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公开(公告)号：EP1732969A2
公开(公告)日：2006-12-20
申请号：EP05705282.1
申请日：2005-01-07
IPC分类号： C08G63/64
CPC分类号： C07C45/002 , C07C2602/42 , C07C2603/68 , C07C2603/72 , C07C2603/86 , C07C49/433 , C07C49/453 , C07C49/423
摘要： A method of preparing a polycyclic compound containing a ketone functionality comprising: reacting a mixture comprising a catalyst , a reactant compound and an amount of water greater than or equal to 3 weight percent (wt%) based on the weight of the reactant compound; wherein said catalyst comprises nickel and base and said reactant compound comprises at least two fused rings, A and B wherein ring A is a saturated ring or ring system having 5 to 7 cyclic carbons and substituted with a hydroxyl functionality and ring B is a non-aromatic unsaturated ring having 5 to 6 cyclic carbons; and converting the hydroxyl functionality of ring A to a ketone functionality and non-aromatic unsaturated ring B to a saturated ring.
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2.发明公开
公开(公告)号：EP1636157A2
公开(公告)日：2006-03-22
申请号：EP04749983.5
申请日：2004-04-12
发明人： KUMBHAR, Pramod, Shankar , THAMPI, Jegadeesh , SINGH, Bharat, 112 Haritha Apt. Flat 302 , FULMER, John, W. , TATAKE, Prashant, Anil
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of an acid treated clay such as acid treated Montmorillonite clay to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译： 对于将CHP转化为BPA的方法的第一步和第二步，使用特定的催化剂组合提供高收率的BPA和低杂质收率，而不需要中间纯化步骤。 在第一步中，CHP在酸处理的粘土如酸处理过的蒙脱石粘土的存在下裂解以产生苯酚和丙酮。 在第二步中，所产生的苯酚和丙酮在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂的阳离子交换树脂催化剂存在下反应，优选不经中间纯化，以产生BPA。
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