INTEGRATED PROCESS FOR CO-PRODUCTION OF CARBOXYLIC ACIDS AND HALOGEN PRODUCTS FROM CARBON DIOXIDE

    公开(公告)号:EP3157897A4

    公开(公告)日:2018-03-21

    申请号:EP14895127

    申请日:2014-07-14

    Abstract: The present disclosure is a method and system for production of carboxylic based chemicals. A method for producing at oxalic acid may include receiving an anolyte feed at an anolyte region of an electrochemical cell including an anode and receiving a catholyte feed including carbon dioxide and an alkali metal bicarbonate at a catholyte region of the electrochemical cell including a cathode. Method may include applying an electrical potential between the anode and cathode sufficient to reduce the carbon dioxide to at least one reduction product and converting the at least one reduction product and an alkali metal hydroxide to an alkali metal oxalate via a thermal reactor. The method may further include converting the alkali metal oxalate to oxalic acid at the electrochemical acidification electrolyzer. The method may further include the co-production of halogen products from the anolyte region of the electrochemical cell, by the oxidation of hydrogen halides used as an anolyte feed. The halogen may then be further reacted with other chemicals to produce chlorinated organics as well as inorganic compounds such as sodium hypochlorite.

    INTEGRATED PROCESS FOR THE MANUFACTURE OF FLUORINATED OLEFINS
    9.
    发明公开
    INTEGRATED PROCESS FOR THE MANUFACTURE OF FLUORINATED OLEFINS 审中-公开
    氟化烯烃制造的综合方法

    公开(公告)号:EP3263543A1

    公开(公告)日:2018-01-03

    申请号:EP17180528.6

    申请日:2011-10-07

    Abstract: The instant invention relates, at least in part, to a method increasing the cost efficiency for dehydrohalogenation production of a fluorinated olefin by recovering and recycling spent dehydrohalogenation agent. In one aspect, the present invention relates to dehydrohalogenating a fluorinated alkane (e.g. pentafluoropropane and/or hexafluoropropane) in the presence of a dehydrohalogenating agent to produce a fluorinated olefin (e.g. tetrafluoropropenes and/or pentafluoropropenes). Removal of spent dehydrohalogenating agent from the reactor allows for facile separation of organic and dehydrohalogenating agent, the latter of which is recycled.

    Abstract translation: 本发明至少部分涉及通过回收和再循环用过的脱卤化氢剂来提高氟化烯烃的脱卤化氢生产的成本效率的方法。 一方面,本发明涉及在脱卤化氢剂存在下使氟化烷烃(例如五氟丙烷和/或六氟丙烷)脱卤化氢以产生氟化烯烃(例如四氟丙烯和/或五氟丙烯)。 从反应器中除去用过的脱卤化氢剂可以使有机和脱卤化氢剂容易分离,后者可循环使用。

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