公开(公告)号：EP2719451A1

公开(公告)日：2014-04-16

申请号：EP12797214.9

申请日：2012-05-30

申请人： Fude (Beijing) Chemical & Industry Co., Ltd ,  Tsinghua University

发明人： WEI, Fei ,  WEI, Xiaobo ,  WANG, Yao ,  ZHU, Chang

IPC分类号： B01J8/24 ,  C07C1/20 ,  C07C11/02

CPC分类号： C07C1/22 ,  B01J8/0055 ,  B01J8/1836 ,  B01J8/1863 ,  B01J8/24 ,  B01J8/28 ,  C07C1/20 ,  C07C2529/85 ,  Y02P20/584 ,  C07C11/02

摘要： The present invention provides a fluidized bed reactor and its use for producing olefins from oxygenates, the fluidized bed reactor comprises: a reaction zone located in the lower portion of the fluidized bed reactor and comprising a lower dense phase zone and an upper riser, wherein the dense phase zone and the riser are connected with each other transitionally; a separation zone located in the upper portion of the fluidized bed reactor and comprising a settling chamber, a fast gas-solid separation means, a cyclone and a gas collecting chamber, wherein the riser extends upwardly into the separation zone and is connected at its outlet with the inlet of the fast gas-solid separation means, the fast gas-solid separation means is connected at its outlet with the inlet of the cyclone via a fast gas passage, the cyclone is connected at its outlet with the gas collecting chamber, and the gas collecting chamber is located below the reactor outlet and connected therewith; and a catalyst recycle line for recycling the catalyst from the settling chamber back to the dense phase zone, a catalyst withdrawl line for withdrawing the deactivated catalyst from the settling chamber and/or the dense phase zone to the catalyst regeneration means, and a catalyst return line for returning the regenerated catalyst from the catalyst regeneration means to the dense phase zone.

摘要翻译： 本发明提供一种流化床反应器及其用于从含氧化合物生产烯烃的用途，该流化床反应器包括：反应区，位于流化床反应器的下部，并包含下部致密相区和上部提升管，其中 密相区和提升管相互连接; 位于流化床反应器上部的分离区，包括沉降室，快速气固分离装置，旋风分离器和气体收集室，其中提升管向上延伸进入分离区并连接在其出口 随着快速气固分离装置的入口，快速气固分离装置通过快速气体通道在其出口与旋风分离器的入口连接，旋风分离器在其出口与气体收集室连接， 气体收集室位于反应器出口下方并与之连接; 以及用于将催化剂从沉降室再循环回密相区域的催化剂再循环管线，用于将去活化催化剂从沉降室和/或致密相区域抽出到催化剂再生装置的催化剂提取管线，以及催化剂返回 使再生催化剂从催化剂再生装置返回到致密相区。

公开(公告)号：EP1391425B1

公开(公告)日：2010-08-18

申请号：EP02700107.2

申请日：2002-01-29

申请人： Tsinghua University

发明人： WEI, Fei ,  WANG, Yao ,  LUO, Guohua ,  YU, Hao ,  LI, Zhifei ,  QIAN, Weizhong ,  WANG, Zhanwen ,  JIN, Yong

IPC分类号： C01B31/02

CPC分类号： B82Y30/00 ,  B01J8/0055 ,  B01J8/1836 ,  B01J21/04 ,  B01J21/08 ,  B01J21/185 ,  B01J23/70 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8892 ,  B01J2208/00132 ,  B82Y40/00 ,  C01B3/26 ,  C01B32/162 ,  C01B32/164 ,  Y10S977/843

摘要： The present invention relates to a way to manufacture carbon nanotubes (CNTs) continuously in a novel nano-agglomerate fluidized-bed and the reactor (NAFBR). It belongs to material and chimical engineering fields. The procedure includes loading transition metal compounds on a support, obtaining a supported catalyst of metal nanoparticles by deoxidization or heater decomposition, catalytic pyrolyzing carbon source gases and vapor depositing of carbon atoms in a NAFBR. CNTs 4∩100 nm in diameter and 0.5∩1000 µm in length have been synthesized on catalyst supports. As the result of a careful choice of the catalysts, as well as the agglomerate structures and size, CNT agglomerates ranged 1∩1000 µm have been smoothly fluidized under 0.005∩2 m/s superficial gas velocity. The bed density is ranged 20∩800 kg/m3 in the NAFBR. This unit is simple and easy to be operated in a high intensity, and it can be used to produce high-purity CNTs with graphitoid walls in high-yield.

公开(公告)号：EP1391425A1

公开(公告)日：2004-02-25

申请号：EP02700107.2

申请日：2002-01-29

申请人： Tsinghua University

发明人： WEI, Fei ,  WANG, Yao ,  LUO, Guohua ,  YU, Hao ,  LI, Zhifei ,  QIAN, Weizhong ,  WANG, Zhanwen ,  JIN, Yong

IPC分类号： C01B31/02

CPC分类号： B82Y30/00 ,  B01J8/0055 ,  B01J8/1836 ,  B01J21/04 ,  B01J21/08 ,  B01J21/185 ,  B01J23/70 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8892 ,  B01J2208/00132 ,  B82Y40/00 ,  C01B3/26 ,  C01B32/162 ,  C01B32/164 ,  Y10S977/843

摘要： The present invention relates to a method for continuous production of carbon nanotubes in a nano-agglomerate fluidized bed, which comprises the following steps: loading transition metal compounds on a support, obtaining supported nanosized metal catalysts by reducing or dissociating, catalytically decomposing a carbon-source gas, and growing carbon nanotubes on the catalyst support by chemical vapor deposition of carbon atoms. The carbon nanotubes are 4∼100 nm in diameter and 0.5∼1000 µm in length. The carbon nanotube agglomerates, ranged between 1∼1000 µm, are smoothly fluidized under 0.005 to 2 m/s superficial gas velocity and 20∼800 kg/m 3 bed density in the fluidized-bed reactor. The apparatus is simple and easy to operate, has a high reaction rate, and it can be used to produce carbon nanotubes with high degree of crystallization, high purity, and high yield.

摘要翻译： 本发明涉及在纳米聚集体流化床中连续生产碳纳米管的方法，包括以下步骤：将载体上的过渡金属化合物加载到载体上，通过还原或解离催化分解碳 - 源气体和通过碳原子的化学气相沉积在催化剂载体上生长的碳纳米管。 碳纳米管的直径为4nm，长度为0.5〜1000μm。 在流化床反应器中，碳纳米管凝聚体在1〜1000μm之间在0.005〜2m / s表观气体速度和20〜800kg / m 3床密度下平稳流动。 该装置简单易操作，反应速度快，可用于制造高结晶度，高纯度，高产率的碳纳米管。