different, and M 1 , M 2 , and M 3 each represent a hydrogen atom or a cation. The compound is a chelating agent for various metals that is excellent in biodegradability and metal sequestering capacity.

    Method of processing silver halide photographic material and composition for processing
    2.
    发明公开
    Method of processing silver halide photographic material and composition for processing 失效
    加工银盐摄影材料及其组合物的处理方法

    公开(公告)号:EP0580041A3

    公开(公告)日:1994-07-27

    申请号:EP93111019.1

    申请日:1993-07-09

    IPC分类号: G03C5/305

    CPC分类号: G03C5/305

    摘要: A developer composition having improved stability to aerial oxidation, which contains at least one compound represented by formulae (A) and (B):
    where R 1 and R 2 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and X represents a group of atoms selected from carbon and nitrogen which forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R 1 and R 2 , respectively, and the carbonyl carbon of formula (A);
    where R 3 and R 4 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and Y represents a group of atoms selected from carbon, nitrogen and oxygen containing at least one ether bond, and Y forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R 3 and R 4 , respectively, and the carbonyl carbon of formula (B), provided that both R 3 and R 4 are not hydroxyl.

    Aminopolycarboxylic acid chelating agent, heavy metal chelate compound thereof, photographic additive and processing method
    4.
    发明公开
    Aminopolycarboxylic acid chelating agent, heavy metal chelate compound thereof, photographic additive and processing method 失效
    氨基多羧酸螯合剂,含有这些重金属,照相添加剂和方法,用于摄影处理

    公开(公告)号:EP0840168A2

    公开(公告)日:1998-05-06

    申请号:EP97118821.4

    申请日:1997-10-29

    摘要: An aminopolycarboxylic acid compound represented by

    X 1 represents a hydrogen atom, alkyl group, hydroxyethyl group, alkoxyalkyl group or hydroxyl group, X 2 represents an alkyl group aralkyl group, hydroxyl group, hydroxyalkyl group or alkoxyalkyl group, M 1 , M 2 , M 3 and M 4 each represent a hydrogen atom or cation, and t and u each represent 0.
    The aminopolycarboxylic acid compound of the present invention can be used as a chelating agent for various metals, which is excellent in the biodegradability and masking effect on metals.
    The aminopolycarboxylic acid or a heavy metal complex thereof may be used as an additive in photographic materials and processing solutions in which case t and u may be 0-5.

    摘要翻译: 由表示的氨基多羧酸化合物 X <1> darstellt氢原子,烷基,羟基乙基,烷氧基烷基或羟基,X <2>烷基芳烷基,羟基,羟烷基或烷氧基烷基的darstellt, 中号<1>中,M <2>中,M <3>和M <4>各自表示氢原子或阳离子,t和u各自表示0。本发明的氨基多羧酸化合物,可以使用作为螯合剂 各种金属,所有这些都具有优异的生物降解性和掩蔽效应对金属。 氨基多羧酸或重金属的复合物可在照相材料和处理溶液在这种情况下,t和u可以是0-5被用作添加剂。

    Aminopolycarboxylic acid chelating agent, heavy metal chelate compound thereof, photographic additive and processing method
    5.
    发明公开
    Aminopolycarboxylic acid chelating agent, heavy metal chelate compound thereof, photographic additive and processing method 失效
    氨基多羧酸螯合剂,其重金属螯合物,照相添加剂和加工方法

    公开(公告)号:EP0840168A3

    公开(公告)日:1998-05-13

    申请号:EP97118821.4

    申请日:1997-10-29

    摘要: An aminopolycarboxylic acid compound represented by
    X 1 represents a hydrogen atom, alkyl group, hydroxyethyl group, alkoxyalkyl group or hydroxyl group, X 2 represents an alkyl group aralkyl group, hydroxyl group, hydroxyalkyl group or alkoxyalkyl group, M 1 , M 2 , M 3 and M 4 each represent a hydrogen atom or cation, and t and u each represent 0. The aminopolycarboxylic acid compound of the present invention can be used as a chelating agent for various metals, which is excellent in the biodegradability and masking effect on metals. The aminopolycarboxylic acid or a heavy metal complex thereof may be used as an additive in photographic materials and processing solutions in which case t and u may be 0-5.

    摘要翻译: 由X1表示的氨基多羧酸化合物表示氢原子,烷基,羟乙基,烷氧基烷基或羟基,X2表示烷基芳烷基,羟基,羟烷基或烷氧基烷基,M1,M2,M3和M4各自表示 氢原子或阳离子,t和u各自表示0.本发明的氨基多羧酸化合物可以用作各种金属的螯合剂,其对金属的生物降解性和掩蔽效果优异。 氨基多羧酸或其重金属配合物可用作照相材料和处理溶液中的添加剂,其中t和u可以为0-5。

    Method of processing silver halide photographic material and composition for processing
    7.
    发明公开
    Method of processing silver halide photographic material and composition for processing 失效
    Verarbeitungszusammensetzung und Verfahren zur Verarbeitung eines photographischer Silberhalogenidmaterials。

    公开(公告)号:EP0580041A2

    公开(公告)日:1994-01-26

    申请号:EP93111019.1

    申请日:1993-07-09

    IPC分类号: G03C5/305

    CPC分类号: G03C5/305

    摘要: A developer composition having improved stability to aerial oxidation, which contains at least one compound represented by formulae (A) and (B):
    where R 1 and R 2 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and X represents a group of atoms selected from carbon and nitrogen which forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R 1 and R 2 , respectively, and the carbonyl carbon of formula (A);
    where R 3 and R 4 each represent a hydroxyl group, an amino group, an acylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, an alkoxycarbonylamino group, a mercapto group or an alkylthio group; and Y represents a group of atoms selected from carbon, nitrogen and oxygen containing at least one ether bond, and Y forms a 5-membered or 6-membered ring together with the two vinyl carbons substituted by R 3 and R 4 , respectively, and the carbonyl carbon of formula (B), provided that both R 3 and R 4 are not hydroxyl.

    摘要翻译: 包含至少一种由式(A)和(B)表示的化合物的空气氧化稳定性的显影剂组合物:其中R 1和R 2各自表示羟基,氨基,酰氨基,烷基磺酰基氨基 基团,芳基磺酰基氨基,烷氧基羰基氨基,巯基或烷硫基; X表示分别与由R 1和R 2取代的两个乙烯基碳和式(A)的羰基碳一起形成5元或6元环的碳原子和氮原子的基团。 其中R 3和R 4各自表示羟基,氨基,酰氨基,烷基磺酰基氨基,芳基磺酰基氨基,烷氧基羰基氨基,巯基或烷硫基。 Y表示选自含有至少一个醚键的碳,氮和氧的原子,Y分别与由R3和R4取代的两个乙烯基碳一起形成5元或6元环,羰基 式(B)的碳,条件是R 3和R 4不是羟基。

    Aminopolycarboxylic acid-series chelating agent, heavy metal compound thereof, photographic additive, and processing method
    10.
    发明公开
    Aminopolycarboxylic acid-series chelating agent, heavy metal compound thereof, photographic additive, and processing method 失效
    Aminopolycarboxylat-Chelatbildner,Schwermetall-Verbindung davon,photographischer Zusatz und Verarbeitungsverfahren

    公开(公告)号:EP0851287A2

    公开(公告)日:1998-07-01

    申请号:EP97122858.0

    申请日:1997-12-23

    摘要: There is disclosed a compound represented by the following formula (I):
       wherein R 1 and R 2 each represent a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, a carboxyl group, an amino group, an alkoxy group, a sulfo group, a nitro group, a phosphono group, an acylamino group, a sulfonylamino group, an aryloxy group, a sulfamoyl group, a carbamoyl group, an alkylthio group, an arylthio group, an acyl group, a hydroxamic acid group, or a hydroxyl group; R 3 represents a hydrogen atom, an alkyl group substituted with at least one selected from a group consisting of an alkoxy group, an aryl group and a heterocyclic group, an unsubstituted alkyl group, an aryl group, or a heterocyclic group; W represents a divalent linking group having a carbon atom(s); m and n are each an integer of 1 to 3, with the proviso that when n = 1, R 3 does not represent a hydrogen atom, when n = 2 or 3, at least one of nR 3 's represents an alkyl group, an aryl group, or a heterocyclic group, and when m and n are each 2 or more, mR 1 's are the same or different and nR 3 's are the same or different, and M 1 , M 2 , and M 3 each represent a hydrogen atom or a cation. The compound is a chelating agent for various metals that is excellent in biodegradability and metal sequestering capacity.

    摘要翻译: 公开了由下式(I)表示的化合物:其中R 1和R 2各自表示氢原子,烷基,芳基,杂环基,羧基, 氨基,烷氧基,磺基,硝基,膦酰基,酰氨基,磺酰氨基,芳氧基,氨磺酰基,氨基甲酰基,烷硫基,芳硫基,酰基 异羟肟酸基或羟基; R 3表示氢原子,被选自烷氧基,芳基和杂环基中的至少一种取代的烷基,未取代的烷基,芳基或杂环基; W表示具有碳原子的二价连接基团; m和n各自为1至3的整数,条件是当n = 1时,R 3不表示氢原子,当n = 2或3时,nR 3中的至少一个表示 烷基,芳基或杂环基,当m和n分别为2以上时,mR 1相同或不同,nR 3相同或不同,M 1,M 2和M 3各自表示氢原子或阳离子。 该化合物是生物降解性和金属螯合能力优异的各种金属螯合剂。