Method for preparing block polyphenylene ether-polycarbonates
    5.
    发明公开
    Method for preparing block polyphenylene ether-polycarbonates 失效
    Verfahren zur Herstellung von Polyphenylentherther-聚碳酸封端复合物。

    公开(公告)号:EP0317773A2

    公开(公告)日:1989-05-31

    申请号:EP88117735.6

    申请日:1988-10-25

    IPC分类号: C08G63/62 C08G65/48

    摘要: Block polyphenylene ether-polycarbonates are prepared by blending a mixture of at least one polyphenylene ether wherein all phenolic end groups are in the free phenol form; at least one cyclic polycarbonate oligomer, preferably an oligomer mixture; and a catalyst for conversion of cyclic polycarbonates to linear polycarbonates; and heating said mixture to polymerization temperature. The preferred catalysts are phenoxides, salts of polycarbonate oligomers and tetraphenylborate salts. The method may be conducted in the melt or in solution, and is adaptable for employment in reactive processing operations.

    摘要翻译: 嵌段聚苯醚 - 聚碳酸酯通过共混至少一种聚苯醚的混合物制备,其中所有酚端基都是游离酚形式; 至少一种环状聚碳酸酯低聚物,优选低聚物混合物; 和用于将环状聚碳酸酯转化成线性聚碳酸酯的催化剂; 并将所述混合物加热至聚合温度。 优选的催化剂是苯氧化物,聚碳酸酯低聚物的盐和四苯基硼酸盐。 该方法可以在熔体或溶液中进行,并且适用于反应处理操作中的使用。